公开(公告)号：US20050224958A1

公开(公告)日：2005-10-13

申请号：US10517669

申请日：2003-06-04

申请人： Dieter Kassel ,  Werner Daub ,  Klaus Dreyer ,  Klaus Rodiger ,  Walter Lengauer ,  Mariann Lovonyak ,  Vera Ucakar

发明人： Dieter Kassel ,  Werner Daub ,  Klaus Dreyer ,  Klaus Rodiger ,  Walter Lengauer ,  Mariann Lovonyak ,  Vera Ucakar

IPC分类号： C04B35/56 ,  B22F3/10 ,  C22C1/05 ,  C22C29/08 ,  C23C30/00 ,  H01L23/043

CPC分类号： C23C30/005 ,  B22F3/1007 ,  B22F3/101 ,  B22F2998/00 ,  B22F2999/00 ,  C22C1/051 ,  C22C29/08 ,  B22F2207/03 ,  B22F2201/02 ,  B22F2201/20 ,  B22F2201/10

摘要： The invention relates to a hard metal substrate body consisting of a WC hard material phase and between 3 and 25 mass % of a binding phase containing at least one binding metal Fe, Co and/or Ni, and up to 15 mass % (in relation to the binding phase) of dissolved dopants from the group containing Al, Cr, Mo, Ti, Zr, Hf, V, Nb, Ta. The invention also relates to a method for producing one such hard metal substrate body, using powder metallurgy followed by sintering. According to the invention, the percentage of all of the dopants in the hard metal is limited to a maximum of 4 mass %, the proportion of cubic phase in the hard metal is less than 4 vol. %, and the binding metal content in an edge region of the hard metal substrate body falls from up to 1 μm, preferably up to 0.5 μm, to less than half the binding agent content inside the substrate body. In order to produce said hard metal substrate body, once the eutectic has been reached and at the latest once the sintering temperature has been reached in the heating phase, the vacuum or inert gas atmosphere is replaced by a N2 atmosphere and maintained at least until the sintering temperature is reached.

摘要翻译： 本发明涉及一种由WC硬质材料相组成的硬质金属基体，和含有至少一种结合金属Fe，Co和/或Ni，至多15质量％（相对关系）的结合相的3〜25质量％ 溶解的掺杂剂由Al，Cr，Mo，Ti，Zr，Hf，V，Nb，Ta组成。 本发明还涉及一种使用粉末冶金烧结之后制造这种硬质金属基体的方法。 根据本发明，硬质合金中所有掺杂剂的百分比限制在最大为4质量％，硬质合金中立方相的比例小于4体积％。 ％，并且硬质金属基体的边缘区域中的结合金属含量从高达1um，优选至多0.5μm下降到小于基体内部的粘合剂含量的一半。 为了生产所述硬质金属基体，一旦达到共晶体并且一旦达到加热阶段的烧结温度，则最终将真空或惰性气体气氛替换为N 2 并保持至少直到达到烧结温度。

公开(公告)号：US07544410B2

公开(公告)日：2009-06-09

申请号：US10572000

申请日：2004-05-14

申请人： Walter Lengauer ,  Vera Ucakar ,  Klaus Dreyer ,  Dieter Kassel ,  Hans Werner Daub

发明人： Walter Lengauer ,  Vera Ucakar ,  Klaus Dreyer ,  Dieter Kassel ,  Hans Werner Daub

IPC分类号： B32B9/00 ,  C22C29/00

CPC分类号： B22F3/101 ,  C21D1/76 ,  C22C1/051 ,  C23C30/005 ,  Y10T428/24975 ,  Y10T428/265

摘要： A hard metal or cermet body has a 2 to 100 μm thick first layer having a binder metal proportion of 2 to 25 mass % and up to 25 volume % of a nitride or carbonitride of one or more metals of Group IVa of the periodic system or up to 10 volume % of a carbide or carbonitride of V, Nb, Ta or Cr, balance WC, whereby the amount of nitride, carbonitride or carbide of the afore-mentioned metals amounts to at least 0.01 volume %. Under the first layer is a 2 to 40 μm thick second layer with an enhanced nitrogen proportion relative to the first layer, is disposed. Thereunder is a transition zone with a thickness of 2 to 100 μm in which the composition gradually changes to a homogeneous composition in the inner core of the hard metal or cermet body.

