公开(公告)号：US11613681B2

公开(公告)日：2023-03-28

申请号：US16306174

申请日：2017-05-29

Applicant: BASF SE

Inventor： Karl-Heinz Schumacher ,  Thomas Fenlon ,  Sophie Putzien ,  Nicolas Vautravers ,  Ulrike Licht

IPC: C09J175/04 ,  C08G71/04 ,  C08J5/12 ,  C09J5/06 ,  C08K5/053 ,  C08K5/17

Abstract: A description is given of the use of compounds having n 2-oxo-1,3-dioxolane-4-carboxamide units as a reactive component in 2-component adhesives, especially for preparing hydroxypolyurethanes or hydroxypolycarbonates for adhesives applications, where n is a number greater than or equal to 2. A description is also given of corresponding two-component adhesives and adhesive bonding methods. Employed preferably as a second component of the two-component adhesive is a polyfunctional curing agent compound which is preferably selected from polyamines which have two or more amine groups and polyols which have two or more alcoholic hydroxyl groups.

公开(公告)号：US10532970B2

公开(公告)日：2020-01-14

申请号：US16307540

申请日：2017-06-27

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Andreas Keller ,  Michaela Fenyn

IPC: C07C45/38 ,  B01J23/00 ,  B01J23/42 ,  B01J21/18

Abstract: Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols where the oxidant is oxygen in the presence of a catalyst comprising platinum on a support in the presence of a liquid phase which contains at least 25 weight-% water based on the total weight of the liquid phase.

公开(公告)号：US09796654B2

公开(公告)日：2017-10-24

申请号：US15312033

申请日：2015-05-19

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim H. Teles ,  Albrecht Berkessel ,  Mathias Paul ,  Veera R. Yatham

IPC: C07C67/00 ,  C07C67/347 ,  B01J31/02

CPC classification number: C07C67/347 ,  B01J31/0244 ,  B01J2231/20 ,  C07C69/593

Abstract: The present invention relates to a process for the preparation of compounds or a mixture of compounds of the general formulae I.a or I.b wherein R1 is selected from C1-C12-alkyl, C3-C6-cycloalkyl, —C(═O)OR2, —PO(OR2a)2, aryl and hetaryl, R2, R2a are independently of each other selected from the group consisting of hydrogen, C1-C12-alkyl, C1-C12-alkenyl, where the last two radicals mentioned are unsubstituted, partly or completely halogenated or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of C1-C6-alkoxy and CN, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, aryl and aryl-C1-C4-alkyl, where the last four radicals mentioned are unsubstituted or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, —CN, and halogen, which comprises dimerizing olefin compound of the general formula II, in the presence of at least one N-heterocyclic carbene catalyst.

公开(公告)号：US10766781B2

公开(公告)日：2020-09-08

申请号：US16060229

申请日：2016-12-07

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Joaquim Henrique Teles ,  Nicolas Vautravers ,  Ulrich Müller

IPC: B01J29/06 ,  C01B39/08 ,  C01B37/02 ,  C01B39/12 ,  C01B39/48 ,  C07D313/04 ,  C07F5/02 ,  C07F7/22 ,  C07C51/00 ,  C07C67/00 ,  B01J29/70 ,  B01J29/86 ,  B01J29/035 ,  B01J37/10 ,  B01J35/10 ,  B01J37/03 ,  C07C51/02

Abstract: A process for preparing a tin-containing zeolitic material having framework type BEA, comprising providing an aqueous synthesis mixture comprising a boron source, a silicon source, and a BEA structure directing agent; subjecting the synthesis mixture provided in to hydrothermal pre-crystallization conditions; adding the tin source to the obtained mixture; subjecting the obtained aqueous synthesis mixture to hydrothermal crystallization conditions, obtaining a tin-containing zeolitic material having framework type BEA comprised in its mother liquor.

