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    Perfluoroaliphatic substituted amine mixtures and the method for preparing the same
    1.
    发明授权
    Perfluoroaliphatic substituted amine mixtures and the method for preparing the same 失效
    全氟脂肪族取代胺混合物及其制备方法

    公开(公告)号：US4059629A

    公开(公告)日：1977-11-22

    申请号：US593173

    申请日：1975-07-03

    申请人： Louis Foulletier ,  Jean-Pierre Lalu

    发明人： Louis Foulletier ,  Jean-Pierre Lalu

    IPC分类号： C07B61/00 ,  C07C215/08 ,  C07C215/24 ,  C07C233/02 ,  C07C233/12 ,  C07F7/12 ,  C08F20/56 ,  C10M169/00 ,  D06M13/322 ,  D06M13/33 ,  D06M13/408 ,  D06M15/277 ,  D06M15/295 ,  C07C87/127 ,  C07C87/22 ,  C07C87/26 ,  C07C87/32

    CPC分类号： D06M15/295 ,  C07B61/00 ,  C07C215/08 ,  C07C215/24 ,  C07C233/02 ,  C07C233/12 ,  C07F7/12 ,  C08F20/56 ,  C10M1/08 ,  C10M169/00 ,  D06M13/322 ,  D06M13/33 ,  D06M13/408 ,  D06M15/277 ,  C10M2215/04 ,  C10M2215/044 ,  C10M2215/06 ,  C10M2215/26

    摘要： The invention comprises perfluoroalkyl substituted amines of the formula ##STR1## wherein n is an integer from 1 to about 20, m is an integer between 2 or 4, R.sup.1 and R.sup.2 each is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms and R.sup.3 and R.sup.4 each is a hydrogen atom, an alkyl containing 1 to 20 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloparaffin radical containing 3 to 12 carbon atoms, a cycloalkenyl radical containing 5 to 12 carbon atoms, and N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, or an aryl, or R.sup.3 or R.sup.4 are joined in the form of an alkylene radical of the formula--(CHR).sub.p --wherein p is an integer from 2 to 6 and R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms. These compounds are prepared by reacting at a temperature in the range between 0.degree. to 200.degree. C. perfluoroalkyl halides of the formulaC.sub.n F.sub.2n+1 (CR.sup.1 R.sup.2).sub.m Y (II)wherein n, m, R.sup.1 and R.sup.2 each has the same meaning as defined hereinabove and Y is an iodine or a bromine atom with amines of the formula ##STR2## wherein R.sup.3 and R.sup.4 have the same meaning as previously stated. The invention also comprises perfluoroalkyl substituted amines of the formula ##STR3## and mixtures of products of formula IV with ##STR4## in which R.sup.1, R.sup.3 and R.sup.4 have the same meaning as designated above and where n is an integer from 4 to 20.The process for producing the products of formulas IV and V and mixtures thereof is the same as that used for the products of the compounds of formula I except that in the starting compounds of formula II at least one of the radicals R.sup.1 or R.sup.2 is hydrogen, m is equal to 2 and n is an integer between 4 and 20.

    摘要翻译： 本发明包括式（I）的全氟烷基取代的胺，其中n为1至约20的整数，m为2或4之间的整数，R 1和R 2各自为氢原子或含有1至 3个碳原子，R 3和R 4各自为氢原子，含有1至20个碳原子的烷基，含有3至10个碳原子的烯基，含有3至12个碳原子的环烷基，含有5至12个碳原子的环烯基 ，并且含有5至12个碳原子的N或O环取代的环烯基或芳基或R 3或R 4以式 - （CHR）p - 亚烷基的亚烷基的形式连接在一起，从2到 6 AND R是氢原子或含有1至3个碳原子的低级烷基。 这些化合物通过在0℃至200℃范围内的温度下反应制备，式C n F 2n + 1（CR 1 R 2）m Y（II）的全氟烷基卤化物，其中n，m，R 1和R 2各自具有与所定义相同的含义 并且Y是碘或溴原子与式（III）的胺，其中R3和R4具有与前述相同的含义。

    Polyfluorinated sulphonic acids and their derivatives
    2.
    发明授权
    Polyfluorinated sulphonic acids and their derivatives 失效
    多氟磺酸及其衍生物

