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公开(公告)号：US4713362A
公开(公告)日：1987-12-15
申请号：US866531
申请日：1986-05-22
CPC分类号： C01B23/00 , B01D53/02 , B01J20/18 , C01B13/027 , C01B3/56 , C01B2203/042 , C01B2203/0465 , C01B2203/047 , C01B2203/048 , C01B2210/0082
摘要： A selective zeolitic adsorbent is prepared by activating a zeolitic composition having at least a portion, preferably at least 50%, of the exchangeable ion capacity occupied by a cation having a charge density of 2.0 or greater, preferably a divalent cation with a charge density of 2.0 or greater, such as calcium or magnesium by thoroughly dehydrating the exchanged zeolite. Additionally, separation ability of the zeolitic adsorbent can be further increased by reacting the thoroughly dehydrated zeolite in an oxidizing atmosphere.
摘要翻译： 通过活化沸石组合物制备选择性沸石吸附剂，所述沸石组合物具有至少一部分，优选至少50％的电荷密度为2.0或更大的阳离子所占据的可交换离子能力，优选电荷密度为 2.0或更大，例如通过使交换的沸石彻底脱水来脱离钙或镁。 此外，通过在氧化气氛中使完全脱水的沸石反应，可以进一步提高沸石吸附剂的分离能力。
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2.发明授权Selective chromatographic process using an ion-exchanged, dehydrated chabazite adsorbent 失效使用离子交换的脱水菱沸石吸附剂进行选择性色谱法
公开(公告)号：US4747854A
公开(公告)日：1988-05-31
申请号：US66789
申请日：1987-06-25
CPC分类号： B01J20/186 , Y10S95/902
摘要： The present invention relates to a process for the selective adsorption and separation of one or more constituents from a gas stream in a gas chromatograph, wherein the gas stream is contacted with a dehydrated chabazite adsorbent having a residual water content of less than 1.5 wt % and having at least 50% of any exchangeable ion capacity exchanged with a polyvalent metal cation. The process of the present invention both anticipates separation of the constituents due to either a difference in the heats of adsorption of the constituents or a size exclusion effect.
摘要翻译： 本发明涉及在气相色谱仪中从气流中选择性吸附和分离一种或多种成分的方法，其中气流与残留含水量小于1.5重量％的脱水菱沸石吸附剂接触， 具有与多价金属阳离子交换的任何可交换离子容量的至少50％。 本发明的方法既预期由于组分的吸附热差异或尺寸排阻效应导致组分的分离。
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3.发明授权
公开(公告)号：US4732584A
公开(公告)日：1988-03-22
申请号：US53283
申请日：1987-05-22
申请人： Charles G. Coe , David A. Roberts
发明人： Charles G. Coe , David A. Roberts
CPC分类号： B01J20/186
摘要： Thoroughly dehydrated, certain forms of chabazite have improved utility for purifying bulk gases. Compared to conventional molecular sieves, these chabazites have improved properties for removing low levels of gas contaminants having larger heats of adsorption than the bulk component. Also, the small pore chabazite can remove weakly interacting adsorbates from bulk gases having kinetic diameters which exceed that of the pore opening. This discovery of the intrinsic properties of polyvalent chabazites expands the range of contaminant gases which can be removed from bulk gases economically using standard adsorption processes, e.g. using these adsorbents it is possible to remove trace nitrogen from argon.
摘要翻译： 彻底脱水，某些形式的菱沸石已经提高了净化散装气体的效用。 与常规分子筛相比，这些菱沸石具有改进的性能，用于除去具有比主体组分更大的吸附热的低含量气体污染物。 此外，小孔菱沸石可以从具有超过孔开口的动力学直径的体积气体中除去弱相互作用的吸附物质。 这种多价菱沸石的固有性质的发现扩大了可以使用标准吸附方法，例如经济地从散装气体中去除的污染气体的范围。 使用这些吸附剂可以从氩气中除去痕量的氮。
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4.发明授权Selective adsorption process using an oxidized ion-exchanged dehydrated chabizite adsorbent 失效选择性吸附方法采用氧化离子交换脱水型硫酸盐吸附剂
公开(公告)号：US4744805A
公开(公告)日：1988-05-17
申请号：US69331
申请日：1987-07-01
CPC分类号： C01B13/027 , B01D53/02 , B01J20/18 , C01B23/00 , C01B3/56 , C01B2203/042 , C01B2203/0465 , C01B2203/047 , C01B2203/048 , C01B2210/0082
摘要： The present invention relates to a process for the selective adsorption and separation of one or more constituents from a gas stream in a gas chromatograph, wherein the gas stream is contacted with a dehydrated chabazite adsorbent having a residual water content of less than 1.5 wt. % and having at least 50% of any exchangeable ion capacity exchanged with a polyvalent metal cation and wherein the dehydrated chabazite has been reacted with an oxidizing atmosphere either during or following dehydration. The process of the present invention both anticipates separation of the constituents due to either a difference in the heats of adsorption of the constituents or a size exclusion effect.
