摘要:
Described are monomeric fluorochemical surfactants having two perfluoroalkyl sulfonamido segments and two hydrophilic group, which are more efficient and effective in lowering the surface tension of organic solvents and water compared to other C4-based fluorochemical surfactants.
摘要:
The present invention provides a fluorochemical composition comprising: (a) one or more fluorochemical oligomers derivable from a free radical polymerization of one or more fluorinated monomers and optionally one or more non-fluorinated monomers in the presence of a chain transfer agent, said fluorochemical oligomer being free of acid groups and comprising one or more groups of the formula: -M1(R)q(Y)p−q−1 (I) wherein M1 is selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn, R represents a non-hydrolysable group, Y represents a hydrolysable group, q is 0, 1 or 2, p equals the valence of M1 and is 3 or 4 and p−q−1 is at least 1; (b) one or more non-fluorinated compounds of an element M2 selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn and having at least two hydrolysable groups per molecule in an amount sufficient to form a polycondensation product upon reaction with said fluorochemical oligomer (a); (c) water; and (d) an organic solvent in an amount sufficient to dissolve and/or disperse components (a), (b) and (c). The invention also provides compositions comprising condensates of components (a) and (b) of the above composition and a method of treatment of substrates therewith.
摘要:
The present invention provides a curable composition for use in retarding the formation of biofilms. The curable composition comprises a polymer derived from ethylenically unsaturated units having pendent long-chain aliphatic groups; ethylenically unsaturated units having pendent poly(oxyalkylene) groups; and ethylenically unsaturated units having pendent substrate-reactive groups; and a crosslinking agent.
摘要:
Fluorochemical oligomeric silanes, compositions comprising such silanes and/or the condensation products of such silanes, and coatings produced with such compositions.
摘要:
Method of forming a very hydrophobic, extremely hydrophobic or superhydrophobic surface comprising depositing a composition comprising hydrophobic microparticles, hydrophobic nanoparticles, or a mixture thereof and a binder in sufficient quantity to provide a hydrophobic or a superhydrophobic surface on a substrate having a micropatterned surface having raised portions, recessed portions or a combination thereof.
摘要:
A composition comprising at least one fluorochemical polyether silane compound having a polyfluoropolyether segment and at least two hydrolysable silane groups per molecule, one or more non-fluorinated compounds having at least two hydrolysable groups per molecule, and/or a partial condensate thereof, is disclosed. The composition provides durable water, oil and stain repellency to a substrate.
摘要:
A composition comprising the condensation product of a least one fluorochemical polyether silane compound having a polyfluoropolyether segment and at least two hydrolysable silane groups per molecule, with one or more non-fluorinated compounds having at least two hydrolysable groups per molecule, and the reaction product thereof, is disclosed. The composition provides durable water, oil and stain repellency to a substrate.
摘要:
The invention provides a method of treating of a substrate by contacting the substrate with a fluorochemical composition that comprises a condensation product of a di- or tri-isocyanate and at least one polyether, the polyether being obtained as the reaction product of a fluorochemical substituted epoxide. Substrates treated in accordance with the invention have good stain release properties, particularly to oil stains or tea stains, so stains can be more easily removed from the treated substrate in a laundering procedure.
摘要:
The invention provides new fluorine-efficient oil- and water-repellent compositions comprising a fluorochemical oil- and water-repellent agent and a polymer extender comprising at least one percent by weight based on the weight of the extender of interpolymerized units derived from monomers containing at least one blocked or masked isocyanate function.
摘要:
An aqueous finishing agent for providing fibrous materials with a soft water and oil repellent treatment is provided. The finishing agent comprisesA) 25 to 65% by weight of a perfluoroaliphatic group-bearing water/oil-repellent agent (at least 5% by weight fluorine) in dispersion,B) 10 to 35% by weight of a dispersion of an emulsifiable polyethylene (density at 20.degree. C. at least 0.92 g/cm.sup.3, acid number at least 5) andC) 25 to 40% by weight of a fluorine-free dispersion of a soft-hand extender based on a modified hydrogen alkyl polysiloxane. A process for providing fibrous materials with a soft water and oil repellent treatment is also provided. The finishing agent provides fibrous material with excellent properties which are resistant to washing and dry cleaning and a particularly smooth, soft hand.
摘要翻译:提供了一种用于提供纤维材料以进行软斥水拒油处理的水性整理剂。 整理剂包括A)25至65重量%的分散体中含全氟脂族基团的防水/拒油剂(至少5重量%氟),B)10至35重量%的可乳化的 聚乙烯(20℃下的密度至少为0.92g / cm 3,酸值至少为5),C)25〜40重量%的基于改性氢烷基聚硅氧烷的软手化剂的无氟分散体。 还提供了一种用于提供纤维材料以进行软斥水斥油处理的方法。 整理剂提供具有优异性能的纤维材料,其耐洗涤和干洗以及特别光滑的柔软手感。