    公开(公告)号：US4610829A

    公开(公告)日：1986-09-09

    申请号：US966508

    申请日：1978-12-04

    申请人： Jean-Pierre Lalu ,  Louis Foulletier

    发明人： Jean-Pierre Lalu ,  Louis Foulletier

    IPC分类号： C07B45/02 ,  C07C309/06 ,  C11D1/00 ,  C23F11/16 ,  C07C143/70

    CPC分类号： C07C309/06 ,  C07B45/02 ,  C11D1/004 ,  C23F11/16 ,  Y10S516/03

    摘要： New products and compositions of matter complying with the general formula:[C.sub.n F.sub.2n+1 --CH.sub.2 --.sub.b SO.sub.2 --Z].sub.d Mwherein: C.sub.n F.sub.2n+1 represents a straight or ramified branched perfluorinated chain: n represents a whole number between 1 and 20, b is a whole number between 2 and 20, preferably equal to 2 or 4, Z represents a chlorine, bromine or an oxygen atom (when Z is a chlorine or a bromine atom, M is nothing and d is equal to 1), when Z is an oxygen atom: M is a hydrogen atom in which case, d is equal to 1, M is a metal of the Groups I.sub.A, II.sub.A, I.sub.B, II.sub.B, VIII of the periodic table, the ammonium radical, the aluminum or the lead radical, and in which case d represents the valence of this metal and methods for preparing new products as illustrated by the following representative reactions.

    摘要翻译： 新产品和符合以下通式的物质组成：[CnF2n + 1-CH2-bSO2-Z] dM其中：CnF2n + 1表示直链或支链支化全氟链：n表示1〜20的整数，b表示 2〜20的整数，优选2或4，Z表示氯，溴或氧原子（当Z为氯或溴原子时，M为无，d为1），当Z为 氧原子：M是氢原子，在这种情况下，d等于1，M是元素周期表中IA，IIA，IB，IIB，VIII族的金属，铵基，铝或铅自由基 ，并且在这种情况下，d表示该金属的化合价和制备新产品的方法，如以下代表性反应所示。

    Perfluoroalkylene quaternary heterocyclic nitrogen salts
    5.
    发明授权
    Perfluoroalkylene quaternary heterocyclic nitrogen salts 失效
    全氟亚烷基季铵杂环氮盐

    公开(公告)号：US4062849A

    公开(公告)日：1977-12-13

    申请号：US696727

    申请日：1976-06-16

    申请人： Louis Foulletier ,  Jean-Pierre Lalu

    发明人： Louis Foulletier ,  Jean-Pierre Lalu

    IPC分类号： C07D215/10 ,  C07D217/10 ,  C07D219/02 ,  C07D219/00

    CPC分类号： C07D217/10 ,  C07D215/10 ,  C07D219/02

    摘要： New compositions having the following general formula: ##STR1## in which A. C.sub.n F.sub.2n+1 represents a straight or branched perfluorinated chain with n being 1 and 20.B. X.sup.- is an anion such as a halogen, a sulfate, an alkyl sulfate.Of these anions the preferred ones are halogens such as the fluoride, chloride, bromide and iodide, or sulfates such asCH.sub.3 SO.sub.4.sup.-,c. R', R" and R'" correspond to the following definitions:1. R' is an alkyl radical containing from 1 to 8 atoms of carbons, in which eventI. R" and R'" can be either the same as R' or different, namely, alkyl radicals containing from 1 to 8 atoms of carbon. R" and R'" can also be cycloalkyl radicals containing from 5 to 10 carbon atoms or alkenyl radicals containing from about 3 to 8 atoms of carbon, or cycloalkenyl radicals containing from 5 to 9 atoms of carbon, or ayrl radicals.Ii. R" and R'" together make up a divalent radical linked to the nitrogen by two simple bonds such as cycloalkyl radicals containing from 4 to 9 carbon atoms, cycloalkenyl radicals containing 4 to 9 carbons, or cyclodienic radicals containing from 4 to 9 carbons.2. R', R" and R'" make up together the remainder of an aromatic tertiary amine derived from the pyridine containing from 5 to 18 carbons. Of these aromatic tertiary amine remainders, the preferred ones are C.sub.5 H.sub.5 (pyridine), C.sub.6 H.sub.8 (the picolines), C.sub.9 H.sub.7 (quinoline and isoquinoline), and C.sub.13 H.sub.9 (acridine).

