摘要:
Coated pipes have a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m3 to 955 kg/m3.
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m to 955 kg/m3. Further, the multimodal ethylene copolymer comprises the multimodal ethylene copolymer comprises from 49 to 59% based on the weight of the multimodal ethylene copolymer a low molecular weight ethylene homopolymer component, said low molecular weight ethylene homopolymer having a weight average molecular weight of from 5000 g/mol to 70000 g/mol; and from 51 to 41% based on the weight of the multimodal ethylene copolymer a high molecular weight ethylene copolymer component, said high molecular weight ethylene copolymer having a weight average molecular weight of from 100000 g/mol to 700000 g/mol. The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m3 to 955 kg/m3. The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m to 955 kg/m3. Further, the multimodal ethylene copolymer comprises the multimodal ethylene copolymer comprises from 49 to 59% based on the weight of the multimodal ethylene copolymer a low molecular weight ethylene homopolymer component, said low molecular weight ethylene homopolymer having a weight average molecular weight of from 5000 g/mol to 70000 g/mol; and from 51 to 41% based on the weight of the multimodal ethylene copolymer a high molecular weight ethylene copolymer component, said high molecular weight ethylene copolymer having a weight average molecular weight of from 100000 g/mol to 700000 g/mol. The pipes can be coated with high throughput and good production economy. The coatings have good mechanical properties.
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol and a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 945 kg/m3 to 958 kg/m3. The coatings have a high stiffness, good properties at elevated temperatures and acceptable stress-cracking properties.
摘要翻译:本发明涉及具有多峰聚乙烯层的涂覆管。 多峰乙烯共聚物是乙烯与一种或多种具有4-10个碳原子的α-烯烃共聚单体的共聚物,其重均分子量为70000g / mol至250000g / mol,熔体指数MFR2为0.05 g / 10分钟至5g / 10min,熔体指数MFR5为0.5至10g / 10min,密度为945kg / m 3至958kg / m 3。 涂层具有高刚度,在高温下具有良好的性能和可接受的应力开裂性能。
摘要:
The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol and a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 945 kg/m3 to 958 kg/m3. The coatings have a high stiffness, good properties at elevated temperatures and acceptable stress-cracking properties.
摘要翻译:本发明涉及具有多峰聚乙烯层的涂覆管。 多峰乙烯共聚物是乙烯与一种或多种具有4-10个碳原子的α-烯烃共聚单体的共聚物,其重均分子量为70000g / mol至250000g / mol,熔体指数MFR2为0.05 g / 10分钟至5g / 10min,熔体指数MFR5为0.5至10g / 10min,密度为945kg / m 3至958kg / m 3。 涂层具有高刚度,在高温下具有良好的性能和可接受的应力开裂性能。
摘要:
A multimodal linear low density polyethylene polymer having a final density of 900 to 940 kg/m3, and containing at least one α-olefin comonomer in addition to ethylene comprising: (A) 30 to 60 wt % of a lower molecular weight component being an ethylene homopolymer or a copolymer of ethylene and at least one α-olefin; and (B) 70 to 40 wt % of a higher molecular weight component being a copolymer of ethylene and at least one α-olefin, said α-olefin being the same or different from any α-olefin used in component (A) but with the proviso that both components (A) and (B) are not polymers of ethylene and butane alone; wherein the multimodal LLDPE has a dart drop of at least 700 g; and wherein components (A) and (B) are obtainable using a Ziegler-Natta catalyst.
摘要:
The present inventions relates to a process for producing polyethylene compositions comprising polymerizing polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFR2 of 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerized, and further comprising a compounding step after polymerization, wherein the final polyethylene composition has a MFR21 of 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133.
摘要:
The present inventions relates to a process for producing polyethylene compositions comprising polymerising polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFR2 of 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerised, and further comprising a compounding step after polymerisation, wherein the final polyethylene composition has a MFR21 of 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133, a multimodal polymer composition comprising a polyethylene resin comprising (i) a first low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, (ii) a second low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, and (iii) a high molecular weight ethylene copolymer fraction, wherein the polyethylene resin has a MFR21 of 3 to 50 g/10 min and white spots are dispersed within the final composition with a white spot dispersion of less than 4.5 after a single compounding step, the melt flow rates being determined according to ISO 1133 and the white spot test according to ISO 18553, and the use of at least two slurry phase reactors for the polymerisation of a low molecular weight polyethylene fraction for improving the homogeneity of a multimodal polyethylene resin.
摘要:
A multimodal linear low density polyethylene polymer having a final density of 900 to 940 kg/m3, and containing at least one α-olefin comonomer in addition to ethylene comprising: (A) 30 to 60 wt % of a lower molecular weight component being an ethylene homopolymer or a copolymer of ethylene and at least one α-olefin; and (B) 70 to 40 wt % of a higher molecular weight component being a copolymer of ethylene and at least one α-olefin, said α-olefin being the same or different from any α-olefin used in component (A) but with the proviso that both components (A) and (B) are not polymers of ethylene and butane alone; wherein the multimodal LLDPE has a dart drop of at least 700 g; and wherein components (A) and (B) are obtainable using a Ziegler-Natta catalyst.