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1.发明授权公开(公告)号：US09567273B2
公开(公告)日：2017-02-14
申请号：US14651405
申请日：2013-12-13
Applicant: SHELL OIL COMPANY , CHINA UNIVERSITY OF PETROLEUM
Inventor： Peter Anton August Klusener , Zhichang Liu , Xianghai Meng , Rui Zhang , Jan De With , Chunming Xu
CPC classification number: C07C7/005 , C07C2/58 , C07C2521/02 , C07C2523/72 , C07C2527/10 , C07C2527/126 , C07C2531/02 , C10G29/205 , C10G31/09 , C10G31/10 , C10G2300/1088 , C10G2400/02 , Y02P20/542 , C07C9/16 , C07C9/21
Abstract: The present invention relates to a process for preparing alkylate comprising the subsequent steps (a), (b) and (c): (a) an alkylation step, wherein in a reaction zone a hydrocarbon mixture comprising at least an isoparaffin and an olefin is reacted with an ionic liquid catalyst to obtain an effluent comprising alkylate and solids, which latter are formed as side products in the alkylation step; (b) a separation step, wherein at least part of the alkylate-comprising effluent coming from the reaction zone is separated in a separator unit into a hydrocarbon-rich phase and an ionic liquid catalyst-rich phase which latter phase also comprises solids formed as side products during the alkylation reaction; and (c) a solids removal step, wherein the solids in ionic liquid catalyst-rich phase are separated from the ionic liquid catalyst using a suitable separating device; wherein the process further comprises a step following the separation step (b) and prior to the solids removal step (c).
Abstract translation: 本发明涉及一种制备烷基化物的方法，其包括随后的步骤（a），（b）和（c）：（a）烷基化步骤，其中在反应区中至少包含异链烷烃和烯烃的烃混合物为 与离子液体催化剂反应以获得包含烷基化物和固体的流出物，其在烷基化步骤中形成为副产物; （b）分离步骤，其中来自反应区的至少部分含烷基化物的流出物在分离器单元中分离成富烃阶段和富含离子液体催化剂的相，其后相还包含固体形成为 在烷基化反应过程中产生副产物; 和（c）固体去除步骤，其中使用合适的分离装置将离子液体富含催化剂相的固体与离子液体催化剂分离; 其中所述方法还包括在分离步骤（b）之后并且在固体除去步骤（c）之前的步骤。
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公开(公告)号：US09346042B2
公开(公告)日：2016-05-24
申请号：US14369215
申请日：2012-12-28
Applicant: SHELL OIL COMPANY , CHINA UNIVERSITY OF PETROLEUM
Inventor： Rui Zhang , Zhichang Liu , Chunming Xu , Xianghai Meng , Peter Anton August Klusener
CPC classification number: B01J31/4069 , B01J31/0279 , B01J31/40 , B01J38/66 , B01J2231/44 , C07C2/58 , C07C2527/125 , C10G29/205 , Y02P20/584 , C07C9/16
Abstract: The present invention relates to a regeneration process for producing a regenerated ionic liquid catalyst from solids formed in an ionic liquid alkylation process wherein a first ionic liquid is used as a catalyst which is a composite ionic liquid comprising ammonium cations, and anions being composite coordinate anions derived from two or more metal salts, the regeneration process comprising (a) removing the solids from the reaction zone of the alkylation process; and (b) subsequently treating the solids with a second ionic liquid made from an ammonium salt as cation, and an aluminum salt as anion which is the same as the aluminum salt present in the first ionic liquid.