摘要翻译： 硬金属或金属陶瓷体具有2至100μm厚的第一层，其具有2至25质量％的粘合剂金属比例和至多25体积％的周期性体系的IVa族的一种或多种金属的氮化物或碳氮化物，或 高达10体积％的V，Nb，Ta或Cr的碳化物或碳氮化物，余量为WC，由此上述金属的氮化物，碳氮化物或碳化物的量为至少0.01体积％。 在第一层下面设置相对于第一层具有增强的氮比例的2至40μm厚的第二层。 以下是厚度为2〜100μm的过渡区域，其中组成在硬金属或金属陶瓷体的内核中逐渐变为均匀的组成。

公开(公告)号：US20070042222A1

公开(公告)日：2007-02-22

申请号：US10572000

申请日：2004-05-14

申请人： Walter Lengauer ,  Vera Ucakar ,  Klaus Dreyer ,  Dieter Kassel ,  Hans Daub

发明人： Walter Lengauer ,  Vera Ucakar ,  Klaus Dreyer ,  Dieter Kassel ,  Hans Daub

IPC分类号： C22C29/02 ,  C22C29/16

CPC分类号： B22F3/101 ,  C21D1/76 ,  C22C1/051 ,  C23C30/005 ,  Y10T428/24975 ,  Y10T428/265

摘要： The invention relates to a hard metal or cermet body comprising a single or several adjoining surfaces. A first layer with a thickness of between 2-100 μm is located beneath the single surface or at least one of the surfaces, said layer comprising an auxiliary metal fraction of between 2 and 25 mass % and up to 25 volume % nitrides or carbonitrides of one or more metals of the IVa group of the periodic table and/or up to 10 volume % carbides and/or carbonitrides of the elements V, Nb, Ta and/or Cr, with WC making up the residual amount. A second layer with a thickness of between 2 and 40 μm is located beneath the first layer, said second layer having a higher nitrogen fraction than the first layer and consisting essentially of nitrides and/or carbonitrides of metals of the IVa group of the periodic table, in addition to containing phase fractions of up to 10 volume % of carbides, nitrides, carbonitrides or oxycarbonitrides of the elements W, Mo, V, Ta, Nb, Cr and/or fractions that are dissolved in the hard substance phase amounting to up to 5 mass % V, NB, TA and up to 2 mass % CR, Mo, W and also containing up to 15 mass % binding agents. A transition zone with a thickness of between 2 and 100 μm is located beneath the second layer, the composition changing gradually to a homogeneous composition in the interior core of the hard metal or cermet body in said zone. To produce said sequence of layers, after being subjected to thermal treatment to produce a layer rich in an auxiliary metal, the body is treated in a nitrogen atmosphere under a nitrogen pressure of 5×103 Pa to 107 Pa below the eutectic.

摘要翻译： 本发明涉及包含单个或几个相邻表面的硬金属或金属陶瓷体。 厚度在2-100μm之间的第一层位于单个表面或至少一个表面下方，所述层包含2至25质量％和至多25体积％的氮化物或碳氮化物的辅助金属部分 周期表IVa族的一种或多种金属和/或元素V，Nb，Ta和/或Cr的至多10体积％的碳化物和/或碳氮化物，其中WC占剩余量。 厚度在2至40μm之间的第二层位于第一层下方，所述第二层具有比第一层高的氮分数，并且基本上由周期表IVa族金属的氮化物和/或碳氮化物组成 ，除了含有高达10体积％的元素W，Mo，V，Ta，Nb，Cr和/或溶解在硬质相中的级分的碳化物，氮化物，碳氮化物或碳氮氧化物的相分数达到 至5质量％V，NB，TA和至多2质量％的CR，Mo，W，并且还含有至多15质量％的粘合剂。 厚度在2至100μm之间的过渡区域位于第二层下方，该组合物逐渐变成在所述区域中硬质金属或金属陶瓷体的内核中均匀的组成。 为了产生所述层序，在进行热处理以产生富含辅助金属的层之后，在氮气气氛中在氮气压力为5×10 3 Pa至10℃ > 7 Pa低于共晶。

公开(公告)号：US20050115742A1

公开(公告)日：2005-06-02

申请号：US10509304

申请日：2003-03-21

申请人： Hans Daub ,  Klaus Dreyer ,  Dieter Kassel ,  Walter Lengauer ,  Klaus Rodiger

