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    Process for the synthesis of DMAPA
    5.
    发明授权
    Process for the synthesis of DMAPA 有权
    合成DMAPA的方法

    公开(公告)号：US07939027B2

    公开(公告)日：2011-05-10

    申请号：US12683015

    申请日：2010-01-06

    申请人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roβ ,  Roland Deeg ,  Johann-Peter Melder

    发明人： Martin Ernst ,  Steffen Oehlenschläger ,  Frank Kuhnke ,  Karl-Heinz Roβ ,  Roland Deeg ,  Johann-Peter Melder

    IPC分类号： B01J10/00 ,  C07C209/00 ,  B01J35/02 ,  B01J19/00 ,  B01J8/00

    CPC分类号： C07C209/48 ,  B01J2219/00006 ,  C07C253/30 ,  C07C211/11 ,  C07C255/24

    摘要： The present invention relates to a process for the industrial preparation of a diamine starting from a corresponding alkenyl nitrile comprising at least one C—C double bond, which comprises the steps (a) reaction of the alkenyl nitrile with a corresponding monoamine in a first reactor so that the monoamine adds exothermically onto the at least one double bond to form an aminoalkyl nitrile, with the monoamine and water being charged initially and the alkenyl nitrile being fed in; (b) evaporation of unreacted alkenyl nitrile and monoamine to increase the concentration of the aminoalkyl nitrile product in the bottoms of the first reactor; (c) transfer of the aminoalkyl nitrile bottom product from step (b) to a second reactor; (d) batchwise catalytic hydrogenation of the aminoalkyl nitrile transferred in step (c) to the diamine in the second reactor, with each batch being obtained by initially charging a catalyst suitable for the hydrogenation of nitriles to amines and also water, the desired diamine and a base, introducing hydrogen into the second reactor and feeding in the aminoalkyl nitrile transferred in step (c); and (e) isolation of the diamine and, if appropriate, repetition of the steps (a) to (e). The invention further relates to an apparatus for preparing these diamines and the use of the apparatuses. A preferred diamine is 3-dimethylaminopropylamine (DMAPA).

    摘要翻译： 本发明涉及从包含至少一个C-C双键的相应链烯基腈开始工业制备二胺的方法，其包括步骤（a）在第一反应器中烯基腈与相应的单胺反应 使得单胺在至少一个双键上放热添加以形成氨基烷基腈，最初加入单胺和水，并加入链烯基腈; （b）蒸发未反应的烯基腈和单胺以增加第一反应器底部氨基烷基腈产物的浓度; （c）将氨基烷基腈底部产物从步骤（b）转移至第二反应器; （d）将步骤（c）中转移的氨基烷基腈分批催化氢化为第二反应器中的二胺，每个批次通过首先将适合于将腈氢化成的催化剂加入到胺中而得到，并且还需要水，所需的二胺和 碱，将氢气引入第二反应器并进料步骤（c）中转移的氨基烷基腈; 和（e）分离二胺，如果合适，重复步骤（a）至（e）。 本发明还涉及一种用于制备这些二胺的装置和该装置的用途。 优选的二胺是3-二甲基氨基丙胺（DMAPA）。

    PROCESS AND DEVICE FOR THE OXIDATION OF ORGANIC COMPOUNDS
    6.
    发明申请
    PROCESS AND DEVICE FOR THE OXIDATION OF ORGANIC COMPOUNDS 有权
    有机化合物氧化的方法和装置

    公开(公告)号：US20110087038A1

    公开(公告)日：2011-04-14

    申请号：US12674058

    申请日：2008-08-01

    申请人： Joaquim H Teles ,  Kai Gumlich ,  Jochen Schäfer ,  Steffen Oehlenschläger ,  Stephan Lamm ,  Roland Merten ,  Martin Schäfer ,  Rüdiger Grob ,  Uwe Emnet