Abstract translation: 本发明涉及一种用于在离子液体烷基化方法中形成的固体生产再生离子液体催化剂的再生方法，其中使用第一离子液体作为催化剂，其为包含铵阳离子的复合离子液体，阴离子为复合配位阴离子 衍生自两种或更多种金属盐，再生方法包括（a）从烷基化方法的反应区除去固体; 和（b）随后用由铵盐形成的第二离子液体作为阳离子处理固体，和作为阴离子的铝盐与第一离子液体中存在的铝盐相同。
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公开(公告)号：US20150231624A1
公开(公告)日：2015-08-20
申请号：US14369215
申请日：2012-12-28
Applicant: SHELL OIL COMPANY , CHINA UNIVERSITY OF PETROLEUM
Inventor： Rui Zhang , Zhichang Liu , Chunming Xu , Xianghai Meng , Peter Anton August Klusener
CPC classification number: B01J31/4069 , B01J31/0279 , B01J31/40 , B01J38/66 , B01J2231/44 , C07C2/58 , C07C2527/125 , C10G29/205 , Y02P20/584 , C07C9/16
Abstract: The present invention relates to a regeneration process for producing a regenerated ionic liquid catalyst from solids formed in an ionic liquid alkylation process wherein a first ionic liquid is used as a catalyst which is a composite ionic liquid comprising ammonium cations, and anions being composite coordinate anions derived from two or more metal salts, wherein at least one metal salt is an aluminium salt and any further metal salt is a salt of a metal selected from the group consisting of Group IB elements of the Periodic Table, Group IIB elements of the Periodic Table and transition elements of the Periodic Table, the regeneration process comprising (a) removing the solids from the reaction zone of the alkylation process; and (b) subsequently treating the solids with a second ionic liquid made from an ammonium salt as cation, and an aluminium salt as anion which is the same as the aluminium salt present in the first ionic liquid. The process of the invention provides means to more efficiently run an ionic liquid alkylation process with less impact on the environment than processes known from the prior art.
Abstract translation: 本发明涉及一种用于在离子液体烷基化方法中形成的固体生产再生离子液体催化剂的再生方法，其中使用第一离子液体作为催化剂，其为包含铵阳离子的复合离子液体，阴离子为复合配位阴离子 衍生自两种或更多种金属盐，其中至少一种金属盐是铝盐，并且任何另外的金属盐是选自元素周期表第IB族元素，元素周期表IIB族元素的金属盐 和周期表的过渡元素，再生过程包括（a）从烷基化方法的反应区除去固体; 和（b）随后用由铵盐形成的第二离子液体作为阳离子处理固体，和作为阴离子的铝盐与第一离子液体中存在的铝盐相同。 本发明的方法提供了比现有技术已知的方法更有效地运行对环境的影响较小的离子液体烷基化方法的方法。
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4.发明授权公开(公告)号：US11097263B2
公开(公告)日：2021-08-24
申请号：US16557968
申请日：2019-08-30
Applicant: CHINA UNIVERSITY OF PETROLEUM—BEIJING
Inventor： Liang Zhao , Jinsen Gao , Tianzhen Hao , Lixia Dong , Di Gao , Xiaoyu Wu , Xiaoqin Wang , Liyuan Cao , Chunming Xu
IPC: B01J29/40 , B01J37/02 , B01J37/00 , B01J37/10 , B01J37/30 , B01J29/064 , B01J29/076 , B01J29/06 , B01J29/068 , B01J29/072 , B01J29/42 , B01J29/83 , B01J29/85 , B01J29/84 , B01J29/44 , B01J29/46 , B01J29/48 , B01J35/00 , B01J35/10 , B01J35/02 , B01J37/28 , C10G45/64 , C10G35/095 , C10G45/68
Abstract: The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.
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公开(公告)号：US10822242B2
公开(公告)日：2020-11-03
申请号：US16525503
申请日：2019-07-29
Applicant: CHINA UNIVERSITY OF PETROLEUM—BEIJING
Inventor： Haiyan Liu , Tao Zheng , Zhichang Liu , Xianghai Meng , Rui Zhang , Chunming Xu
Abstract: The present application provides a ZSM-35 molecular sieve and a preparation method thereof. The ZSM-35 molecular sieve is an aggregated ZSM-35 molecular sieve having a hierarchical macro-meso-microporous pore structure. Raw materials for the preparation method do not include an organic template agent and a crystal seed, and the preparation method includes the following steps: preparing a reactant gel where a molar ratio of SiO2, Al2O3, Na2O, K2O, oxygen-containing acid radical and H2O is (20-40):1.0:(1.5-2.0):(4.0-6.5):(1.0-4.0):(600-1200); sequentially performing an aging treatment and a crystallization treatment on the reactant gel, washing and drying a resulting synthetic product. The ZSM-35 molecular sieve provided by the present application may be obtained by synthesizing without using an organic template agent and crystal seed, and because it has a hierarchical pore structure, it is favorable for material diffusion and mass transfer.