发明人： Hans Daub ,  Klaus Dreyer ,  Dieter Kassel ,  Walter Lengauer ,  Klaus Rodiger

IPC分类号： B23B27/14 ,  C22C29/00 ,  C22C29/02 ,  E21B10/36

CPC分类号： C22C29/005 ,  B22F2005/001

摘要： The invention relates to a hard metal or cermet cutting material for cutting chromium-alloy steel parts. Said cutting material comprises a hard phase containing carbides, nitrides and/or carbonitrides and a binder phase based on iron, cobalt and nickel. The aim of the invention is to prevent an agglomeration of the cutting material during cutting operations. For this purpose, the binder phase contains 10% by weight to 75% by weight of Co, 10% by weight to 75% by weight of Ni, 5% by weight to 30% by weight of Cr, ≧20% by weight to 60% by weight of Fe, the total of Co, Ni, Cr and Fe not exceeding 100% by weight.

摘要翻译： 本发明涉及用于切割铬合金钢部件的硬金属或金属陶瓷切割材料。 所述切削材料包括含有碳化物，氮化物和/或碳氮化物的硬质相和基于铁，钴和镍的粘结相。 本发明的目的是在切割操作期间防止切割材料的聚集。 为此，粘合剂相包含10重量％至75重量％的Co，10重量％至75重量％的Ni，5重量％至30重量％的Cr，≥20重量％ 至60重量％的Fe，Co，Ni，Cr和Fe的总量不超过100重量％。

公开(公告)号：US6110603A

公开(公告)日：2000-08-29

申请号：US342966

申请日：1999-06-29

申请人： Limin Chen ,  Walter Lengauer ,  Hans Werner Daub ,  Klaus Dreyer ,  Dieter Kassel

发明人： Limin Chen ,  Walter Lengauer ,  Hans Werner Daub ,  Klaus Dreyer ,  Dieter Kassel

IPC分类号： C22C1/05 ,  C22C29/00 ,  C22C29/08 ,  C23C30/00 ,  B32B15/02

CPC分类号： C22C29/00 ,  C22C1/051 ,  C22C29/08 ,  C23C30/005 ,  B22F2999/00 ,  Y10T428/12028 ,  Y10T428/12049 ,  Y10T428/12063 ,  Y10T428/12139

摘要： A hard metal or cermet body, especially as a cutting insert, has a WC content in the hard phase making up at least 10% and at most 96% thereof and three layers or zones between the interior of the body and the surface formed by the heat treatment to which the sinterable body is subjected. In the outermost layer hard material with limited binder content can be formed underlain by an intermediate layer of a substantially pure WC--Co composition, the innermost layer having a tungsten content falling to the value in the body interior and a binder phase and Group IVa and Group Va metal which increased progressively to the levels in the body interior.

摘要翻译： 硬质金属或金属陶瓷体，特别是作为切削刀片，硬质相中的WC含量至少为10％，最多为96％，并且主体内部与由 可烧结体经受的热处理。 在最外层中，具有有限粘合剂含量的硬质材料可以通过基本上纯的WC-Co组合物的中间层形成，最内层具有下降到体内内部的钨含量和粘结相和组IVa和 组Va金属逐渐增加到身体内部的水平。

公开(公告)号：US06506226B1

公开(公告)日：2003-01-14

申请号：US09674739

申请日：2000-11-03

申请人： Limin Chen ,  Walter Lengauer ,  Hans Werner Daub ,  Klaus Dreyer ,  Dieter Kassel ,  José Garcia ,  Georg Korb

发明人： Limin Chen ,  Walter Lengauer ,  Hans Werner Daub ,  Klaus Dreyer ,  Dieter Kassel ,  José Garcia ,  Georg Korb

IPC分类号： B22F312

CPC分类号： C22C1/051 ,  B22F2998/00 ,  B22F2999/00 ,  C22C29/00 ,  C22C29/08 ,  C23C30/005 ,  Y10T428/12028 ,  B22F2207/03 ,  B22F2207/07 ,  B22F3/101 ,  B22F3/1017

摘要： The invention relates to a hard metal or cermet body with a hard material phase consisting of WC and/or at least one carbide, nitride, carbonitride and/or oxicarbonitride of at least one of the elements from group IVa, Va, or VIa of the periodic table and a binding metal phase consisting of Fe, Co and/or Ni, said binding metal phase making up 3 to 25 mass %. In particular, WC crystallites should protrude beyond the hard metal or cermet surface of the by 2 to 20 &mgr;m in order to improve the adhesion of surface layers that are applied.

