公开(公告)号：US09598658B2

公开(公告)日：2017-03-21

申请号：US13428919

申请日：2012-03-23

申请人： Eugene Scanlon ,  Kevin DeSantis ,  Virginie Bette ,  Jochen Petzoldt

发明人： Eugene Scanlon ,  Kevin DeSantis ,  Virginie Bette ,  Jochen Petzoldt

IPC分类号： C10M145/14 ,  C10M149/04 ,  C08F220/18 ,  C08F220/14

CPC分类号： C10M145/14 ,  C08F220/14 ,  C08F220/18 ,  C08F2220/1833 ,  C10M149/04 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2270/00

摘要： A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.

公开(公告)号：US20120245068A1

公开(公告)日：2012-09-27

申请号：US13428919

申请日：2012-03-23

申请人： Eugene Scanlon ,  Kevin DeSantis ,  Virginie Bette

发明人： Eugene Scanlon ,  Kevin DeSantis ,  Virginie Bette

IPC分类号： C10M169/04

CPC分类号： C10M145/14 ,  C08F220/14 ,  C08F220/18 ,  C08F2220/1833 ,  C10M149/04 ,  C10M2209/084 ,  C10N2220/021 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2270/00

摘要： A lubricant composition having improved non-Newtonian viscometrics includes at least 85 weight percent of a base oil and 1 to 15 weight percent of a lubricant additive. The additive itself includes 10 to 80 weight percent of a diluent oil and 30 to 80 weight percent of a random co-polymeric viscosity index improver. The viscosity index improver is the free-radical polymerization product of at least 5 to 15 weight percent methyl methacrylate and 5 to 95 weight percent of a C8-C10 alkyl (meth)acrylate. The additive is formed using a method that includes the step of providing the diluent oil, the methyl methacrylate, the C8-C10 alkyl (meth)acrylate, and a free-radical initiator. The method also includes the steps of flowing the diluent oil into a reactor, flowing the methyl methacrylate and the C8-C10 alkyl (meth)acrylate into the reactor independently from the free-radical initiator, and flowing the free-radical initiator into the reactor.

摘要翻译： 具有改进的非牛顿粘度的润滑剂组合物包括至少85重量％的基础油和1至15重量％的润滑剂添加剂。 添加剂本身包含10至80重量％的稀释油和30至80重量％的无规共聚粘度指数改进剂。 粘度指数改进剂是至少5至15重量％甲基丙烯酸甲酯和5至95重量％的（甲基）丙烯酸C 8 -C 10烷基酯的自由基聚合产物。 使用包括提供稀释油，甲基丙烯酸甲酯，（甲基）丙烯酸C 8 -C 10烷基酯和自由基引发剂的步骤的方法形成添加剂。 该方法还包括将稀释油流入反应器中的步骤，将甲基丙烯酸甲酯和（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯独立于自由基引发剂流入反应器，并将自由基引发剂流入反应器 。

公开(公告)号：US20090151235A1

公开(公告)日：2009-06-18

申请号：US12316721

申请日：2008-12-16

申请人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Mock

发明人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Mock

IPC分类号： C10L1/22

CPC分类号： C10L10/14 ,  C10L1/1963 ,  C10L1/1985 ,  C10L1/2364 ,  C10L1/2366 ,  C10L2200/0476 ,  Y02E50/13

摘要： The present invention is directed to the use of alkyl (meth)acrylate polymers or copolymers of the formula (I) In-Poly-(E)y  (I) as cold flow improvers in biodiesel fuel (or bio-fuel) and biodiesel compositions incorporating said polymers or copolymers, obtained by nitroxyl mediated controlled free radical polymerization, wherein In is the initiator fragment starting the polymerization reaction; E is an end group bearing at least one stable free nitroxyl radical, which is bound via an oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; Poly is any polymer or copolymer formed from ethylenically unsaturated monomer(s); and y is a number 1 or greater than 1 indicating the average number of end groups E attached to Poly.

摘要翻译： 本发明涉及（甲基）丙烯酸烷基酯聚合物或式（I）的共聚物的使用<？in-line-formula description =“In-Line Formulas”end =“lead”？> In-Poly-（ 作为生物柴油燃料（或生物燃料）中的冷流改进剂以及包含所述聚合物或共聚物的生物柴油组合物，E（Y）y（I）<？in-line-formula description =“In-line Formulas”end =“tail” 通过硝酰基介导的受控自由基聚合获得，其中In是引发聚合反应的引发剂片段; E是具有至少一个稳定的游离硝酰基的端基，其通过氧原子与聚合物或共聚物结合; 或由所连接的稳定游离硝酰基的取代或消除反应产生的基团; Poly是由烯属不饱和单体形成的任何聚合物或共聚物; y是数字1或大于1，表示连接到Poly的端基E的平均数。

公开(公告)号：US08900333B2

公开(公告)日：2014-12-02

申请号：US12316721

申请日：2008-12-16

申请人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

发明人： Eugene Scanlon ,  Kevin DeSantis ,  Clemens Auschra ,  Andreas Möck

IPC分类号： C10L10/14 ,  C10L1/236 ,  C10L1/198 ,  C10L1/196

CPC分类号： C10L10/14 ,  C10L1/1963 ,  C10L1/1985 ,  C10L1/2364 ,  C10L1/2366 ,  C10L2200/0476 ,  Y02E50/13

摘要： The present invention is directed to the use of alkyl(meth)acrylate polymers or copolymers of the formula (I) In-Poly-(E)y  (I) as cold flow improvers in biodiesel fuel (or bio-fuel) and biodiesel compositions incorporating said polymers or copolymers, obtained by nitroxyl mediated controlled free radical polymerization, wherein In is the initiator fragment starting the polymerization reaction; E is an end group bearing at least one stable free nitroxyl radical, which is bound via an oxygen atom to the polymer or copolymer; or a group which results from a substitution or elimination reaction of the attached stable free nitroxyl radical; Poly is any polymer or copolymer formed from ethylenically unsaturated monomer(s); and y is a number 1 or greater than 1 indicating the average number of end groups E attached to Poly.

摘要翻译： 本发明涉及在生物柴油燃料（或生物燃料）和生物柴油组合物中使用（甲基）丙烯酸烷基酯聚合物或共聚物（I）In-Poly-（E）y（I））作为冷流动改进剂 加入通过硝酰基介导的受控自由基聚合获得的所述聚合物或共聚物，其中In是开始聚合反应的引发剂片段; E是具有至少一个稳定的游离硝酰基的端基，其通过氧原子与聚合物或共聚物结合; 或由所连接的稳定游离硝酰基的取代或消除反应产生的基团; Poly是由烯属不饱和单体形成的任何聚合物或共聚物; y是数字1或大于1，表示连接到Poly的端基E的平均数。