公开(公告)号：US20140288344A1

公开(公告)日：2014-09-25

申请号：US14219058

申请日：2014-03-19

Applicant: IFP ENERGIES NOUVELLES

Inventor： Filipe Manuel MARQUES MOTA ,  Christophe BOUCHY ,  Pascal DUCHENE ,  Johan MARTENS

IPC: C07C5/22

CPC classification number: C07C5/222 ,  B01J21/12 ,  B01J23/42 ,  B01J29/74 ,  B01J35/002 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0036 ,  B01J37/0201 ,  C07C5/2775 ,  C07C5/2791 ,  C07C2529/74 ,  C10G45/64 ,  C10G2300/1011 ,  Y02P30/20 ,  C07C9/22

Abstract: The invention concerns a process for the conversion of a paraffinic feed produced from renewable resources, to the exclusion of paraffinic feeds obtained by a process employing a step for upgrading by the Fischer-Tropsch pathway, said process employing a catalyst comprising at least one hydrodehydrogenating metal, used alone or as a mixture, and a support comprising at least one Nu-10 zeolite and at least one silica-alumina, said process being carried out at a temperature in the range 150° C. to 500° C., at a pressure in the range 0.1 MPa to 15 MPa, at an hourly space velocity in the range 0.1 to 10 h−1 and in the presence of a total quantity of hydrogen mixed with the feed such that the hydrogen/feed ratio is in the range 70 to 2000 Nm3/m3 of feed.

Abstract translation: 本发明涉及将由可再生资源产生的链烷烃进料转化为排除通过采用通过费 - 托途径升级的方法获得的石蜡饲料的方法，所述方法采用包含至少一种氢化氢化金属的催化剂 ，单独使用或作为混合物使用，和包含至少一种Nu-10沸石和至少一种二氧化硅 - 氧化铝的载体，所述方法在150℃至500℃的温度下进行，在 压力范围为0.1MPa至15MPa，时间间隔为0.1至10h-1，在与进料混合的氢气总量存在下，氢/进料比在70° 至2000 Nm3 / m3饲料。

公开(公告)号：US20130270154A1

公开(公告)日：2013-10-17

申请号：US13860850

申请日：2013-04-11

Applicant: ENI S.P.A. ,  IFP ENERGIES NOUVELLES

Inventor： Aline GREZAUD ,  Jean Philippe HERAUD ,  Hugues DULOT ,  Christophe BOUCHY ,  Vincenzo CALEMMA

IPC: C10G65/12

CPC classification number: C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J23/75 ,  B01J23/755 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J35/0026 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0201 ,  C07C1/0495 ,  C07C1/12 ,  Y02P20/52 ,  C07C9/04

Abstract: A method for producing middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds, including: a) a step of bringing the feedstock into contact with a hydrotreating catalyst allowing the methanation of the CO and CO2 contained in the feedstock or originating from the decomposition of the oxygenated compounds present in the feedstock, b) a step of hydroisomerization/hydrocracking of at least a part of the liquid and gaseous effluent originating from step a), in the presence of a hydroisomerization/hydrocracking catalyst, c) a step of gas/liquid separation of the effluent originating from step b) into a gaseous fraction comprising predominantly hydrogen and a hydroisomerized/hydrocracked liquid fraction, d) a step of fractionation of the liquid fraction separated in step c) to obtain at least one fraction of middle distillate, in which the hydrogen in step a) is obtained from the gaseous fraction separated in step c).