摘要翻译： 本发明涉及一种在气相色谱仪中从气流中选择性吸附和分离一种或多种成分的方法，其中气流与残留含水量小于1.5重量％的脱水菱沸石吸附剂接触。 并且具有与多价金属阳离子交换的任何可交换离子能力的至少50％，并且其中脱水的菱沸石在脱水期间或之后与氧化气氛反应。 本发明的方法既预期由于组分的吸附热差异或尺寸排阻效应导致组分的分离。
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公开(公告)号：US5584912A
公开(公告)日：1996-12-17
申请号：US626814
申请日：1996-04-03
申请人： Hong-Xin Li , Charles G. Coe , Thomas R. Gaffney , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
发明人： Hong-Xin Li , Charles G. Coe , Thomas R. Gaffney , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
CPC分类号： B01D53/02 , B01J20/18 , C01B13/027 , C01B21/0466 , C01B39/205 , B01D2253/104 , B01D2253/106 , B01D2253/311 , B01D53/047 , C01B2210/0046 , Y10S423/21 , Y10S95/902
摘要： The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a micropore volume determined in the sodium and/or potassium form of at least 0.20 cm.sup.3 /g and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:M.sub.2/n O:X.sub.2 O.sub.3 :(2.0 to
摘要翻译： 本发明是一种组合物，该组合物的合成和一种使用该组合物选择性地从氧气中分离氮气的方法，其中该组合物是Si / Al比小于2.0的结晶EMT，在钠中测定的微孔体积 和/或钾形式为至少0.20cm 3 / g和至少80％的锂阳离子交换，优选包括与结晶FAU结构的共生体，其中纯或共生成分具有以下化学式：M2 / nO：X 2 O 3： （2.0至<4.0）SiO 2，其中M =一价或多价的价数为n的金属阳离子，X选自铝，镓和硼，优选铝。
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公开(公告)号：US4744837A
公开(公告)日：1988-05-17
申请号：US002841
申请日：1987-01-13
摘要： A process for bright annealing of chromium containing alloys such as stainless steels in an atmosphere of nitrogen and hydrogen containing controlled additions of an inhibitor as described in U.S. Pat. No. 4,334,938 wherein at least one element provided at the surface of the article being annealed in an amount such that it is oxidized in preference to the chromium in said article, whereby nitrogen uptake is inhibited and dulling of the metal surface by formation of a film containing chromium oxide is avoided.
摘要翻译： 在氮气和氢气气氛中对含铬合金如不锈钢进行光亮退火的方法，其含有受控添加的抑制剂，如美国专利No. 其中提供在制品表面处的至少一种元素被退火，其量使其优先于所述制品中的铬被氧化，由此通过形成膜来抑制氮吸收并使金属表面变钝 避免了含铬氧化铬。
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7.发明授权Substituted acetylacetonate cobaltic promoters for unsaturated polyester resin 失效用于不饱和聚酯树脂的取代的乙酰丙酮钴助催化剂
公开(公告)号：US4138385A
公开(公告)日：1979-02-06
申请号：US830182
申请日：1977-09-02
IPC分类号： C08F299/04 , C08L67/00 , C08L67/06
CPC分类号： C08F299/0464
摘要： This invention relates to an improvement in a process for curing unsaturated polyester resins, preferably chemically thickened with a Group II metal oxide or hydroxide, and to the resulting product. The improvement resides in the use of an acetylacetonate ligand of cobalt III, which is mono, di, or tri-substituted with an electron withdrawing group, e.g. a nitro, phenyl or halogen atom.
