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1.发明授权Magnesium dichloride-based adducts and catalyst components obtained therefrom 有权二氯化镁基加合物和由此获得的催化剂组分公开(公告)号：US07932206B2
公开(公告)日：2011-04-26
申请号：US10537079
申请日：2003-11-25
CPC分类号： B01J31/0209 , B01J23/02 , B01J31/0202 , B01J31/0204 , B01J31/0208 , B01J31/0212 , B01J31/0237 , B01J31/0274 , B01J31/128 , B01J31/143 , B01J2231/122 , B01J2531/22 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/18
摘要： Solid Lewis adducts comprising MgCl2, a Lewis base (LB) belonging to ethers, esters, ketones, silanes or amines and an alcohol ROH, in which R is a C1-C15 hydrocarbon group optionally substituted with heteroatoms containing groups, which compounds are in molar ratios to each other defined by the following formula MgCl2(ROH)m(LB)n in which m ranges from 0.05 to 6, n ranges from 0.08 to 6. The solid Lewis adducts herein can be used to prepare catalysts having good morphological stability, and high polymerization activity.
摘要翻译： 固体Lewis加合物，其包含MgCl 2，属于醚，酯，酮，硅烷或胺的路易斯碱（LB）和醇ROH，其中R是任选被含杂原子的基团取代的C 1 -C 15烃基，该化合物为摩尔 其中m为0.05至6，n为0.08至6.下列通式MgCl 2（ROH）m（LB）n定义：本文中的固体Lewis加合物可用于制备具有良好形态稳定性的催化剂， 和高聚合活性。
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2.发明申请Magnesium dichloride-based adducts and catalyst components obtained therefrom 有权二氯化镁基加合物和由此获得的催化剂组分公开(公告)号：US20060025300A1
公开(公告)日：2006-02-02
申请号：US10537079
申请日：2003-11-25
CPC分类号： B01J31/0209 , B01J23/02 , B01J31/0202 , B01J31/0204 , B01J31/0208 , B01J31/0212 , B01J31/0237 , B01J31/0274 , B01J31/128 , B01J31/143 , B01J2231/122 , B01J2531/22 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/651 , C08F2500/18
摘要： Solid Lewis adducts comprising MgCl2, a Lewis base (LB) belonging to ethers, esters, ketones, silanes or amines and an alcohol ROH, in which R is a C1-C15 hydrocarbon group optionally substituted with heteroatoms containing groups, which compounds are in molar ratios to each other defined by the following formula MgC12(ROM) m(LB)n in which m ranges from 0.05 to 6, n ranges from 0.08 to 6. These adducts allow to prepare catalysts having a good morphological stability and high polymerization activities.
摘要翻译： 包含MgCl 2 N 2的固体Lewis加合物，属于醚，酯，酮，硅烷或胺的路易斯碱（LB）和醇ROH，其中R是任选被杂原子取代的C 1 -C 15烃基 （ROM）m（LB）n，其中m为0.05-6，n为0.08至6，这些化合物的摩尔比彼此相同。 这些加合物可以制备具有良好形态稳定性和高聚合活性的催化剂。
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3.发明申请Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom 有权二氯化镁 - 乙醇加合物和由其获得的催化剂组分公开(公告)号：US20070260024A1
公开(公告)日：2007-11-08
申请号：US11354273
申请日：2006-02-13
CPC分类号： C08F10/00 , C01F5/30 , C01P2002/72 , C01P2002/74 , C01P2002/88 , C01P2004/32 , C07F3/003 , C08F110/06 , C08F4/651 , C08F4/022 , C08F4/6545 , C08F2500/15 , C08F2500/18
摘要： A MgCl2.mEtOH.nH2O adducts, where 3.4
摘要翻译： 其中3.4
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公开(公告)号：US09598509B2
公开(公告)日：2017-03-21
申请号：US13996629
申请日：2011-12-16
IPC分类号： C08F4/10 , C08F4/58 , C08F4/16 , C08F10/00 , C08F110/06
CPC分类号： C08F4/10 , C08F4/16 , C08F4/58 , C08F10/00 , C08F110/06 , C08F4/6543 , C08F4/022 , C08F2500/15 , C08F2500/24
摘要： A solid adduct comprising magnesium chloride and ethanol in which the moles of ethanol per mole of magnesium chloride range from 2 to 5 and in which the ratio between the average pore radius measured in Angstrom of said adduct, determined by mercury porosity, and the moles of ethanol, is higher than 500.