Abstract translation: 由费 - 托合成生产并含有氧化化合物的原料生产中间馏分的方法，包括：a）使原料与加氢处理催化剂接触的步骤，允许原料中所含的CO和CO 2的甲烷化或起始 来自原料中存在的含氧化合物的分解，b）在加氢异构化/加氢裂化催化剂存在下，来自步骤a）的至少一部分液体和气态流出物的加氢异构化/加氢裂化步骤，c） 将来自步骤b）的流出物气/液分离成主要包含氢气和加氢异构化/加氢裂化的液体馏分的气体馏分的步骤，d）在步骤c）中分离的液体馏分的分级步骤，以获得至少一个馏分 的中间馏分，其中步骤a）中的氢气是从步骤c）中分离的气体馏分得到的。

公开(公告)号：US20200024530A1

公开(公告)日：2020-01-23

申请号：US16513819

申请日：2019-07-17

Applicant: IFP Energies Nouvelles

Inventor： Jean-Philippe HERAUD ,  Christophe BOUCHY

IPC: C10G67/00 ,  B01J29/74 ,  B01J21/04 ,  B01J37/00 ,  B01J37/30 ,  B01J37/08 ,  B01J37/02

Abstract: A process is described for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis and divided into a light fraction (cold condensate) and a heavy fraction (waxes). The process involves fractionation of the waxes to obtain a light fraction, the final boiling point of which is between 350° C. and 400° C., and a heavy fraction which boils above the light fraction. The light fraction is mixed with at least one portion of the cold condensate. The resultant mixture is hydrotreated in the presence of a hydrotreatment catalyst of at least one portion of the resultant effluent is hydroisomerized in the presence of a catalyst comprising at least one noble metal from Group VIII and at least one zeolite IZM-2. At least one portion of the heavy fraction is subjected to hydrocracking and hydroisomerization in the presence of a hydrocracking catalyst. The resultant effluents are fractionated to obtain at least one middle distillates fraction.

公开(公告)号：US20130105358A1

公开(公告)日：2013-05-02

申请号：US13661183

申请日：2012-10-26

Applicant: ENI S.P.A ,  IFP Energies Nouvelles

Inventor： Christophe BOUCHY ,  Aline GREZAUD ,  Jean Philippe HERAUD ,  Hugues DULOT ,  Vincenzo CALEMMA

IPC: C10G65/12

CPC classification number: C10G65/12 ,  B01J21/12 ,  B01J23/42 ,  B01J23/44 ,  B01J35/0066 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0009 ,  C10G65/043 ,  C10G2300/1022 ,  C10G2300/1081 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08

Abstract: The present invention relates to a process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising a limited content of molecules containing at least one oxygen atom in which said feedstock is subjected to at least one hydrocracking/hydroisomerization stage in the presence of a hydrogen stream also containing a limited atomic oxygen content.

Abstract translation: 本发明涉及由费 - 托合成生产的石蜡原料生产中间馏分的方法，包括含有至少一个氧原子的有限含量的分子，其中所述原料经受至少一个加氢裂化/加氢异构化步骤 存在还含有有限原子氧含量的氢气流。

公开(公告)号：US20250034065A1

公开(公告)日：2025-01-30

申请号：US18716743

申请日：2022-11-26

Applicant: IFP ENERGIES NOUVELLES

Inventor： Christophe BOUCHY ,  Vincent COUPARD ,  Alexandre PAGOT ,  Thi Bich Ngoc DANG

IPC: C07C5/27

Abstract: The present invention relates to a process and a device for the conversion of aromatic compounds, in which the aromatic compounds of a hydrocarbon feedstock (1) comprising aromatic compounds containing 9 carbon atoms are isomerized in an isomerization unit (A) in the presence of a bifunctional isomerization catalyst having a hydro/dehydrogenating function and a hydroisomerizing function, to produce an isomerization effluent (10) enriched in trimethylbenzenes. The present invention also relates to a process and a device for the production of aromatic compounds, comprising the process and the device for the conversion of aromatic compounds.