摘要翻译： 本发明涉及用于固化不饱和聚酯树脂，优选用第II族金属氧化物或氢氧化物化学增稠的方法和所得产物的改进。 改进在于使用由吸电子基团单，二或三取代的钴III的乙酰丙酮配体。 硝基，苯基或卤原子。
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公开(公告)号：US5567407A
公开(公告)日：1996-10-22
申请号：US241880
申请日：1994-05-12
申请人： Charles G. Coe , Thomas R. Gaffney , Hong-Xin Li , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
发明人： Charles G. Coe , Thomas R. Gaffney , Hong-Xin Li , Yanliang Xiong , Johan A. Martens , Pierre A. Jacobs
IPC分类号： B01D53/34 , B01D53/047 , B01D53/81 , B01J20/18 , B01J20/30 , C01B13/02 , C01B21/04 , C01B39/20
CPC分类号： B01D53/02 , B01D53/047 , B01J20/18 , C01B13/027 , C01B21/0466 , C01B39/205 , B01D2253/108 , B01D2253/30 , B01D2256/12 , B01D2257/102 , B01D2259/402 , C01B2210/0046 , Y10S423/21 , Y10S95/902
摘要： The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:(0.20-0.0)M.sub.2/n O:(0.80-1.0)Li.sub.2 O:X.sub.2 O.sub.3 :(2.0 to
摘要翻译： 本发明是一种组合物，该组合物的合成以及使用该组合物选择性地从氧气中分离氮气的方法，其中该组合物是Si / Al比小于2.0的结晶EMT和至少一种锂阳离子交换 80％，优选包括具有结晶FAU结构的共生体，其中纯或共生成分具有以下化学式：（0.20-0.0）M2 / nO：（0.80-1.0）Li 2 O：X 2 O 3：（2.0至4.0）SiO 2其中 M =具有n价的锂以外的金属阳离子，X选自铝，镓和硼，优选铝。
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公开(公告)号：US4481018A
公开(公告)日：1984-11-06
申请号：US441822
申请日：1982-11-15
申请人： Charles G. Coe , Steven M. Kuznicki
发明人： Charles G. Coe , Steven M. Kuznicki
CPC分类号： B01D53/04 , B01J20/186 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2257/102 , B01D2257/80
摘要： The invention relates to faujasite-containing compositions in which the original hydrogen or monovalent forms are ion exchanged to their polyvalent form and then thermally activated to promote dehydration and dehydroxylation of the faujasite while maintaining substantially the same zeolite content. The resulting compositions containing faujasites substantially in their dehydrated/dehydroxylated state have been found to have surprisingly high selectivities and capacities for the separation of air into nitrogen and oxygen.
摘要翻译： 本发明涉及含有八面沸石的组合物，其中原始氢或一价形式被离子交换为其多价形式，然后热活化以促进八面沸石的脱水和脱羟基化，同时保持基本相同的沸石含量。 已经发现得到的含有基本上脱水/脱羟基化状态的八面沸石的组合物具有惊人的高选择性和将空气分离成氮和氧的能力。
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公开(公告)号：US4150047A
公开(公告)日：1979-04-17
申请号：US883885
申请日：1978-03-06
摘要： This invention relates to an improved process for preparing halogenated metal chelates of beta-dicarbonyl compounds, particularly the tris-brominated acetylacetonates. The process comprises passing elemental halogen through a solution comprising the metal chelate, an inert solvent in which the metal chelate has a solubility of at least 0.5 grams per 100 grams solvent and the halogenated product has a solubility of less than 1 gram per 100 grams solvent and a halogenated Lewis acid at a temperature from about 0.degree.-60.degree. C. thereby forming a halogenated metal chelate precipitate and then recovering the precipitate.
摘要翻译： 本发明涉及一种制备β-二羰基化合物，特别是三溴化乙酰丙酮化物的卤化金属螯合物的改进方法。 该方法包括使元素卤素通过包含金属螯合物的溶液，惰性溶剂，其中金属螯合物的溶解度至少为0.5克/ 100克溶剂，卤化产物的溶解度小于1克/ 100克溶剂 和卤代路易斯酸，在约0°-60℃的温度下，由此形成卤化金属螯合物沉淀，然后回收沉淀物。
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