摘要:
Styrene polymer foam particles of from 10 to 30 kg/m.sup.3 in density are obtained by foaming styrene polymers which, per kg, contain from 0.7 to 3 moles of blowing agent mixture composed of from 60 to 90 mol % of water and from 10 to 40 mol % of the C.sub.4 - or C.sub.5 -hydrocarbon with the aid of microwaves.
摘要翻译:通过发泡苯乙烯聚合物获得密度为10至30kg / m 3的苯乙烯聚合物泡沫颗粒,苯乙烯聚合物每kg含有0.7至3摩尔由60至90摩尔%的水组成的发泡剂混合物和10至40 在微波辅助下,C4-或C5-烃的摩尔%。
摘要:
Expandable styrene polymers of from 95 to 99.5% by weight of polystyrene and from 0.15 to 5% by weight of a styrene-soluble styrene/acrylonitrile copolymer having a total content of not less than 0.15% by weight of acrylonitrile, which contain from 3 to 10% by weight of a C.sub.3 -C.sub.6 -hydrocarbon and may contain conventional additives, give foams which do not shrink. The said styrene polymers can be prepared by suspension polymerization of a solution of the styrene/acrylonitrile copolymer in styrene.
摘要:
Particulate styrene polymers containing blowing agents are prepared by a process in which an aliphatic hydrocarbon of 7 to 9 carbon atoms is added in an amount of from 0.01 to 0.5% by weight, based on the styrene polymer, before, during or after the polymerization. The particulate styrene polymers can be processed to foam blocks and moldings having a satisfactory smooth surface.
摘要:
Expandable styrene polymers and styrene polymer foams having a particularly uniform and fine-cell foam structure contain, as a cell regulator, small amounts of a mixture of resin acids, lower alkyl esters of resin acids or (hydro)abietyl phthalate and a polyoxyethylene monoester or monoether.
摘要:
Particulate polystyrene containing blowing agent and having improved expandability is based on polystyrene having a weight-average mean molecular weight of not more than from 130,000 to 180,000 and a molecular weight distribution curve in which the high molecular weight flank drops steeply. The expandable polystyrene particles are produced by polymerizing styrene in aqueous suspension in the presence of blowing agents and of chain transfer agents or styrene oligomers.
摘要:
A process for the preparation of polyurethane foams modified with melamine-formaldehyde precondensates, in which the precondensates employed are storage-stable, aqueous 40-85% strength by weight resin solutions which are obtained by condensing melamine with formaldehyde in a molar ratio of 1:1.1-1.75 in aqueous solution at a pH which, at least periodically, is above 8, and at from 60 to 130.degree. C., until one part by volume of resin solution can be diluted with from 0.5 to 4 parts by volume of water at 20.degree. C. without causing a persisting cloudiness.
摘要:
Particulate self-extinguishing thermoplastic molding compositions based on styrene polymers containing volatile blowing agents are surface-coated with an organic bromine compound and, to stabilize the bromine compound against photodegradation, a N-hydroxyphenylbenzotriazole or a hydroxybenzophenone. The molding compositions may be used for the manufacture of foams by expanding the blowing agents at elevated temperatures.
摘要:
The present invention relates to melamine-formaldehyde foams comprising hollow microspheres wherein said hollow microspheres have a median particle diameter (D50, volume averaged, Malvern, Fraunhofer diffraction) in the range from 260 μm to 490 μm, and also processes for producing these melamine-formaldehyde foams and their uses.
摘要:
The invention relates to a process for producing expandable pelletized material which comprises polylactic acid which comprises the following steps: a) melting and incorporation by mixing of the following components: i) from 50 to 99.9% by weight, based on the total weight of components i to iii), of polylactic acid, ii) from 0 to 49.9% by weight, based on the total weight of components i to iii), of one or more further polymers, iii) from 0.1 to 2% by weight, based on the total weight of components i to iii), of a diepoxide or polyepoxide, and iv) from 0 to 10% by weight of one or more additives, b) incorporation by mixing of v) from 3 to 7% by weight, based on the total weight of components i to iv), of an organic blowing agent into the polymer melt by means of a static or dynamic mixer at a temperature of at least 140° C., c) discharging through a die plate with holes, the diameter of which at the exit from the die is at most 1.5 mm, and d) pelletizing the melt comprising blowing agent directly downstream of the die plate, and under water, at a pressure in the range from 1 to 20 bar. The invention further relates to expandable pelletized material which comprises polylactic acid and which is obtainable by said process, and also to specific expandable pelletized material which comprises polylactic acid and which has a proportion of from 3 to 7% by weight of an organic blowing agent, preferably n-pentane and particularly preferably isopentane. The invention further relates to a preferred process for producing expandable pelletized material which comprises blowing agent and which comprises polylactic acid, and which has low bulk density.
摘要:
Styrene beads, wherein the styrene polymer beads comprise from 0.5 to 5% by weight of one or more high-temperature peroxides, where the high-temperature peroxides have a half-life time of 1 hour in the range from 110 to 160° C., measured in cumene.