摘要:
Disclosed is a composition comprised of at least one compound selected from 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoro-1-propene and 1-chloro-3,3,3-trifluoropropene and halogenated impurity selected from the group consisting of HFO-1141 (CH2═CHF), HCFO-1140 (CH2═CHCl), and HCFO-1131 (CH2═CFCl and/or translcis-CHF═CHCl) and combination thereof, said halogenated impurity being present in said composition in an amount of 50 ppm or less.
摘要:
The present disclosure provides a method for separating 244bb from 1233xf by using solid adsorbent selected from molecular sieves having an average pore size of 5 Å or greater.
摘要:
Provided are azeotropic and azeotrope-like compositions of 1,2,3,3,3-pentafluoropropene (HFO-1225ye) and water. Such azeotropic and azeotrope-like compositions are useful in isolating 1,2,3,3,3-pentafluoropropene from impurities during production. Azeotropes of the instant invention are similarly useful in final compositions or manufacturing final compositions, such as blowing agent, propellants, refrigerants, diluents for gaseous sterilization and the like.
摘要:
The present invention is a method for purifying a linear saturated fluorohydrocarbon compound comprising bringing a crude linear saturated fluorohydrocarbon compound having four or five carbon atoms into contact with a hydrous metal salt of a synthetic crystalline aluminosilicate that has a carbon dioxide adsorption amount of 50 μmol/g or less and an average pore size of 3 Å to remove water from the crude linear saturated fluorohydrocarbon compound. The present invention makes it possible to reduce or suppress the production of a dehydrofluorinated compound due to a decomposition reaction of the linear saturated fluorohydrocarbon compound, and to remove water efficiently.
摘要:
The present disclosure provides a method for separating 244bb from 1233xf by using solid adsorbent selected from molecular sieves having an average pore size of 5A or greater.
摘要:
The present invention is a method for purifying a linear saturated fluorohydrocarbon compound comprising bringing a crude linear saturated fluorohydrocarbon compound having four or five carbon atoms into contact with a hydrous metal salt of a synthetic crystalline aluminosilicate that has a carbon dioxide adsorption amount of 50 μmol/g or less and an average pore size of 3 Å to remove water from the crude linear saturated fluorohydrocarbon compound. The present invention makes it possible to reduce or suppress the production of a dehydrofluorinated compound due to a decomposition reaction of the linear saturated fluorohydrocarbon compound, and to remove water efficiently
摘要:
Provided is a purification method for efficiently reducing an undesirable organic compound or compound in (E)-1-chloro-3,3,3-trifluoropropene and thereby obtaining (E)-1-chloro-3,3,3-trifluoropropene with high purity. The purification method of OF-1233E according to the present invention is characterized by bringing a composition containing OF-1233E and at least one organic compound selected from the group consisting of HCFC-142 isomers, HCFC-244fa, HFC-245fa, OF-1234E, OF-1234Z and OF-1233Z into contact with a solid adsorbent.
摘要:
A method for forming 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising providing a dehydrochlorination starting material having relatively low concentrations of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), especially and preferable less than about 8.0% when the dehydrochlorination reaction utilizes no substantial amount of catalyst or catalyst comprising austenitic nickel-based materials.
摘要:
To provide a dichloromethane purification method which can reduce the amount of stabilizers present in dichloromethane and is feasible in industry by a simple operation, a dichloromethane purification method includes bringing dichloromethane containing at least one stabilizer selected from the group consisting of 2-methyl-2-butene, hydroquinone and resorcinol into contact in a liquid phase state with a zeolite having an average pore size of 3 to 11 Å and thereby reducing the amount of the stabilizer.
摘要:
A process for treating a composition comprising one or more desired (hydro)halocarbons and one or more undesired halogenated hydrocarbon containing impurities so as to reduce the concentration of at least one undesired halogenated hydrocarbon containing impurity, the process comprising contacting the composition with an adsorbent comprising a carbon molecular sieve.