公开(公告)号：US10202324B2

公开(公告)日：2019-02-12

申请号：US15571107

申请日：2016-05-04

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Ralf Pelzer ,  Daniel Schneider ,  Florian Garlichs ,  Andreas Keller ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC: C07C45/54 ,  C07C45/78 ,  C07C67/39 ,  C07C45/64

Abstract: A process for preparing 2,6-dimethyl-5-heptenal, comprising oxidizing citral of which more than 50% are present as geranial with hydrogen peroxide in the presence of a catalyst comprising a Baeyer-Villiger oxidation catalyst, preferably a tin-containing molecular sieve.

公开(公告)号：US09765003B2

公开(公告)日：2017-09-19

申请号：US15308755

申请日：2015-05-04

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim H. Teles ,  Ralf Pelzer ,  Daniel Schneider

IPC: C07C45/28 ,  C07C45/00 ,  C07C45/82

CPC classification number: C07C45/002 ,  C07B2200/07 ,  C07C45/28 ,  C07C45/82 ,  C07C47/21

Abstract: The present invention relates to a process for producing 2,6-dimethyl-5-hepten-1-al, which comprises reacting 3,7-dimethyl-1,6-octadiene (dihydromyrcene, beta-citronellene) with N2O in a solvent or solvent mixture containing at least one solvent having a proton-donating functional group.

公开(公告)号：US20140128622A1

公开(公告)日：2014-05-08

申请号：US14072179

申请日：2013-11-05

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Andrei-Nicolae Parvulescu ,  Ulrich Müller

IPC: C07B41/06 ,  C07C51/285 ,  C07D309/30 ,  C07C45/29 ,  C07D313/04 ,  C07D315/00

CPC classification number: C07D313/04 ,  B01J23/00 ,  C07C45/54 ,  C07C51/285 ,  C07D309/30 ,  C07D313/00 ,  C07C47/21 ,  C07C57/03

Abstract: A process for the oxidation of an organic carbonyl compound comprising reacting the organic carbonyl compound, optionally in the presence of a solvent, with hydrogen peroxide in the presence of a catalyst comprising a tin-containing zeolitic material having an MWW-type framework structure.

Abstract translation: 一种有机羰基化合物的氧化方法，包括有机羰基化合物，任选在溶剂存在下，在含有具有MWW型骨架结构的含锡沸石材料的催化剂存在下，与过氧化氢反应。

公开(公告)号：US11111197B2

公开(公告)日：2021-09-07

申请号：US16956972

申请日：2018-12-05

Applicant: BASF SE

Inventor： Michaela Fenyn ,  Joseph John Zakzeski ,  Nicolas Vautravers ,  Joaquim Henrique Teles

IPC: C07C45/38 ,  B01J23/42 ,  B01J23/44 ,  B01J23/52 ,  C07C47/21

Abstract: Process for the preparation of alpha, beta unsaturated aldehydes by oxidation of alcohols in the presence of a liquid phase.

公开(公告)号：US10144691B2

公开(公告)日：2018-12-04

申请号：US15537128

申请日：2015-12-18

Applicant: BASF SE

Inventor： Nicolas Vautravers ,  Joaquim Henrique Teles ,  Ralf Pelzer ,  Daniel Schneider

IPC: C07C45/28 ,  C07C45/82

Abstract: The present invention relates to a process for preparing 1-[(1R,4R/S,8S)-10,10-dimethyl-7-methylene-4-bicyclo[6.2.0]decanyl]ethanone.

公开(公告)号：US09987624B2

公开(公告)日：2018-06-05

申请号：US15033402

申请日：2014-11-05

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Georg Uhl ,  Joaquim H. Teles ,  Nicolas Vautravers ,  Dominic Riedel

IPC: C01B39/06 ,  C01B39/48 ,  B01J29/70 ,  C01B39/12 ,  C07C45/58 ,  B01J35/00 ,  B01J35/10 ,  B01J37/08 ,  B01J37/30 ,  C01B39/02 ,  C01B39/46

CPC classification number: B01J29/7088 ,  B01J35/002 ,  B01J35/1019 ,  B01J37/08 ,  B01J37/30 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/026 ,  C01B39/06 ,  C01B39/12 ,  C01B39/46 ,  C01B39/48 ,  C07C45/58 ,  C07C2601/10 ,  C07C47/225

Abstract: A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.