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公开(公告)号：US07863027B2
公开(公告)日：2011-01-04
申请号：US12429526
申请日：2009-04-24
CPC分类号： C12N9/78 , C12N9/96 , C12P7/42 , C12Y305/05001
摘要： A process is provided to improve the specific activity of an enzyme catalyst having nitrilase activity when converting glycolonitrile to glycolic acid under aqueous reaction conditions. Inclusion of an effective amount of at least one amine protectant improves the specific activity and catalytic productivity of the enzyme catalyst.
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公开(公告)号：US07741083B2
公开(公告)日：2010-06-22
申请号：US12189869
申请日：2008-08-12
申请人： Robert DiCosimo , Anna Panova , Jeffery Scott Thompson , Robert D. Fallon , F. Glenn Gallagher , Thomas Foo , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
发明人： Robert DiCosimo , Anna Panova , Jeffery Scott Thompson , Robert D. Fallon , F. Glenn Gallagher , Thomas Foo , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
CPC分类号： C07C51/48 , C07C51/42 , C07C51/487 , C12P7/42 , C07C59/06
摘要： A process is provided for producing glycolic acid from formaldehyde and hydrogen cyanide. More specifically, heat-treated formaldehyde and hydrogen cyanide are reacted to produce glycolonitrile having low concentrations of impurities. The glycolonitrile is subsequently converted to an aqueous solution of ammonium glycolate using an enzyme catalyst having nitrilase activity derived from Acidovorax facilis 72W (ATCC 57746). Glycolic acid is recovered in the form of the acid or salt from the aqueous ammonium glycolate solution using a variety of methods described herein.
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公开(公告)号：US20100087528A1
公开(公告)日：2010-04-08
申请号：US12572059
申请日：2009-10-01
申请人： Robert DiCosimo , William R. Cahill , David George Dipietro , Eugenia Costa Hann , Richard Alan Reynolds
发明人： Robert DiCosimo , William R. Cahill , David George Dipietro , Eugenia Costa Hann , Richard Alan Reynolds
CPC分类号： C12N9/18 , A61L2/183 , A61L2/186 , A61L2/22 , A61L2202/24 , C11D3/06 , C11D3/10 , C11D3/201 , C11D3/2017 , C11D3/2044 , C11D3/2048 , C11D3/2068 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/32 , C11D3/361 , C11D3/38636 , C11D3/3947 , C11D17/041 , C12P7/40 , C12Y301/01001 , Y02E50/16
摘要： Disclosed herein are two-component enzymatic peracid generation systems and methods of using such systems wherein the first component comprises a formulation of at least one enzyme catalyst having perhydrolysis activity, a carboxylic acid ester substrate, and a cosolvent and wherein the second component comprises a source of peroxygen in water. The two components are combined to produce an aqueous peracid formulation useful as, e.g., a disinfecting or bleaching agent. Specifically, organic cosolvents are used to control the viscosity of a substrate-containing component and to enhance the solubility of the substrate in an aqueous reaction formulation without causing substantial loss of perhydrolytic activity of the enzyme catalyst.
摘要翻译： 本文公开了双组分酶过酸生成系统和使用这种系统的方法，其中第一组分包含至少一种具有过水解活性的酶催化剂的制剂，羧酸酯底物和共溶剂，并且其中第二组分包含来源 的过氧在水中。 将两种组分组合以产生用作例如消毒剂或漂白剂的含水过酸制剂。 具体地说，使用有机共溶剂来控制含底物的组分的粘度，并提高底物在水性反应制剂中的溶解度，而不会引起酶催化剂的过水解活性的显着损失。
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公开(公告)号：US20100086621A1
公开(公告)日：2010-04-08
申请号：US12572107
申请日：2009-10-01
申请人： Robert DiCosimo , Arie Ben-Bassat , William R. Cahill , David George Dipietro , Eugenia Costa Hann , Mark S. Payne , Richard Alan Reynolds , Raymond Richard Zolandz
发明人： Robert DiCosimo , Arie Ben-Bassat , William R. Cahill , David George Dipietro , Eugenia Costa Hann , Mark S. Payne , Richard Alan Reynolds , Raymond Richard Zolandz
CPC分类号： C12N9/18 , A61L2/183 , A61L2/186 , A61L2/22 , A61L2202/24 , C11D3/06 , C11D3/10 , C11D3/201 , C11D3/2017 , C11D3/2044 , C11D3/2048 , C11D3/2068 , C11D3/2079 , C11D3/2082 , C11D3/2086 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/32 , C11D3/361 , C11D3/38636 , C11D3/3947 , C11D17/041 , C12P7/40 , C12Y301/01001 , Y02E50/16
摘要： Disclosed herein are multi-component peroxycarboxylic acid generation systems for enzymatically producing aqueous formulations of peroxycarboxylic acids suitable for use in, e.g., disinfectant and/or bleaching applications. The multi-component peroxycarboxylic acid generation systems comprise at least one carbohydrate esterase family 7 enzyme having perhydrolytic activity.
摘要翻译： 本文公开了用于酶促生产适用于例如消毒剂和/或漂白应用的过氧羧酸的水性制剂的多组分过氧羧酸生成系统。 多组分过氧羧酸生成系统包含至少一种具有过水解活性的碳水化合物酯酶家族7酶。
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公开(公告)号：US20100041752A1
公开(公告)日：2010-02-18
申请号：US11638635
申请日：2006-12-12
摘要： A method is provided for producing peroxycarboxylic acids from carboxylic acid esters. More specifically, carboxylic acid esters are reacted with an inorganic peroxide, such as hydrogen peroxide, in the presence of an enzyme catalyst having perhydrolysis activity derived from Bacillus sp. to produce peroxycarboxylic acids.
