公开(公告)号：US2416985A

公开(公告)日：1947-03-04

申请号：US37407841

申请日：1941-01-11

Applicant: CALIFORNIA RESEARCH CORP

Inventor： FARRINGTON BRUCE B ,  CLAYTON JAMES O ,  RUTHERFORD JOHN T

IPC: C07F9/02 ,  C07F9/08 ,  C07F9/30 ,  C07F9/38 ,  C10M137/06 ,  C10M137/12 ,  C10M141/10 ,  H01B3/22

CPC classification number: C07F9/02 ,  C07F9/08 ,  C07F9/30 ,  C07F9/38 ,  C10M129/10 ,  C10M137/06 ,  C10M137/12 ,  C10M141/10 ,  C10M2207/023 ,  C10M2207/025 ,  C10M2207/026 ,  C10M2207/027 ,  C10M2207/046 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/28 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/289 ,  C10M2207/40 ,  C10M2207/402 ,  C10M2207/404 ,  C10M2211/042 ,  C10M2211/06 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/042 ,  C10M2223/045 ,  C10M2223/047 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/065 ,  C10N2210/00 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2210/04 ,  C10N2210/06 ,  C10N2210/08 ,  C10N2230/08 ,  C10N2240/00 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/12 ,  C10N2240/121 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  C10N2250/10 ,  C10N2270/02 ,  H01B3/22

Abstract: 537,816. Metal phenates. STANDARD OIL CO. OF CALIFORNIA. Oct. 3, 1939, No. 27128. Convention date, Oct. 4, 1938. [Class 2 (iii)] [Also in Groups III and XIII] The properties of lubricating oils in respect of resistance to heat deterioration, decomposition causing piston ring sticking and corrosion of bearings are improved by the addition thereto of a metal phenate with a phenolic radical having more than 10 carbon atoms. The preferred phenates are those containing alkayl groups. Metals mentioned include sodium, potassium, beryllium, calcium, strontium, barium, magnesium, zinc, cadmium and aluminium. Specific compounds mentioned include sodium lauryl phenate, sodium cetyl phenate, calcium lauryl phenate, calcium cetyl phenate, calcium diamyl phenate, calcium heptyl phenate, calcium p-tertiary amyl phenate, calcium mono-chlor amyl phenate, calcium p-cyclohexyl phenate, aluminium lauryl phenate, aluminium di-cetyl phenate, magnesium cetyl phenate, barium cetyl phenate and calcium cetyl cresylate. Examples are given of the preparation of alkyl phenols from phenol and butene polymers by the addition of sulphuric acid to a mixture of phenol and the polymers followed by heating in an autoclave. The apparent molecular weight of the product depends on the exact composition of the polymers used and the degree of condensation. From products obtained by this process of different apparent molecular weights phenates of calcium, sodium, aluminium, magnesium and barium and prepared. An alkyl phenol is also produced by the addition of sulphuric acid to a mixture of cresylic acid and olefine polymers containing an average of 14 carbon atoms per molecule. The compound so obtained is reacted with calcium carbide to form the calcium salt which is used according to the process of the present invention.

Abstract translation: 537,816。 金属酚盐。 加利福尼亚标准油公司 1938年10月3日，第27128号。公约日期，1938年10月4日。[第2类（iii）] [也在第三和第三组]润滑油在耐热劣化，分解活塞方面的性质 通过添加具有多于10个碳原子的酚基的金属酚盐，提高了轴承的环粘结和腐蚀。 优选的酚盐是含有烷基的那些。 所提及的金属包括钠，钾，铍，钙，锶，钡，镁，锌，镉和铝。 所提及的具体化合物包括十二烷基酚盐，十二烷基酚盐，十二烷基酚盐，十二烷基酚盐，十二烷基酚盐，十二烷基苯磺酸盐，十二烷基苯磺酸钙， 酚盐，二十六烷基酚铝，十六烷基酚镁，十六烷基酚钠和十六烷基十六烷基十六烷基化钠。 给出了通过向酚和聚合物的混合物中加入硫酸制备烷基苯酚和丁烯聚合物，然后在高压釜中加热的实例。 产品的表观分子量取决于所用聚合物的精确组成和缩合度。 从通过该方法获得的产物通过不同表观分子量的钙，钠，铝，镁和钡的酚盐制备。 通过向每个分子平均含有14个碳原子的甲酚和烯烃聚合物的混合物中加入硫酸也产生烷基酚。 如此获得的化合物与碳化钙反应形成根据本发明方法使用的钙盐。

公开(公告)号：US2723995A

公开(公告)日：1955-11-15

申请号：US41132354

申请日：1954-02-19

Applicant: CALIFORNIA RESEARCH CORP

Inventor： RUTHERFORD JOHN T

IPC: C07C51/48

CPC classification number: C07C51/48 ,  C07C63/04 ,  C07C63/06

公开(公告)号：US2488662A

公开(公告)日：1949-11-22

申请号：US67926246

申请日：1946-06-25

Applicant: CALIFORNIA RESEARCH CORP

Inventor： FARRINGTON BRUNCE B ,  CLAYTON JAMES O ,  RUTHERFORD JOHN T

IPC: C07F9/09 ,  C07F9/11

CPC classification number: C10M1/08 ,  C07F9/09 ,  C10M2223/04 ,  C10M2223/042 ,  C10N2210/02