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Patent Agency Ranking
公开(公告)号：US12115522B2
公开(公告)日：2024-10-15
申请号：US17390123
申请日：2021-07-30
Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING
Inventor： Liang Zhao , Jinsen Gao , Butian Xia , Lixia Dong , Jingye Chen , Yuhao Zhang , Chunming Xu
IPC: B01J29/40 , B01J21/04 , B01J23/10 , B01J29/70 , B01J35/00 , B01J37/02 , B01J37/04 , B01J37/08 , C10G45/12
CPC classification number: B01J29/405 , B01J21/04 , B01J23/10 , B01J29/40 , B01J29/70 , B01J35/19 , B01J37/0201 , B01J37/0207 , B01J37/04 , B01J37/082 , C10G45/12 , B01J2229/18 , B01J2229/20 , C10G2300/104 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/70 , C10G2400/02
Abstract: Provided are an in situ bifunctional catalyst for deep desulfurization and increasing octane number of gasoline, and its preparation method and application. The bifunctional catalyst includes a modified catalyst carrier and a loaded active metal, where the modified catalyst carrier is a composite carrier prepared through mixing γ-Al2O3 and an acidic molecular sieve by a binder and calcining. When the bifunctional catalyst provided by the present application is used for hydrodesulfurization of gasolines, deep desulfurization, olefin reduction and octane number preservation can be realized simultaneously, thereby obtaining a high-quality oil product.
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公开(公告)号：US11998899B2
公开(公告)日：2024-06-04
申请号：US17390820
申请日：2021-07-30
Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING
Inventor： Liang Zhao , Jinsen Gao , Butian Xia , Lixia Dong , Jingye Chen , Yuhao Zhang , Chunming Xu
IPC: B01J29/40 , B01J21/04 , B01J23/10 , B01J29/70 , B01J35/00 , B01J37/02 , B01J37/04 , B01J37/08 , C10G45/12
CPC classification number: B01J29/405 , B01J21/04 , B01J23/10 , B01J29/40 , B01J29/70 , B01J35/19 , B01J37/0201 , B01J37/0207 , B01J37/04 , B01J37/082 , C10G45/12 , B01J2229/18 , B01J2229/20 , C10G2300/104 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , C10G2300/70 , C10G2400/02
Abstract: Provided are a bifunctional catalyst for deep desulfurization and gasoline quality improvement and a preparation method therefore and a use thereof. The bifunctional catalyst includes a modified catalyst and a loaded active metal, where the modified catalyst carrier is a γ-Al2O3 modified with a rare earth element, or the modified catalyst carrier is a composite carrier prepared by mixing and calcinating γ-Al2O3 and an acid molecular sieve through a binder, and then modifying with the rare earth element. The bifunctional catalyst for deep desulfurization and gasoline quality improvement can achieve deep desulfurization of high-sulfur fluid catalytic cracking gasoline, and ensure no significant loss of octane number under relatively mild conditions.
