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    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, POSITIVE ELECTRODE ACTIVE MATERIAL AND METHOD OF MANUFACTURING THE SAME
    91.
    发明申请
    NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY, POSITIVE ELECTRODE ACTIVE MATERIAL AND METHOD OF MANUFACTURING THE SAME 有权
    非水电解质二次电池，正极电极活性材料及其制造方法

    公开(公告)号：US20090011336A1

    公开(公告)日：2009-01-08

    申请号：US12205270

    申请日：2008-09-05

    申请人： Takao Inoue ,  Masahisa Fujimoto ,  Masaharu Itaya

    发明人： Takao Inoue ,  Masahisa Fujimoto ,  Masaharu Itaya

    IPC分类号： H01M4/26 ,  C01G49/04 ,  C01G51/04 ,  C01G53/04 ,  C01G45/02

    CPC分类号： H01M4/525 ,  C01G45/1228 ,  C01G49/009 ,  C01G51/42 ,  C01G51/66 ,  C01G53/42 ,  C01G53/66 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2006/40 ,  H01M4/0438 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M10/0525

    摘要： As a positive electrode active material, a lithium transition metal complex oxide having a layered rock-salt structure containing lithium (Li) and containing magnesium atoms (Mg) substituted for part of lithium atoms (Li) is used. The lithium transition metal complex oxide is formed by chemical or electrochemical substitution of Mg atoms for part of Li atoms in LiCoO2, LiMnO2, LiFeO2, LiNiO2, or the like. A cell is prepared in which a negative electrode 2 and a positive electrode 1 including the lithium transition metal complex oxide (positive electrode active material) are disposed in a non-aqueous electrolyte 5 including a lithium salt, and part of Li in the lithium transition metal complex oxide is extracted by discharging the cell. Then, the electrolyte including Li is replaced with an electrolyte including Mg, and the cell is discharged, so that Mg atoms are substituted for the part of Li atoms in the lithium transition metal complex oxide.

    摘要翻译： 作为正极活性物质，使用具有锂（Li）层状岩盐结构并含有镁原子（Mg）取代部分锂原子（Li）的锂过渡金属络合物氧化物。 锂过渡金属复合氧化物通过Mg原子在LiCoO 2，LiMnO 2，LiFeO 2，LiNiO 2等中的部分Li原子的化学或电化学取代而形成。 制备电池，其中将包含锂过渡金属络合物（正极活性物质）的负极2和正极1设置在包含锂盐的非水电解质5中，并且在锂转变中的一部分Li 通过排出电池提取金属复合氧化物。 然后，将包含Li的电解质替换为包含Mg的电解质，并且电池被排出，使得Mg原子被锂过渡金属复合氧化物中的Li原子的一部分代替。

    Sodium ion secondary battery
    93.
    发明申请
    Sodium ion secondary battery 有权
    钠离子二次电池

    公开(公告)号：US20070218361A1

    公开(公告)日：2007-09-20

    申请号：US11723386

    申请日：2007-03-19

    申请人： Takao Inoue ,  Motoharu Saito ,  Masahisa Fujimoto ,  Masaharu Itaya

    发明人： Takao Inoue ,  Motoharu Saito ,  Masahisa Fujimoto ,  Masaharu Itaya

    IPC分类号： H01M4/50 ,  H01M4/52

    CPC分类号： H01M4/131 ,  H01M4/1391 ,  H01M4/505 ,  H01M4/525 ,  H01M10/054 ,  H01M10/0566 ,  H01M2004/028 ,  H01M2300/0025

    摘要： The positive electrode active material of a positive electrode includes a sodium-containing transition metal oxide (NaaLibMxO2±α). The M includes at least two of manganese (Mn), iron (Fe), cobalt (Co), and nickel (Ni). For a negative electrode, a sodium metal or a metal that forms an alloy with sodium is used. A non-aqueous electrolyte produced by dissolving an electrolytic salt (sodium salt) in a non-aqueous solvent is used. Examples of the non-aqueous solvent may include a cyclic carbonate, a chain carbonate, esters, cyclic ethers, chain ethers, nitrites, amides and a combination thereof.