    摘要翻译： 具有以下通式的新组合物：其中A.CnF2n + 1表示直链或支链全氟链，其中n为1和20。

    Mixtures of perfluoroaliphatic substituted amino compounds and the method for preparing the same
    6.
    发明授权
    Mixtures of perfluoroaliphatic substituted amino compounds and the method for preparing the same 失效
    全氟脂肪族取代氨基化合物的混合物及其制备方法

    公开(公告)号：US3997604A

    公开(公告)日：1976-12-14

    申请号：US138810

    申请日：1971-04-29

    申请人： Louis Foulletier ,  Jean-Pierre Lalu

    发明人： Louis Foulletier ,  Jean-Pierre Lalu

    IPC分类号： C07B61/00 ,  C07C215/08 ,  C07C215/24 ,  C07C233/02 ,  C07C233/12 ,  C08F20/56 ,  C10M133/04 ,  C10M169/00 ,  D06M13/322 ,  D06M13/33 ,  D06M13/408 ,  D06M15/277 ,  C07C103/58

    CPC分类号： D06M15/277 ,  C07B61/00 ,  C07C215/08 ,  C07C215/24 ,  C07C233/02 ,  C07C233/12 ,  C08F20/56 ,  C10M1/08 ,  C10M133/04 ,  C10M169/00 ,  D06M13/322 ,  D06M13/33 ,  D06M13/408 ,  C10M2215/04 ,  C10M2215/044 ,  C10M2215/06 ,  C10M2215/26

    摘要： This invention comprises perfluoroaliphatic substituted amino compounds of the formula ##STR1## wherein n is an integer from 6 to 20, m is 2 or 4, R.sup.1 and R.sup.2 each is hydrogen atom or a lower alkyl with 1 to 3 carbon atoms, R.sup.3 is a hydrogen atom, an alkyl containing 1 to 29 carbon atoms, an alkenyl containing 3 to 10 carbon atoms, a cycloalkyl radical containing 3 to 12 carbon atoms, a cycloalkenyl with 5 to 12 carbon atoms, an N or O ring substituted cycloalkenyl radical containing 5 to 12 carbon atoms, an aryl, the radical --(CHR).sub.1 --OH wherein R is a hydrogen atom or a lower alkyl containing 1 to 3 carbon atoms, and R.sup.4 is a hydrogen atom or a methyl group and the method for preparing the same. This invention also comprises perfluoroaliphatic substituted amino compounds of the formula ##STR2## and mixtures of products of formula II with compounds of the formula ##STR3## and the method for preparing the same. The compounds are strong oleophobic and hydrophobic agents.

    摘要翻译： 本发明包括式（1）的全氟脂肪族取代的氨基化合物，其中n为6至20的整数，m为2或4，R 1和R 2各自为氢原子或具有1至3个碳原子的低级烷基， R3为氢原子，含有1〜29个碳原子的烷基，含有3〜10个碳原子的烯基，含有3〜12个碳原子的环烷基，具有5〜12个碳原子的环烯基，N或O环取代的环烯基 含有5至12个碳原子的基团，芳基，基团 - （CHR）1-OH其中R是氢原子或含有1至3个碳原子的低级烷基，R4是氢原子或甲基，并且该方法 为准备相同。 本发明还包括式（II）的全氟脂肪族取代的氨基化合物和式II的产物与式“IMAGE”的化合物的混合物及其制备方法。 这些化合物是强疏油和疏水剂。

    Polyfluorinated sulfonamides
    7.
    发明授权
    Polyfluorinated sulfonamides 失效
    多氟磺酰胺

    公开(公告)号：US4296034A

    公开(公告)日：1981-10-20

    申请号：US41926

    申请日：1979-05-24

    申请人： Pierre Bouvet ,  Jean-Pierre Lalu

    发明人： Pierre Bouvet ,  Jean-Pierre Lalu

    IPC分类号： C07C20060101 ,  C07D295/22 ,  C07C143/75 ,  C07C143/74

    CPC分类号： C07D207/46 ,  C10M2219/044

    摘要： This invention pertains to polyfluorinated sulfonamides having the formulaC.sub.n F.sub.2n+1 --CH.sub.2 --.sub.b SO.sub.2 --NRR'wherein n is a number of from 1 to about 20; b is an integer of from 2 to about 20; R is selected from the group consisting of a hydrogen radical and an alkyl radical having from 1 to about 10 carbon atoms; and R' is selected from the group consisting of a hydrogen radical, an alkyl radical of from 1 to about 10 carbon atoms, a cyclic alkyl radical of from 5 to 12 carbon atoms, and an aryl radical of from about 6 to 12 carbon atoms. These compounds are prepared through the action of polyfluorinated sulfonic chloride on an amino derivative.

    摘要翻译： 本发明涉及具有式CnF2n + 1-CH2-bSO2-NRR'的多氟磺酰胺，其中n为1至约20的数; b为2至约20的整数; R选自氢基团和具有1至约10个碳原子的烷基; 和R'选自氢基，1至约10个碳原子的烷基，5至12个碳原子的环状烷基和约6至12个碳原子的芳基 。 这些化合物通过多氟化磺酰氯对氨基衍生物的作用而制备。