摘要:
This invention relates to an improvement in a process for curing unsaturated polyester resins, preferably chemically thickened with a Group II metal oxide or hydroxide, and to the resulting product. The improvement resides in the use of an acetylacetonate ligand of cobalt III, which is mono, di, or tri-substituted with an electron withdrawing group, e.g. a nitro, phenyl or halogen atom.
摘要:
This invention relates to an improved process for preparing halogenated metal chelates of beta-dicarbonyl compounds, particularly the tris-brominated acetylacetonates. The process comprises passing elemental halogen through a solution comprising the metal chelate, an inert solvent in which the metal chelate has a solubility of at least 0.5 grams per 100 grams solvent and the halogenated product has a solubility of less than 1 gram per 100 grams solvent and a halogenated Lewis acid at a temperature from about 0.degree.-60.degree. C. thereby forming a halogenated metal chelate precipitate and then recovering the precipitate.
摘要:
This invention relates to an improved three component promoter for enhancing the cure rate of a molding compound comprising an unsaturated polyester resin and an unsaturated monomer copolymerizable therewith. The presence of the three component promoter system substantially enhances the cure rate of the molding compound while at the same time substantially lengthening the shelf life of the prepromoted resin. The three component system comprises a cobalt salt in the plus 2 valence state with the cobalt being present in an amount to provide from about 0.0005-0.06 parts cobalt metal per 100 parts unsaturated polyester resin (including unsaturated monomer), a copper salt, the salt being present in an amount to provide from 0.01-1.times.10.sup.-6 parts copper metal per 100 parts of unsaturated polyester resin (including unsaturated monomer), and an amine selected from the group consisting of tertiary amino alkyl acrylates and methacrylates, heterocyclic amines, para substituted aromatic amines and lower alkyl and alkanol amines (C.sub.1 -C.sub.6) and phenolic amines, the amine being present in an amount to provide from about 0.0001 to 0.05 moles per 100 parts of unsaturated polyester resin, including unsaturated monomer.
摘要:
The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a micropore volume determined in the sodium and/or potassium form of at least 0.20 cm.sup.3 /g and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:M.sub.2/n O:X.sub.2 O.sub.3 :(2.0 to
摘要:
A process for bright annealing of chromium containing alloys such as stainless steels in an atmosphere of nitrogen and hydrogen containing controlled additions of an inhibitor as described in U.S. Pat. No. 4,334,938 wherein at least one element provided at the surface of the article being annealed in an amount such that it is oxidized in preference to the chromium in said article, whereby nitrogen uptake is inhibited and dulling of the metal surface by formation of a film containing chromium oxide is avoided.
摘要:
A selective zeolitic adsorbent is prepared by activating a zeolitic composition having at least a portion, preferably at least 50%, of the exchangeable ion capacity occupied by a cation having a charge density of 2.0 or greater, preferably a divalent cation with a charge density of 2.0 or greater, such as calcium or magnesium by thoroughly dehydrating the exchanged zeolite. Additionally, separation ability of the zeolitic adsorbent can be further increased by reacting the thoroughly dehydrated zeolite in an oxidizing atmosphere.
摘要:
The present invention is a composition, a synthesis of the composition and a method of using the composition for selectively adsorptively separating nitrogen from oxygen wherein the composition is a crystalline EMT with a Si/Al ratio less than 2.0 and a lithium cation exchange of at least 80%, preferably including an intergrowth with a crystalline FAU structure, wherein the pure or intergrowth compositions have the chemical formula:(0.20-0.0)M.sub.2/n O:(0.80-1.0)Li.sub.2 O:X.sub.2 O.sub.3 :(2.0 to
摘要翻译:本发明是一种组合物,该组合物的合成以及使用该组合物选择性地从氧气中分离氮气的方法,其中该组合物是Si / Al比小于2.0的结晶EMT和至少一种锂阳离子交换 80%,优选包括具有结晶FAU结构的共生体,其中纯或共生成分具有以下化学式:(0.20-0.0)M2 / nO:(0.80-1.0)Li 2 O:X 2 O 3:(2.0至4.0)SiO 2其中 M =具有n价的锂以外的金属阳离子,X选自铝,镓和硼,优选铝。
摘要:
The present invention relates to a process for the selective adsorption and separation of one or more constituents from a gas stream in a gas chromatograph, wherein the gas stream is contacted with a dehydrated chabazite adsorbent having a residual water content of less than 1.5 wt % and having at least 50% of any exchangeable ion capacity exchanged with a polyvalent metal cation. The process of the present invention both anticipates separation of the constituents due to either a difference in the heats of adsorption of the constituents or a size exclusion effect.
摘要:
Thoroughly dehydrated, certain forms of chabazite have improved utility for purifying bulk gases. Compared to conventional molecular sieves, these chabazites have improved properties for removing low levels of gas contaminants having larger heats of adsorption than the bulk component. Also, the small pore chabazite can remove weakly interacting adsorbates from bulk gases having kinetic diameters which exceed that of the pore opening. This discovery of the intrinsic properties of polyvalent chabazites expands the range of contaminant gases which can be removed from bulk gases economically using standard adsorption processes, e.g. using these adsorbents it is possible to remove trace nitrogen from argon.
摘要:
The invention relates to faujasite-containing compositions in which the original hydrogen or monovalent forms are ion exchanged to their polyvalent form and then thermally activated to promote dehydration and dehydroxylation of the faujasite while maintaining substantially the same zeolite content. The resulting compositions containing faujasites substantially in their dehydrated/dehydroxylated state have been found to have surprisingly high selectivities and capacities for the separation of air into nitrogen and oxygen.