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公开(公告)号：US09725658B2
公开(公告)日：2017-08-08
申请号：US14296387
申请日：2014-06-04
Inventor： Gang Wang , Jinsen Gao , Chunming Xu , Baojian Shen , Hongliang Wang
CPC classification number: C10G11/18 , C10G11/02 , C10G11/04 , C10G2300/107 , C10G2300/1077 , C10G2400/02 , C10G2400/04 , C10G2400/30
Abstract: The present invention provides a method for processing low-grade heavy oil, comprising: providing a riser-bed reactor; preheating the low-grade heavy oil and injecting it into the riser reactor to react with solid catalyst particles at the temperature of 550-610° C.; oil-gas, after reacting with the solid catalyst particles in the riser reactor, being introduced into the fluidized bed reactor to continue to react at temperature of 440-520° C. and weight hourly space velocity of 0.5-5 h−1; and the oil-gas, after reacting in the fluidized bed reactor, being separated from coked solid catalyst particles carried therein, and the separated oil-gas being introduced into a fractionation system. The method can effectively remove carbon residues, heavy metals, asphaltenes and other impurities from the low-grade heavy oil, and obtain high liquid product yield in a simple process.
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公开(公告)号：US09290706B2
公开(公告)日：2016-03-22
申请号：US13851802
申请日：2013-03-27
Applicant: CHINA UNIVERSITY OF PETROLEUM-BEIJING
Inventor： Suoqi Zhao , Xuewen Sun , Zhiming Xu , Chunming Xu , Keng H. Chung
CPC classification number: C10G55/04 , C10G21/003 , C10G21/14 , C10G69/06 , C10G2300/206 , C10G2300/4081 , C10G2300/44
Abstract: The invention provides an integrated process for processing heavy oil, wherein the integrated process at least comprises: solvent deasphalting is carried out for heavy oil material, and de-oiled asphalt phase is mixed with dispersing agent and then entered a thermal cracking reactor to undergo thermal cracking reactions. Upgraded oil can be obtained through the mixture of the de-asphalted oil and thermal cracking oil separated from thermal cracking reaction products. The solvent and heavy gas oil, which are separated from the thermal cracking reaction products, are respectively recycled back to the solvent deasphalting process as solvent and as mixed feed to remove asphaltene. The integrated process of the present invention solves the problems that solvent is difficult to be separated from asphalt with high softening point in solvent deasphalting process and hard asphalt is difficult to be transported.
Abstract translation: 本发明提供了一种加工重油的综合方法，其中一体化方法至少包括：对重油材料进行溶剂脱沥青，脱油沥青相与分散剂混合，然后进入热裂解反应器进行热处理 开裂反应。 通过从热裂解反应产物中分离的脱沥青油和热裂解油的混合物可以获得升级的油。 与热裂解反应产物分离的溶剂和重质瓦斯油分别作为溶剂和混合进料循环回到溶剂脱沥青法中以除去沥青质。 本发明的一体化方法解决了在溶剂脱沥青工艺中溶剂难以与高软化点的沥青分离的困难，难以运输硬沥青的问题。
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公开(公告)号：US10266778B2
公开(公告)日：2019-04-23
申请号：US14940027
申请日：2015-11-12
Applicant: CHINA UNIVERSITY OF PETROLEUM—BEIJING
Inventor： Jinsen Gao , Liang Zhao , Chunming Xu , Tianzhen Hao , Xiaona Han
IPC: C10G67/02 , C10G67/06 , C10G67/00 , C10L1/06 , C10G21/16 , C10G21/27 , C10G25/00 , C10G45/08 , C10G45/64 , C10G45/68 , C10G67/04 , C10G69/00 , C10G69/04
Abstract: A method for upgrading fluid catalytic cracking gasoline includes the following steps: cutting fluid catalytic cracking gasoline into light, medium, and heavy gasoline fractions; subjecting the medium gasoline fraction to an aromatization/hydroisomerization reaction in the presence of a catalyst to obtain a desulfurized medium gasoline fraction; and blending the light gasoline fraction, the desulfurized medium gasoline fraction and the heavy gasoline fraction to obtain upgraded gasoline; where, a cutting temperature of the light and the medium gasoline fractions is 35-60° C., and a cutting temperature of the medium and the heavy gasoline fractions is 70-160° C. The method according to the present invention not only can realize deep desulfurization of fluid catalytic cracking gasoline, but also can improve octane number significantly.
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