摘要:
Langmuir-Blodgett films are provided in which a molecule is chemically bonded with a bottom electrode substrate as part of a crossed wire device comprising two electrodes and a molecular layer therebetween. The molecule, which comprises a switchable moiety and a connecting moiety, is provided with a photolabile capping group attached to the connecting moiety. The photolabile capping group temporarily caps the reactive connecting group of the molecule. The capped molecules are processed to form a LB film on the water-air interface of water. The films are then exposed to UV light. The photolabile capping group decomposes to give back the connecting group, which remains in the water. As the uncapped LB films are transferred to a bottom electrode substrate, the surface of the electrode reacts with the reactive connecting group of the molecule to form a chemically bonded LB layer on the substrate, thereby providing improved LB films.
摘要:
A method for reversibly switching a molecular system between three or four states is disclosed. The method includes exposing a photochromic compound within the molecular system to at least one radiation and at least one of an acid and a base. Upon such exposure, the photochromic compound switches from one of the three or four states to an other of the three or four states.
摘要:
The present invention is drawn to a composition or layered composite for absorbing and utilizing radiant energy in a solar cell. The composition can comprise a blend of a push-pull copolymer including at least one electron donor entity and at least one electron acceptor entity, and a fullerene composition. The layered composite can comprise a push-pull copolymer including at least one electron donor entity and at least one electron acceptor entity configured in a first layer, and a fullerene composition configured in a second layer. The first layer is typically in contact with the second layer.
摘要:
The invention described herein includes a molecular switch, comprising: a donor subunit; an acceptor subunit; and an aromatic bridging subunit comprising one or more bridging groups for bonding the donor subunit to the aromatic bridging subunit and for bonding the acceptor subunit to the aromatic bridging subunit wherein the aromatic bridging subunit is conformable in a manner effective for polarizing and de-polarizing the molecular switch at a low electric field voltage.
摘要:
The present invention is drawn to compositions and methods of generating active ester functionalized latex particulates in a liquid suspension, as well as compositions and methods of preparing ink-jet inks. Steps of the methods can include synthesizing polymerizable monomers with active ester groups and polymerizing these monomers with other monomers to form functionalized latex particulates having active ester group. These latex particulates can be used in a wide variety of applications, including in ink-jet ink printing applications.
摘要:
A digital dye having an optical change resulting from an electrochemical oxidation/reduction reaction is provided for use in a molecular system. The molecular system provides two different colors based on two different oxidation states of at least one digital dye in the molecular system. Further, an optical switch comprising the molecular system configured within an electric field generated by a pair of electrodes is provided, employing the above-described digital dye. Still further, a display device including a transparent display electrode, a counter electrode, and the molecular system disposed therebetween is provided, where the molecular system comprises at least one digital dye.
摘要:
A self-assembled molecular color switch is formed on a substrate and comprises coupled coaxial rotors and non-coaxial stators, with each rotor rotatably connected to two stators, to form molecular planes wherein all rotors at rest are parallel to the substrate and orthogonal to an electric field. The color switch employs a novel chemistry for producing a molecular film having a field switchable color. More particularly, it is a chemistry that provides for relatively thick self-assembled molecular layers collectively having print-like optical density. Further, a means for bi-stable color switching is provided.
摘要:
The present disclosure is related to coated photoconductors. In an example, a coated photoconductor can comprise a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto and a top coating adhered to the photoconductor. The top coating can comprise a cross-linkable polymer, a cross-linker, and a polymeric dopant having a weight average molecular weight of less than 500,000. Additionally, the top coating can have a thickness of 0.1 μm to 12 μm and the polymeric dopant can be present in the top coating at a concentration of 0.1 wt % to 10 wt %.
摘要:
Surfactants are provided that have a hydrophobic tail portion and a hydrophilic head portion. The hydrophilic head portion includes a terminal dialkyl-substituted tertiary amine or a terminal cycloalkyl-substituted tertiary amine. Also provided are pigment-based inks employing the surfactant, a combination of an electronic display and the pigment-based inks, and a process for reducing conductivity in primary amine-based surfactants and improving reliability of electronic inks employing such surfactants.
摘要:
Pigment based inks are provided. The inks include a non-polar carrier fluid and a surface-functionalized pigment particle including a nitrogen-linked moiety to the surface of the pigment particle through a nitrogen link at one end of the nitrogen-linked moiety and a graft copolymer having two or three blocks attached at another end, the pigment particle suspended in the non-polar carrier fluid, the nitrogen-linked moiety further including an alkyl chain interposed between the nitrogen-linked moiety and the graft copolymer having the structure (I), where X is the nitrogen-linked moiety and Y is a copolymer, and the letter a is an integer between 0 and about 5,000, while the letter b is an integer of 2 or more.