公开(公告)号：US20240240108A1

公开(公告)日：2024-07-18

申请号：US18558622

申请日：2022-04-15

Applicant: IFP Energies nouvelles

Inventor： Christophe BOUCHY ,  Anne-Sophie GAY ,  Mélanie GOMEZ ALMENDROS

IPC: C11C3/12 ,  B01D3/14 ,  B01J21/12 ,  B01J23/888 ,  B01J37/02 ,  B01J37/08 ,  B01J37/20

CPC classification number: C11C3/126 ,  B01D3/14 ,  B01J21/12 ,  B01J23/888 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/20 ,  C11C3/123

Abstract: The present invention describes a process for treating a feedstock obtained from a renewable source, comprising a step a) of hydrotreating said feedstock, a step b) of separation into at least a light fraction and at least a hydrocarbon liquid effluent, a step c) of removing at least a portion of the water from the hydrocarbon liquid effluent, a step d) of hydroconversion of at least a portion of the hydrocarbon liquid effluent, said hydroconversion step d) being characterized firstly by the use of a bifunctional catalyst comprising a molybdenum and/or tungsten sulfide phase promoted with nickel and/or cobalt and secondly by a ratio between the partial pressure of hydrogen sulfide and of hydrogen at the inlet of the hydroconversion unit of 10 less than 5×10−5 and a step e) of fractionation of the effluent obtained from step d) to obtain at least a middle distillate fraction.

公开(公告)号：US20230019569A1

公开(公告)日：2023-01-19

申请号：US17785197

申请日：2020-12-09

Applicant: IFP Energies Nouvelles

Inventor： Christophe BOUCHY

IPC: C10G45/64 ,  B01J29/74 ,  B01J35/10

Abstract: Process for isomerization of paraffinic feedstocks operating at a temperature of between 200° C. and 500° C., at a total pressure of between 0.45 MPa and 7 MPa, at a partial pressure of hydrogen of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kg of feedstock introduced per kg of catalyst and per hour, using a catalyst having at least one group VIII metal, at least one matrix and at least one IZM-2 zeolite, the total weight content of alkali metal and/or alkaline-earth metal elements is less than 200 ppm by weight relative to the total mass of said catalyst.

公开(公告)号：US20190382323A1

公开(公告)日：2019-12-19

申请号：US16440272

申请日：2019-06-13

Applicant: IFP Energies nouvelles

Inventor： Christophe BOUCHY

IPC: C07C5/27 ,  C10G45/64 ,  B01J29/74

Abstract: The present invention describes a process for the isomerization of paraffinic feedstocks operating at a temperature of between 200° C. and 500° C., at a total pressure of between 0.45 MPa and 7 MPa, at a hydrogen partial pressure of between 0.3 and 5.5 MPa, at an hourly space velocity of between 0.1 and 10 kilograms of feedstock introduced per kilogram of catalyst and per hour and using a catalyst comprising at least one metal of group VIII of the periodic table of elements, at least one matrix and at least one zeolite IZM-2, in which the ratio between the number of moles of silicon and the number of moles of aluminium of the zeolite IZM-2 network is between 25 and 55, preferably between 25 and 50, and preferably between 30 and 50.

公开(公告)号：US20230008326A1

公开(公告)日：2023-01-12

申请号：US17783734

申请日：2020-12-09

Applicant: IFP Energies Nouvelles

Inventor： Christophe BOUCHY

IPC: B01J29/74 ,  B01J21/04 ,  C07C5/27

Abstract: A catalyst containing a IZM-2 zeolite and a specific content of alkali metal or alkaline-earth metal compounds, and a process for the isomerization of an aromatic C8 cut using the catalyst.

公开(公告)号：US20160184809A1

公开(公告)日：2016-06-30

申请号：US14909637

申请日：2014-06-30

Applicant: IFP ENERGIES NOUVELLES

Inventor： Matthieu LAGAUCHE ,  Laure BRANDHORST ,  Christophe BOUCHY

IPC: B01J29/74 ,  C07C5/27 ,  B01J37/00

Abstract: A process is described for preparing a catalyst comprising at least one zeolite with a modified EUO structure type, at least one matrix and at least one metal from group VIII of the periodic classification of the elements. Said catalyst is used in a process for the isomerization of an aromatic feed comprising at least one compound containing eight carbon atoms per molecule.

Abstract translation: 描述了一种制备催化剂的方法，该催化剂包含至少一种具有改性的EUO结构类型的沸石，至少一种基质和至少一种元素周期分类的VIII族金属。 所述催化剂用于包含至少一种每分子含有8个碳原子的化合物的芳族原料异构化的方法。