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5.发明申请Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom 审中-公开二氯化镁 - 乙醇加合物和由其获得的催化剂组分公开(公告)号：US20090099324A1
公开(公告)日：2009-04-16
申请号：US12283798
申请日：2008-09-16
CPC分类号： C08F10/00 , C01F5/30 , C01P2002/72 , C01P2002/74 , C01P2002/88 , C01P2004/32 , C07F3/003 , C08F110/06 , C08F4/651 , C08F4/022 , C08F4/6545 , C08F2500/15 , C08F2500/18
摘要： A MgCl2.mEtOH.nH2O adducts, where 3.4
摘要翻译： 一种MgCl 2·mEtOH·nH 2 O加合物，其中3.4
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6.发明申请MAGNESIUM DICHLORIDE-ETHANOL ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 有权二氯二苯醚 - 乙醇添加剂和催化剂组分公开(公告)号：US20130274428A1
公开(公告)日：2013-10-17
申请号：US13996629
申请日：2011-12-16
CPC分类号： C08F4/10 , C08F4/16 , C08F4/58 , C08F10/00 , C08F110/06 , C08F4/6543 , C08F4/022 , C08F2500/15 , C08F2500/24
摘要： A solid adduct comprising magnesium chloride and ethanol in which the moles of ethanol per mole of magnesium chloride range from 2 to 5 and in which the ratio between the average pore radius measured in Angstrom of said adduct, determined by mercury porosity, and the moles of ethanol, is higher than 500.
摘要翻译： 包含氯化镁和乙醇的固体加合物，其中每摩尔氯化镁的乙醇摩尔数为2至5，其中以汞孔隙度测定的所述加合物的单位埃的平均孔半径之比和由汞孔隙率确定的摩尔数 乙醇，高于500。
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7.发明授权Magnesium dichloride-ethanol adduct and catalyst components obtained therefrom 有权二氯化镁 - 乙醇加合物和由此获得的催化剂组分公开(公告)号：US07087688B2
公开(公告)日：2006-08-08
申请号：US10495940
申请日：2003-08-21
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C01F5/30 , C01P2002/72 , C01P2002/74 , C01P2002/88 , C01P2004/32 , C07F3/003 , C08F110/06 , C08F4/651 , C08F4/022 , C08F4/6545 , C08F2500/15 , C08F2500/18
摘要： A MgCl2·mEtOH·nH2O adducts, where 3.4
摘要翻译： 其中3.4
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8.发明授权Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom 有权二氯化镁 - 乙醇加合物和由其获得的催化剂组分公开(公告)号：US07439313B2
公开(公告)日：2008-10-21
申请号：US11354273
申请日：2006-02-13
IPC分类号： C08F210/00 , C08F4/614
CPC分类号： C08F10/00 , C01F5/30 , C01P2002/72 , C01P2002/74 , C01P2002/88 , C01P2004/32 , C07F3/003 , C08F110/06 , C08F4/651 , C08F4/022 , C08F4/6545 , C08F2500/15 , C08F2500/18
摘要： A MgCl2.mEtOH.nH2O adducts, where 3.4
摘要翻译： 其中3.4
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公开(公告)号：US20120329963A1
公开(公告)日：2012-12-27
申请号：US13582230
申请日：2011-03-01
申请人： Diego Brita , Gianni Collina , Daniele Evangelisti , Benedetta Gaddi , Maria Carbonara , Paolo Vincenzi
发明人： Diego Brita , Gianni Collina , Daniele Evangelisti , Benedetta Gaddi , Maria Carbonara , Paolo Vincenzi
CPC分类号： C08F10/00 , C08F110/02 , C08F4/022 , C08F4/6543 , C08F2500/12 , C08F2500/18 , C08F4/651
摘要： The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.
摘要翻译： 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg，卤素和属于 1,2-二醚作为内电子给体化合物。 本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。
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10.发明申请Magnesium dichloride-water adducts and catalyst components obtained therefrom 审中-公开二氯化镁 - 水加合物和由其获得的催化剂组分公开(公告)号：US20120283402A1
公开(公告)日：2012-11-08
申请号：US13517036
申请日：2010-12-17
申请人： Daniele Evangelisti , Benedetta Gaddi , Diego Brita , Gianni Collina , Anna Fait
发明人： Daniele Evangelisti , Benedetta Gaddi , Diego Brita , Gianni Collina , Anna Fait
CPC分类号： C01F5/30 , C01P2006/14 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/6543 , C08F4/6545 , C08F2500/12 , C08F2500/18 , C08F4/022
摘要： Solid adducts comprising MgCl2 and water and optionally an organic hydroxy compound (A) selected from hydrocarbon structures containing at least one hydroxy group, said compounds being present in molar ratio defined by the following formula MgCl2.(H20)n(A)p in which n is from 0.6 to 6, p ranges from 0 to 3, said adduct having a porosity (PF), measured by the mercury method and due to pores with radius equal to or lower than 1 μm, of at least 0.15 cm3/g with the proviso that when p is 0, (PF) is equal to or higher than 0.3 cm3/g.
摘要翻译： 包含MgCl 2和水以及任选的选自含有至少一个羟基的烃结构的有机羟基化合物（A）的固体加合物，所述化合物以下式MgCl 2（H 2 O）n（A）p定义的摩尔比存在，其中 n为0.6至6，p为0至3，所述加合物具有通过汞法测量的孔隙度（PF），并且由于半径等于或小于1μm的孔隙至少为0.15cm 3 / g， 条件是当p为0时，（PF）等于或高于0.3cm 3 / g。
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