公开(公告)号：US2906734A

公开(公告)日：1959-09-29

申请号：US68536657

申请日：1957-09-23

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C08F10/00 ,  C08K5/19

CPC classification number: C08F10/00 ,  C08K5/09 ,  C08K5/19 ,  C08F4/642 ,  C08L83/04

公开(公告)号：US2830968A

公开(公告)日：1958-04-15

申请号：US51177055

申请日：1955-05-27

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

CPC classification number: C08G77/16

公开(公告)号：US2672104A

公开(公告)日：1954-03-16

申请号：US11389949

申请日：1949-09-02

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: A21D8/08 ,  C08G77/00

CPC classification number: A21D8/08 ,  C08G77/00 ,  Y10S220/912

公开(公告)号：US2507521A

公开(公告)日：1950-05-16

申请号：US10124349

申请日：1949-06-24

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C08G77/60

CPC classification number: C08G77/60

公开(公告)号：US2507515A

公开(公告)日：1950-05-16

申请号：US7799049

申请日：1949-02-23

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C07F7/08

CPC classification number: C07F7/0809

Abstract: The invention comprises organo silicon compounds of the general formula where each R is a phenyl or methyl radical, and a method of preparing the above compounds by reacting a compound of the general formula R3SiC6H4X with a compound of the general formula R2SiCl2 in the presence of an alkali metal, e.g. sodium, potassium or lithium, where R has the above significance and X is a halogen atom. The compounds may be prepared by condensing the above reactants in a Grignard reaction. In the examples compounds of the general formula where both R radicals are methyl and phenyl radicals and where one R is a methyl and the other a phenyl radical, are prepared.

公开(公告)号：US3355473A

公开(公告)日：1967-11-28

申请号：US60341666

申请日：1966-12-21

Applicant: DOW CORNING

Inventor： CLARK HAROLD A ,  HALUSKA LOREN A

IPC: C07F7/08 ,  C08G18/10 ,  C08G77/00 ,  C08G77/38

CPC classification number: C08G77/38 ,  C07F7/0818 ,  C07F7/0852 ,  C08G18/10 ,  C08G77/00 ,  C08G18/38 ,  C08G18/3893

Abstract: The invention comprises (1) silanes of the formula [(HO)cR]bSiR1a , and (2) siloxanes containing units of the formula with or without other units of the formula wherein each R is a tri- or tetra-valent hydrocarbon or hydrocarbon ether radical and is bonded to the silicon atom via a silicon carbon bond, R1 is monovalent hydrocarbon radical free from aliphatic unsaturation, and each R11 is a monovalent hydrocarbon or halohydrocarbon radical free from aliphatic unsaturation, a and n are 0-3, b is 1 or 2, c is 2 or 3, and all the hydroxyl groups are primary. Typical [(HO)cR] groups are (HOCH2)2CHCH2CH2-, Specified R1 and R11 groups are alkyl, aryl, alkaryl, aralkyl and cycloalkyl, and R11 may in addition be halogenated derivatives of these; many examples are given. The compounds may be prepared by reacting a hydroxy olefinic compound with a silane or siloxane containing silicon-hydrogen bonds in the presence of a platinum catalyst. Many examples are given; in typical Examples (9C) the silane (CH3)2SiH2 is reacted with (HOCH2CH2)3CH=CH2 to give and in (11A) a siloxane comprising the units (CF3CH2CH2)2SiO is prepared. Uses: Curing agents for isocyanate prepolymers, preparing polyurethane rubbers and making varnishes.

公开(公告)号：US3317460A

公开(公告)日：1967-05-02

申请号：US26978163

申请日：1963-04-01

Applicant: DOW CORNING

Inventor： CLARK HAROLD A ,  HALUSKA LOREN A

IPC: C07F7/08 ,  C08G18/10 ,  C08G77/00 ,  C08G77/38

CPC classification number: C08G77/38 ,  C07F7/0818 ,  C07F7/0852 ,  C08G18/10 ,  C08G77/00 ,  C08G18/38 ,  C08G18/3893

公开(公告)号：US2877255A

公开(公告)日：1959-03-10

申请号：US62497656

申请日：1956-11-29

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C07F7/08

CPC classification number: C07F7/0896

公开(公告)号：US2718483A

公开(公告)日：1955-09-20

申请号：US33497153

申请日：1953-02-03

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C08G77/04

CPC classification number: C08G77/04 ,  Y10T442/2992 ,  Y10T442/3472

公开(公告)号：US2507517A

公开(公告)日：1950-05-16

申请号：US8247249

申请日：1949-03-19

Applicant: DOW CORNING

Inventor： CLARK HAROLD A

IPC: C07F7/12 ,  C07F7/18

CPC classification number: C07F7/12 ,  C07F7/182