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    Mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives
    8.
    发明授权
    Mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives 失效
    巯基取代的羟乙基 - （三唑-1-基）衍生物

    公开(公告)号：US4898875A

    公开(公告)日：1990-02-06

    申请号：US91557

    申请日：1987-08-31

    申请人： Karl H. Buchel ,  Graham Holmwood ,  Udo Kraatz ,  Wolfgang Kramer ,  Paul Reinecke ,  Wilhelm Brandes ,  Wilhelm Stendel

    发明人： Karl H. Buchel ,  Graham Holmwood ,  Udo Kraatz ,  Wolfgang Kramer ,  Paul Reinecke ,  Wilhelm Brandes ,  Wilhelm Stendel

    IPC分类号： A01N43/653 ,  C07D249/08 ,  C07D521/00

    CPC分类号： C07D231/12 ,  A01N43/653 ,  C07D233/56 ,  C07D249/08

    摘要： Novel mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives of the formula ##STR1## in which Ar represents optionally substituted aryl,X represents oxygen, sulphur, a direct bond or the groupings --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --, --O--CH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 --, and --S--CH.sub.2 --CH.sub.2 --, the hetero atom being bonded to the aryl radical if X represents --OCH.sub.2 --, --SCH.sub.2 --, --O--CH.sub.2 --CH.sub.2 -- or --S--CH.sub.2 --CH.sub.2 -- andR represents hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aralkyl or optionally substituted phenyl, and their acid addition salts and metal salt complexes are very effective as fungicides and parasiticides. Novel oxiranes of the formula ##STR2## in which Ar and X have the above-mentioned meaning, and their use as intermediates for the synthesis of the mercapto-substituted hydroxyethyl-(triazol-l-yl) derivatives.

    摘要翻译： 式（I）的新型巯基取代的羟乙基 - （三唑-1-基）衍生物，其中Ar表示任选取代的芳基，X表示氧，硫，直接键或-CH 2 - ， - CH2-，-O-CH2-，-SCH2-，-O-CH2-CH2-和-S-CH2-CH2-，如果X表示-OCH2-，-SCH2-，则杂原子键合到芳基上， -O-CH 2 -CH 2 - 或-S-CH 2 -CH 2 - ，R表示氢，任选取代的烷基，任选取代的烯基，任选取代的炔基，任选取代的环烷基，任选取代的环烷基烷基，任选取代的芳烷基或任选取代的苯基， 酸加成盐和金属盐络合物作为杀真菌剂和杀寄生物剂是非常有效的。 其中Ar和X具有上述含义的式“IMAGE”的新型环氧乙烷及其作为合成巯基取代的羟乙基 - （三唑-1-基）衍生物的中间体的用途。

    1-hydroxyethyl-azole compounds and agricultural compositions
    10.
    发明授权
    1-hydroxyethyl-azole compounds and agricultural compositions 失效
    1-羟乙基 - 唑类化合物和农业组合物

    公开(公告)号：US4871390A

    公开(公告)日：1989-10-03

    申请号：US732193

    申请日：1985-05-08

    申请人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    发明人： Graham Holmwood ,  Karl H. Buchel ,  Klaus Lurssen ,  Paul-Ernst Frohberger ,  Wilhelm Brandes

    IPC分类号： A01N20060101 ,  A01N43/20 ,  A01N43/50 ,  A01N43/64 ,  A01N43/653 ,  C07D20060101 ,  C07D233/60 ,  C07D249/08 ,  C07D301/00 ,  C07D301/02 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/20 ,  C07D303/22 ,  C07D521/00

    CPC分类号： A01N43/50 ,  A01N43/653 ,  C07D231/12 ,  C07D233/56 ,  C07D249/08 ,  C07D303/02 ,  C07D303/04 ,  C07D303/08 ,  C07D303/22

    摘要： A 1-Hydroxyethyl-azole compound of the formula ##STR1## wherein R is an alkyl radical with 1 to 4 carbon atoms; a cycloalkyl radical which has 3 to 7 carbon atoms and is optionally substituted by alkyl with 1 or 2 carbon atoms or a phenyl radical which is optionally substituted by halogen, alkyl with 1 to 4 carbon atoms or haloalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms; or else is phenyl which is optionally mono- or di-substituted by identical or different substituents selected form fluorine, chlorine, methyl and trifluoromethylX is --CH--;Y is a grouping --OCH.sub.2 --;Z is a halogen atom an alkyl radical with 1 to 4 carbon atoms; a cycloalkyl radical with 5 to 7 carbon atoms, an alkoxy radical with 1 to 4 carbon atoms, an alkylthio radical with 1 to 4 carbon atoms, a haloalkyl radical 1 or 2 carbon atoms and 1 to 5 halogen atoms, a haloalkoxy radical with 1 or 2 carbon atoms and 1 to 5 halogen atoms, a haloalkylthio radical with 1 or 2 carbon atoms and 1 to 5 halogen atoms, a phenyl radical which is optionally substituted by halogen or alkyl with 1 to 4 carbon atoms, a phenoxy radical which is optionally substituted by halogen or alkyl with 1 to 4 carbon atoms, a phenylalkyl radical which has 1 or 2 carbon atoms in the alkyl part and is optionally substituted by halogen or alkyl with 1 to 4 carbon atoms, or a phenylalkoxy radical which has 1 or 2 carbon atoms in the alkoxy part and is optionally substituted by halogen or alkyl with 1 to 4 carbon atoms; andm is 0, 1, 2 or 3and physiologically acceptable acid addition salts thereof or metal salt complexes thereof. Such compound being useful as a plant growth regulant and a fungicide.

    摘要翻译： 式（I）的1-羟基乙基 - 唑化合物，其中R是具有1至4个碳原子的烷基; 具有3至7个碳原子并且任选被具有1或2个碳原子的烷基取代的环烷基或任选被卤素取代的苯基，具有1至4个碳原子的烷基或具有1或2个碳原子的卤代烷基和1 至5个卤素原子; 或者是任选地被选自氟，氯，甲基和三氟甲基的相同或不同取代基单取代或二取代的苯基，是-CH-; Y是一个分组-OCH2-; Z是卤原子，具有1至4个碳原子的烷基; 具有5至7个碳原子的环烷基，具有1至4个碳原子的烷氧基，具有1至4个碳原子的烷硫基，1或2个碳原子的卤代烷基，1至5个卤原子，卤代烷氧基与1 或2个碳原子和1至5个卤素原子，具有1或2个碳原子和1至5个卤素原子的卤代烷硫基，任选被卤素或具有1至4个碳原子的烷基取代的苯基，苯氧基是 任选地被卤素或具有1至4个碳原子的烷基取代，在烷基部分中具有1或2个碳原子并且任选被卤素或具有1至4个碳原子的烷基取代的苯基烷基或具有1或4个碳原子的苯基烷氧基， 烷氧基部分中的2个碳原子，任选被卤素或具有1至4个碳原子的烷基取代; 和m为0,1,2或3及其生理学上可接受的酸加成盐或其金属盐络合物。 这种化合物可用作植物生长调节剂和杀真菌剂。