    发明人： Joaquim H Teles ,  Kai Gumlich ,  Jochen Schäfer ,  Steffen Oehlenschläger ,  Stephan Lamm ,  Roland Merten ,  Martin Schäfer ,  Rüdiger Grob ,  Uwe Emnet

    IPC分类号： C07C51/235 ,  B01J19/00

    CPC分类号： C07C51/235 ,  C07C53/124 ,  C07C53/128 ,  C07C53/122 ,  C07C53/126

    摘要： The invention relates to a process for the oxidation of organic compounds by means of oxygen, in which, in a first step, the organic compound and at least part of the oxygen required for the oxidation are introduced into a first reaction zone which is operated isothermally and with backmixing and, in a second step, the reaction mixture from the first reaction zone is introduced into a second reaction zone which is operated adiabatically. The invention further relates to a reactor for carrying out the process, which comprises at least one isothermal reaction zone (3, 5) and an adiabatic reaction zone (7) which are arranged in a reactor shell (8), with each isothermal reaction zone (3, 5) being configured in the form of a jet loop reactor and the adiabatic reaction zone (7) being configured as a bubble column.

    摘要翻译： 本发明涉及通过氧气氧化有机化合物的方法，其中在第一步骤中，将有机化合物和氧化所需的至少一部分氧气引入到等温运行的第一反应区中 并且通过回混，并且在第二步中将来自第一反应区的反应混合物引入绝热操作的第二反应区。 本发明还涉及一种用于进行该方法的反应器，该反应器包括布置在反应器壳体（8）中的至少一个等温反应区（3,5）和绝热反应区（7），每个等温反应区 （3,5）被配置为喷射回路反应器的形式，并且绝热反应区（7）被配置为气泡塔。

    Process and device for the oxidation of organic compounds
    7.
    发明授权
    Process and device for the oxidation of organic compounds 有权
    用于氧化有机化合物的方法和装置

    公开(公告)号：US08575379B2

    公开(公告)日：2013-11-05

    申请号：US12674058

    申请日：2008-08-01

    申请人： Joaquim Henrique Teles ,  Kai Gumlich ,  Jochen Schäfer ,  Steffen Oehlenschläger ,  Stephan Lamm ,  Roland Merten ,  Martin Schäfer ,  Rüdiger Grob ,  Uwe Emnet

    发明人： Joaquim Henrique Teles ,  Kai Gumlich ,  Jochen Schäfer ,  Steffen Oehlenschläger ,  Stephan Lamm ,  Roland Merten ,  Martin Schäfer ,  Rüdiger Grob ,  Uwe Emnet

    IPC分类号： C07C51/16 ,  B01J10/00

    CPC分类号： C07C51/235 ,  C07C53/124 ,  C07C53/128 ,  C07C53/122 ,  C07C53/126

    摘要： The invention relates to a process for the oxidation of organic compounds by means of oxygen, in which, in a first step, the organic compound and at least part of the oxygen required for the oxidation are introduced into a first reaction zone which is operated isothermally and with backmixing and, in a second step, the reaction mixture from the first reaction zone is introduced into a second reaction zone which is operated adiabatically. The invention further relates to a reactor for carrying out the process, which comprises at least one isothermal reaction zone (3, 5) and an adiabatic reaction zone (7) which are arranged in a reactor shell (8), with each isothermal reaction zone (3, 5) being configured in the form of a jet loop reactor and the adiabatic reaction zone (7) being configured as a bubble column.

    摘要翻译： 本发明涉及通过氧气氧化有机化合物的方法，其中在第一步骤中，将有机化合物和氧化所需的至少一部分氧气引入到等温运行的第一反应区中 并且通过回混，并且在第二步中将来自第一反应区的反应混合物引入绝热操作的第二反应区。 本发明还涉及一种用于进行该方法的反应器，该反应器包括布置在反应器壳体（8）中的至少一个等温反应区（3,5）和绝热反应区（7），每个等温反应区 （3,5）被配置为喷射回路反应器的形式，并且绝热反应区（7）被配置为气泡塔。