公开(公告)号：US2382043A

公开(公告)日：1945-08-14

申请号：US47127643

申请日：1943-01-04

Applicant: CALIFORNIA RESEARCH CORP

Inventor： FARRINGTON BRUCE B ,  CLAYTON JAMES O ,  RUTHERFORD JOHN T

IPC: C07F9/02 ,  C07F9/08 ,  C07F9/30 ,  C07F9/38 ,  C10M137/06 ,  C10M137/12 ,  C10M141/10 ,  H01B3/22

CPC classification number: C07F9/02 ,  C07F9/08 ,  C07F9/30 ,  C07F9/38 ,  C10M129/10 ,  C10M137/06 ,  C10M137/12 ,  C10M141/10 ,  C10M2207/023 ,  C10M2207/025 ,  C10M2207/026 ,  C10M2207/027 ,  C10M2207/046 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/28 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/289 ,  C10M2207/40 ,  C10M2207/402 ,  C10M2207/404 ,  C10M2211/042 ,  C10M2211/06 ,  C10M2223/04 ,  C10M2223/041 ,  C10M2223/042 ,  C10M2223/045 ,  C10M2223/047 ,  C10M2223/06 ,  C10M2223/061 ,  C10M2223/065 ,  C10N2210/00 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2210/04 ,  C10N2210/06 ,  C10N2210/08 ,  C10N2230/08 ,  C10N2240/00 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/12 ,  C10N2240/121 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  C10N2250/10 ,  C10N2270/02 ,  H01B3/22

Abstract: 537,816. Metal phenates. STANDARD OIL CO. OF CALIFORNIA. Oct. 3, 1939, No. 27128. Convention date, Oct. 4, 1938. [Class 2 (iii)] [Also in Groups III and XIII] The properties of lubricating oils in respect of resistance to heat deterioration, decomposition causing piston ring sticking and corrosion of bearings are improved by the addition thereto of a metal phenate with a phenolic radical having more than 10 carbon atoms. The preferred phenates are those containing alkayl groups. Metals mentioned include sodium, potassium, beryllium, calcium, strontium, barium, magnesium, zinc, cadmium and aluminium. Specific compounds mentioned include sodium lauryl phenate, sodium cetyl phenate, calcium lauryl phenate, calcium cetyl phenate, calcium diamyl phenate, calcium heptyl phenate, calcium p-tertiary amyl phenate, calcium mono-chlor amyl phenate, calcium p-cyclohexyl phenate, aluminium lauryl phenate, aluminium di-cetyl phenate, magnesium cetyl phenate, barium cetyl phenate and calcium cetyl cresylate. Examples are given of the preparation of alkyl phenols from phenol and butene polymers by the addition of sulphuric acid to a mixture of phenol and the polymers followed by heating in an autoclave. The apparent molecular weight of the product depends on the exact composition of the polymers used and the degree of condensation. From products obtained by this process of different apparent molecular weights phenates of calcium, sodium, aluminium, magnesium and barium and prepared. An alkyl phenol is also produced by the addition of sulphuric acid to a mixture of cresylic acid and olefine polymers containing an average of 14 carbon atoms per molecule. The compound so obtained is reacted with calcium carbide to form the calcium salt which is used according to the process of the present invention.

公开(公告)号：US2610201A

公开(公告)日：1952-09-09

申请号：US8660149

申请日：1949-04-09

Applicant: CALIFORNIA RESEARCH CORP

Inventor： RUTHERFORD JOHN T

IPC: C07C29/16 ,  C07C31/125 ,  C07C33/02 ,  C08K5/12

CPC classification number: C08K5/12 ,  C07C29/16 ,  C07C31/125 ,  C07C33/02

公开(公告)号：US2565428A

公开(公告)日：1951-08-21

申请号：US73507647

申请日：1947-03-17

Applicant: CALIFORNIA RESEARCH CORP

Inventor： HETZNER HOWARD P ,  RUTHERFORD JOHN T

IPC: C07C209/18

CPC classification number: C07C209/18

公开(公告)号：US2514625A

公开(公告)日：1950-07-11

申请号：US63478745

申请日：1945-12-13

Applicant: CALIFORNIA RESEARCH CORP

Inventor： CLAUSEN THEODORE I ,  RUTHERFORD JOHN T

CPC classification number: C10M1/08 ,  C10M2207/027 ,  C10M2207/123 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/14 ,  C10M2207/142 ,  C10M2207/16 ,  C10M2207/22 ,  C10M2207/288 ,  C10M2207/40 ,  C10M2207/404 ,  C10M2219/02 ,  C10M2219/044 ,  C10M2219/082 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/045 ,  C10N2210/00 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2230/12 ,  C10N2270/02

公开(公告)号：US2412903A

公开(公告)日：1946-12-17

申请号：US52068644

申请日：1944-02-01

Applicant: CALIFORNIA RESEARCH CORP

Inventor： MILLER ROBERT J ,  RUTHERFORD JOHN T

CPC classification number: C10M1/08 ,  C10M2207/025 ,  C10M2207/027 ,  C10M2207/028 ,  C10M2207/046 ,  C10M2211/042 ,  C10M2211/06 ,  C10M2215/062 ,  C10M2215/202 ,  C10M2219/066 ,  C10M2219/068 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089 ,  C10N2210/01 ,  C10N2210/02 ,  C10N2210/03 ,  C10N2210/04 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2270/02