摘要翻译： 提供了从羧酸酯制备过氧羧酸的方法。 更具体地，羧酸酯与无机过氧化物如过氧化氢在具有源自芽孢杆菌属芽孢杆菌属的过水解活性的酶催化剂存在下反应。 以生产过氧羧酸。
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公开(公告)号：US20100016429A1
公开(公告)日：2010-01-21
申请号：US12565419
申请日：2009-09-23
申请人： Robert DiCosimo , Mark S. Payne , Vincent Brian Croud , John E. Gavagan , Lorraine W. Wagner , Eugenia Costa Hann
发明人： Robert DiCosimo , Mark S. Payne , Vincent Brian Croud , John E. Gavagan , Lorraine W. Wagner , Eugenia Costa Hann
CPC分类号： A61L2/186 , A61L2/183 , A61L2202/18 , A61L2202/24 , A61L2202/26 , C11D1/521 , C11D3/2093 , C11D3/32 , C11D3/386 , C11D3/3947 , C11D3/48 , C12P7/00 , C12P7/40
摘要： A process is provided to produce a concentrated aqueous peracid solution in situ using at least one enzyme having perhydrolase activity in the presence of hydrogen peroxide (at a concentration of at least 500 mM) under neutral to acidic reaction conditions from suitable carboxylic acid esters (including glycerides) and/or amides substrates. The concentrated peracid solution produced is sufficient for use in a variety of disinfection and/or bleaching applications.
摘要翻译： 提供了一种方法，在中性至酸性反应条件下，使用至少一种具有过水解酶活性的酶在过氧化氢（至少500mM浓度）存在下，从合适的羧酸酯（包括 甘油酯）和/或酰胺底物。 所生产的浓缩的过酸溶液足以用于各种消毒和/或漂白应用。
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公开(公告)号：US20090325266A1
公开(公告)日：2009-12-31
申请号：US12497384
申请日：2009-07-02
CPC分类号： C11D3/38636 , A01N37/16 , C11D3/2093 , C11D3/221 , C11D3/226 , C11D3/3947 , C11D3/48 , C12P7/40 , A01N37/02 , A01N37/12 , A01N37/46 , A01N43/16 , A01N59/00 , A01N61/00 , A01N2300/00
摘要： A process is provided for producing peroxycarboxylic acids from carboxylic acid esters. More specifically, carboxylic acid esters are reacted with an inorganic peroxide, such as hydrogen peroxide, in the presence of an enzyme catalyst having perhydrolysis activity. The present perhydrolase catalysts are classified as members of the carbohydrate esterase family 7 (CE-7) based on the conserved structural features. Further, disinfectant formulations comprising the peracids produced by the processes described herein are provided.
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公开(公告)号：US20090305366A1
公开(公告)日：2009-12-10
申请号：US12538565
申请日：2009-08-10
申请人： Robert DiCosimo , John E. Gavagan
发明人： Robert DiCosimo , John E. Gavagan
IPC分类号： C12P7/40
CPC分类号： A01N37/02 , A01N37/16 , A01N37/36 , A01N59/00 , A61L2/186 , C12P7/40 , C12P7/62 , A01N63/02 , A01N2300/00
摘要： A process is provided for producing peroxycarboxylic acids from carboxylic acid esters. More specifically, carboxylic acid esters are reacted with an inorganic peroxide, such as hydrogen peroxide, in the presence of an enzyme catalyst having perhydrolysis activity. The present perhydrolase catalysts are classified as members of the carbohydrate esterase family 7 (CE-7) based on the conserved structural features. Further, disinfectant formulations comprising the peracids produced by the processes described herein are provided.
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99.发明申请COPOLYMERS COMPRISING TRIMETHYLENE CARBONATE AND POLY(TRIMETHYLENE ETHER) GLYCOLS 有权包含三甲基碳酸酯和聚（三甲苯醚）甘油的共聚物公开(公告)号：US20090143555A1
公开(公告)日：2009-06-04
申请号：US12277616
申请日：2008-11-25
IPC分类号： C08F18/24
CPC分类号： C08G64/183 , Y10T428/31511
摘要： The present invention relates to novel copolymers comprising unsubstituted or R-substituted trimethylene carbonate and poly(trimethylene ether)glycol. The copolymers find use in areas including personal care, coatings and lubricants.
摘要翻译： 本发明涉及包含未取代或R取代的三亚甲基碳酸酯和聚（三亚甲基醚）二醇的新型共聚物。 共聚物可用于个人护理，涂料和润滑剂等领域。
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公开(公告)号：US20090011483A1
公开(公告)日：2009-01-08
申请号：US12189912
申请日：2008-08-12
申请人： Robert DiCosimo , Anna Panova , Jerrery Scott Thompson , Robert D. Fallon , Thomas Foo , F. Glenn Gallagher , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
发明人： Robert DiCosimo , Anna Panova , Jerrery Scott Thompson , Robert D. Fallon , Thomas Foo , F. Glenn Gallagher , Xu Li , George C. Fox , Joseph J. Zaher , Mark S. Payne , Daniel P. O'Keefe
IPC分类号： C12P7/42
CPC分类号： C07C51/48 , C07C51/42 , C07C51/487 , C12P7/42 , C07C59/06
摘要： A process is provided for producing glycolic acid from formaldehyde and hydrogen cyanide. More specifically, heat-treated formaldehyde and hydrogen cyanide are reacted to produce glycolonitrile having low concentrations of impurities. The glycolonitrile is subsequently converted to an aqueous solution of ammonium glycolate using an enzyme catalyst having nitrilase activity derived from Acidovorax facilis 72W (ATCC 57746). Glycolic acid is recovered in the form of the acid or salt from the aqueous ammonium glycolate solution using a variety of methods described herein.
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