摘要翻译： 本发明涉及一种具有由WC和/或至少一种碳化物，氮化物，碳氮化物和/或氧化碳氮化物组成的硬质材料相的硬质金属或金属陶瓷体，所述碳化物，氮化物，碳氮化物和/或氧碳氮化物至少一种元素来自IVa，Va或VIa族 周期表和由Fe，Co和/或Ni组成的结合金属相，所述结合金属相构成3〜25质量％。 特别地，WC微晶应突出超过2〜20μm的硬质金属或金属陶瓷表面，以提高所施加的表面层的粘附性。

公开(公告)号：US20060280639A1

公开(公告)日：2006-12-14

申请号：US10557885

申请日：2004-04-29

申请人： Walter Lengauer ,  Klaus Dreyer ,  Klaus Rodiger

发明人： Walter Lengauer ,  Klaus Dreyer ,  Klaus Rodiger

IPC分类号： B22F3/12

CPC分类号： C23C30/005 ,  B22F3/24 ,  B22F2003/241 ,  B22F2998/00 ,  B22F2999/00 ,  C22C1/051 ,  C23C8/36 ,  C22C29/04 ,  C22C29/08 ,  B22F2202/13 ,  B22F2207/03

摘要： The invention relates to a sintered part consisting of a hard metal, in particular WC with Co, Ni and/or Fe binders-based hard metal, or cermet, in particular on the base of composition consisting of (Ti, W) (C, N) or (Ti, Mo) (C, N) with Co, Ni and/or Fe binders and to a method for producing such a sintered part. The inventive method consists in exposing a sintered part totally or partially to an active plasma gaseous phase at a maximum pressure of 3×104 Pa during heating, sintering or after sintering, at least during a certain time preferably during a time period ranging from 10 to 100 min.

摘要翻译： 本发明涉及由硬质金属，特别是WC与Co，Ni和/或Fe基于粘合剂的硬质金属或金属陶瓷组成的烧结部件，特别是由（Ti，W）（C， N）或（Ti，Mo）（C，N）与Co，Ni和/或Fe粘结剂以及制造这种烧结部件的方法。 本发明的方法包括：在加热，烧结或烧结之后，至少在一定时间内，优选在一段时间内将烧结部分全部或部分地暴露于最大压力为3×10 -4 Pa的活性等离子体气相 时间范围为10至100分钟。

公开(公告)号：US5352533A

公开(公告)日：1994-10-04

申请号：US946307

申请日：1992-10-26

申请人： Klaus Dreyer ,  Dieter Kassel ,  Hans Kolaska

发明人： Klaus Dreyer ,  Dieter Kassel ,  Hans Kolaska

IPC分类号： C04B35/10 ,  C04B35/111 ,  C04B35/645 ,  C04B35/80 ,  C04B35/81 ,  B41M5/40

CPC分类号： C04B35/6455 ,  C04B35/111 ,  C04B35/803

摘要： A composite body includes 5 to 40% by mass of SiC whiskers and/or up to 80% by mass SiC lamellae and/or of up to 75% by mass SiC powder, 0.05 to 3% by mass of at least one component selected from the group of Y.sub.2 O.sub.3, SiO.sub.3, MgO, NiO and AlN and/or up to 40% by mass of at least one compound selected from the group of carbides, nitrides or carbonitrides of a metal from one of the Groups IVa, Va, Via of the Periodic Table of elements, and/or up to 40% by mass of at least one oxide of at least one metal selected from the group which consists of the metals of Group IVa of the Periodic Table of elements, 0.05 to 10% by mass of a metal constituent selected from the group which consists of at least one element selected from the group including nickel, cobalt and iron, and of the group which consists of chromium in an amount up to 25% of the mass of the metal constituent with the balance being at least one element selected from the group which consists of nickel, cobalt and iron, and a minimum of 30% by mass Al.sub.2 O.sub.3 to the balance of the body.

