Ring opening of cyclic nitro ketones
    6.
    发明授权
    Ring opening of cyclic nitro ketones 失效
    环状硝基酮的开环

    公开(公告)号:US4554387A

    公开(公告)日:1985-11-19

    申请号:US604891

    申请日:1984-04-27

    Inventor: Paul D. Seemuth

    CPC classification number: C07C201/12

    Abstract: Macrocyclic ring opening reaction. The 2-nitro cycloalkan-1-ones and similar 2-nitro heterocyclic compounds are ring opened by reduction of the carbonyl oxygen with an anionic species such as NaBH.sub.4. An .alpha.,.omega.-nitro alcohol is recovered.

    Abstract translation: 大环开环反应。 2-硝基环烷-1-酮和类似的2-硝基杂环化合物通过用阴离子物质如NaBH 4还原羰基氧来开环。 回收α,ω-硝基醇。

    Cetane improver composition
    10.
    发明授权
    Cetane improver composition 失效
    十六烷改进剂组成

    公开(公告)号:US4536190A

    公开(公告)日:1985-08-20

    申请号:US596043

    申请日:1984-04-02

    Inventor: Paul D. Seemuth

    CPC classification number: C10L1/231 F02B3/06

    Abstract: Compounds that are themselves effective cetane improvers in diesel fuel but are considered too explosion sensitive for safe handling can be rendered relatively nonsensitive by blending with nitric acid esters of bicyclic or tricyclic alcohols containing a four-membered or five-membered ring and the resulting blend is an effective cetane improver. An example is a 50-50 blend of 2-methyl-2-nitropropyl nitrate, a shock-sensitive compound, with 5,6-cyclopenteno-2-norbornyl nitrate to give a relatively insensitive, but very effective cetane improver.

    Abstract translation: 在柴油燃料中本身有效的十六烷值改进剂的化合物,对于安全处理而言被认为对爆炸敏感的化合物可以通过与含有四元或五元环的二环或三环醇的硝酸酯共混而变得相对不敏感,所得混合物 有效的十六烷改良剂。 一个例子是硝酸2-甲基-2-硝基丙酯,一种冲击敏感化合物与5,6-环戊烯-2-降冰片基硝酸盐的50-50混合物,以产生相对不敏感但非常有效的十六烷值改进剂。

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