摘要:
A description is given of a polymer dispersion comprising i) polymer particles dispersed in an aqueous medium and composed of units of ethylenically unsaturated monomers, ii) a water-soluble polymeric polyelectrolyte which along a polymeric backbone carries a large number of ionic groups of uniform charge character or groups which can be ionized to such groups, and iii) an ionic surfactant which carries an ionic group having a charge character opposite to that of the polymeric polyelectrolyte, or a group which can be ionized to such a group. The polymer dispersion can be coagulated by simple dilution with water.
摘要:
The invention relates to a thermally hardenable polymer dispersion powder and the use of said powder as a binding agent in particular for fibrous and grainy materials. The binding agent in powder form is obtained by drying a polymer dispersion which comprises a carboxyl-group-containing polymerization component in addition to, optionally, a hydroxy-alkylated amine.
摘要:
Heat-curable aqueous compositions which comprise a carboxyl-containing polymer component and optionally a hydroxyalkylated amine are used as binders for shaped articles.
摘要:
Described is a polymer dispersion comprising in an aqueous medium (a) dispersed particles of a polymer containing more than from 5 to 20% by weight of &agr;,&bgr;-ethylenically unsaturated mono- or dicarboxylic acid, (b) a dissolved polymer containing from 60 to 100% by weight of &agr;,&bgr;-ethylenically unsaturated mono- or dicarboxylic acid, and (c) an alkoxylated long-chain amine. Heat-curable compositions are obtained by adding polyfunctional alcohols and, optionally, reaction accelerant. The polymer dispersions and the heat-curable compositions are suitable for use as binders for textile sheetlike structures and for moldings.
摘要:
Ammonia-free polymer dispersions containing at least one copolymer which contains, as polymerized monomers, a) from 40 to 80% by weight of at least one ester of acrylic acid with C2-C12-alkanols, b) from 10 to 40% by weight of at least one vinylaromatic monomer and/or at least one ester of methacrylic acid with C1-C4-alkanols, c) from 2 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid, d) not more than 1% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) less than 5% by weight of &agr;,&bgr;-ethylenically unsaturated nitrites and f) less than 1% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids, and the polymer powders or polymer granules obtainable from the polymer dispersion, are used as additives for building materials based on hydraulic binders. The building materials based on hydraulic binders and binder formulations which contain these polymers and a process for improving the mechanical strength, elasticity and processibility of building materials based on hydraulic binders are also described.
摘要:
Cement-based compositions comprising per 100 parts by weight of cement from 1 to 500 parts by weight of a polymer built up from a) 30-99.5% by weight of at least one alkyl ester of (meth)acrylic acid, b) 0-70% by weight of at least one vinylaromatic, c) 0.5-10% by weight of at least one alkyl polyethoxy(meth)acrylate of the formula where R1 is a hydrogen atom or a methyl group, R2 is a C1 to C4 alkyl group and n is an integer from 1 to 55, d) 0-10% by weight of at least one ethylenically unsaturated mono- or dicarboxylic acid, such as acrylic acid, methacrylic acid, maleic acid, itaconic acid, or anhydride, amide or hydroxyalkylamide thereof, e) 0-10% by weight of acrylonitrile or methacrylonitrile, and f) 0-50% by weight of further ethylenically unsaturated compounds other than a) to e).
摘要:
Thermally curable aqueous compositions comprising a low-acid and an acid-rich polymer component and also a hydroxyalkylated amine are used as binders for shaped articles.
摘要:
A formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl groups can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, is useful as binder for renewable raw materials in the form of fibers or chips to produce shaped articles.
摘要:
The present invention relates to the use of a heat-curable aqueous composition comprising dispersed polymer particles of at least a) one polymer A1 comprising, 98-100% by weight of ethylenically unsaturated monomers A, it being possible for up to 20% by weight of the monomers A to comprise glycidyl and/or hydroxyl groups and/or amino/amido groups, and the polymer comprising, incorporated in the form of polymerized units, ≦5% by weight of an α,β-ethylenically unsaturated mono- or dicarboxylic acid and at least 1% by weight of acrylonitrile, and 0-5% by weight of a bi- or polyfunctional monomer and b) a polymer A2 which is soluble in the serum and comprises, incorporated in the form of polymerized units, 60-100% by weight of at least one α,β-ethylenically unsaturated mono- or dicarboxylic acid whose carboxyl groups can form an anhydride group, salts or mixtures thereof c) and a polyfunctional crosslinking agent or mixtures thereof d) and, if appropriate, divalent or trivalent metal ions which are added in the form of hydroxides, oxides, carbonates or bicarbonates as a binder for substrates.