摘要翻译： PCT No.PCT / EP91 / 00980 Sec。 371日期：1992年10月26日 102（e）日期1992年10月26日PCT 1991年5月28日PCT PCT。 第WO91 / 18847号公报 日本1991年12月12日。复合体包含5〜40质量％的SiC晶须和/或高达80质量％的SiC薄片和/或高达75质量％的SiC粉末，0.05〜3质量％ 的至少一种选自Y 2 O 3，SiO 3，MgO，NiO和AlN的组分和/或至多40质量％的至少一种选自以下的金属的碳化物，氮化物或碳氮化物的化合物 元素周期表IVa，Va，VIa族和/或至多40质量％的至少一种选自元素周期表第Ⅳa族金属的金属的至少一种金属， ，0.05〜10质量％的选自由选自镍，钴和铁中的至少一种元素组成的组的金属成分，以及由铬组成的基团，其含量高达25％ 金属成分的质量余量为选自镍，钴和铁组成的组中的至少一种元素 ，以及至少30质量％的Al 2 O 3与身体的平衡。

公开(公告)号：US20110150692A1

公开(公告)日：2011-06-23

申请号：US13061593

申请日：2009-07-14

申请人： Klaus Rödiger ,  Hendrikus Van Den Berg ,  Walter Lengauer ,  Klaus Dreyer ,  Dominic Janisch

发明人： Klaus Rödiger ,  Hendrikus Van Den Berg ,  Walter Lengauer ,  Klaus Dreyer ,  Dominic Janisch

IPC分类号： B22F3/12 ,  B22F3/24 ,  B22F1/00

CPC分类号： C22C29/00 ,  C22C1/051

摘要： A cemented carbide body is 1-30% by mass of binder consisting of Co, Co/Ni, Co/Fe, Co/Ni/Fe or Ni/Fe and a hard material having a hexagonal WC phase and having a face-centered cubic phase of the form (M1, M2, M3)C or (M1, M2, M3)(C, N) or (M1, M2, M3)(O, C, N) where M1=Ti and/or Zr and M2=W and M3 optionally means none or one or a plurality of the elements Ta, Nb, Hf, Cr, Mo or V, wherein the proportion of the face-centered cubic phase based on the total mass is 2% to 97%, preferably 5 to 12% by mass, and the microstructure of the hexagonal phase and of the face-centered cubic phase has a mean grain size of between 0.2 μm and 1 μm, preferably ≦0.9 μm, and the mean grain sizes of the hexagonal phase and of the face-centered cubic phase differ at most by 30%.

摘要翻译： 硬质合金体为由Co，Co / Ni，Co / Fe，Co / Ni / Fe或Ni / Fe组成的粘合剂为1-30质量％，硬质合金具有六方晶相WC并具有面心立方 形式（M1，M2，M3）C或（M1，M2，M3）（C，N）或（M1，M2，M3）（O，C，N）的形式（M1，M2，M3）的相位，其中M1 = Ti和/或Zr和M2 = W和M3可选地意味着不含或一个或多个元素Ta，Nb，Hf，Cr，Mo或V，其中基于总质量的面心立方相的比例为2％至97％，优选 5〜12质量％，六方晶相和面心立方相的微观结构的平均粒径为0.2μm〜1μm，优选为nlE;0.9μm，六方相的平均粒径 和面心立方相最多相差30％。

公开(公告)号：US5856032A

公开(公告)日：1999-01-05

申请号：US716340

申请日：1996-09-30

申请人： Hans Werner Daub ,  Klaus Dreyer

发明人： Hans Werner Daub ,  Klaus Dreyer

IPC分类号： B23B27/14 ,  C22C1/05 ,  C22C29/02 ,  C22C29/04 ,  B32B9/00

CPC分类号： C22C29/04 ,  B22F2998/00 ,  Y10T428/265

摘要： A cermet including a cermet core zone in which the content of a binder amounts to at most 90% by mass in relationship to a cermet hard phase is formed with a 0.01 to 3 um deep surface layer having an increased resistance to wear compare to the cermet core zone.

摘要翻译： PCT No.PCT / DE95 / 00434 Sec。 371日期1996年9月30日 102（e）1996年9月30日PCT 1995年3月29日PCT PCT。 WO95 / 30030 PCT出版物 日期：1995年11月9日金属陶瓷包括金属陶瓷核心区，其中粘合剂的含量相对于金属陶瓷硬质相为至多90质量％，形成有0.01〜3μm的表面层，耐蚀性增加 磨损与金属陶瓷核心区域相比。