    摘要翻译： 正极的正极活性物质包含含钠的过渡金属氧化物（Na 2 O 2·M 2 O 2 O 2） ±α）。 M包括锰（Mn），铁（Fe），钴（Co）和镍（Ni）中的至少两种。 对于负极，使用与钠形成合金的钠金属或金属。 使用通过将电解质盐（钠盐）溶解在非水溶剂中而制得的非水电解质。 非水溶剂的实例可包括环状碳酸酯，链状碳酸酯，酯，环醚，链醚，亚硝酸酯，酰胺及其组合。

    Non-aqueous electrolyte secondary battery
    95.
    发明申请
    Non-aqueous electrolyte secondary battery 审中-公开
    非水电解质二次电池

    公开(公告)号：US20060014076A1

    公开(公告)日：2006-01-19

    申请号：US11181894

    申请日：2005-07-15

    申请人： Kazunori Donoue ,  Takao Inoue ,  Denis Yu ,  Masahisa Fujimoto

    发明人： Kazunori Donoue ,  Takao Inoue ,  Denis Yu ,  Masahisa Fujimoto

    IPC分类号： H01M4/62 ,  H01M4/58

    CPC分类号： H01M4/5825 ,  H01M4/136 ,  H01M4/621 ,  H01M4/623 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/021 ,  H01M2004/028

    摘要： A non-aqueous electrolyte secondary battery comprises a positive electrode, a negative electrode, and a non-aqueous electrolyte. The positive electrode comprises a positive electrode mixture and a current collector, wherein the positive electrode mixture has a positive electrode active material, a binder, and a conducting agent. A lithium-containing compound having an olivine structure is used as the positive electrode active material. A copolymer of polyvinylidene fluoride, tetrafluoroethylene, and hexafluoropropylene is used as the binder. Conducting carbon powder may be used as the conducting agent. Lithium metal may be used as the negative electrode. A non-aqueous solvent in which an electrolytic salt is dissolved may be used as the non-aqueous electrolyte.

    摘要翻译： 非水电解质二次电池包括正极，负极和非水电解质。 正极包括正极混合物和集电体，其中正极混合物具有正极活性物质，粘合剂和导电剂。 使用具有橄榄石结构的含锂化合物作为正极活性物质。 使用聚偏二氟乙烯，四氟乙烯和六氟丙烯的共聚物作为粘合剂。 可以使用导电碳粉作为导电剂。 可以使用锂金属作为负极。 可以使用其中溶解电解质盐的非水溶剂作为非水电解质。

    Secondary cell
    97.
    发明授权
    Secondary cell 失效
    二次电池

    公开(公告)号：US5378561A

    公开(公告)日：1995-01-03

    申请号：US937728

    申请日：1992-09-01

    申请人： Nobuhiro Furukawa ,  Masahisa Fujimoto ,  Noriyuki Yoshinaga ,  Koji Ueno

    发明人： Nobuhiro Furukawa ,  Masahisa Fujimoto ,  Noriyuki Yoshinaga ,  Koji Ueno

    IPC分类号： C01B31/02 ,  C04B35/528 ,  H01M4/133 ,  H01M4/525 ,  H01M10/05 ,  H01M10/052 ,  H01N10/40 ,  C01B31/07

    CPC分类号： H01M4/587 ,  C04B35/528 ,  H01M10/0525 ,  H01M4/1393 ,  H01M10/058 ,  H01M4/131 ,  H01M4/133

    摘要： The present invention provides a secondary cell with an enlarged capacity, therefore enlarging a discharge capacity as well as improving charge/discharge cycle characteristics. The secondary cell has a carbon material for a negative electrode, wherein the spacing of (002) planes d.sub.002, a true density, a crystallite size in the direction of c axis Lc, a and specific surface area of the carbon material are restricted to ranges of 3.39.ANG. to 3.62.ANG., 1.70 g/cc to 2.20 g/cc, 10.ANG. to 50.ANG., and 2 m.sup.2 /g to 50 m.sup.2, respectively. The carbon material is selected from a carbon material group consisting of needle cokes, pitch cokes, and coke derived from furfuryl alcohol.

    摘要翻译： 本发明提供一种具有放大容量的二次电池，因此放大放电容量以及改善充电/放电循环特性。 二次电池具有用于负极的碳材料，其中（002）面d002的间隔，真实密度，c轴Lc方向的微晶尺寸a和碳材料的比表面积被限制在范围内 3.39 ANGSTROM至3.62 ANGSTROM，1.70 g / cc至2.20 g / cc，10 ANGSTROM至50 ANGSTROM，分别为2 m2 / g至50 m2。 碳材料选自由针状焦炭，沥青焦炭和源自糠醇的焦炭组成的碳材料组。

    Secondary battery
    98.
    发明授权
    Secondary battery 失效
    二次电池

    公开(公告)号：US5352548A

    公开(公告)日：1994-10-04

    申请号：US85631

    申请日：1993-06-30

    申请人： Masahisa Fujimoto ,  Masatoshi Takahashi ,  Koji Nishio

    发明人： Masahisa Fujimoto ,  Masatoshi Takahashi ,  Koji Nishio

    IPC分类号： H01M4/587 ,  H01M10/05 ,  H01M10/0569 ,  H01M6/16 ,  H01M4/58

    CPC分类号： H01M10/0569

    摘要： A secondary battery is comprised of a positive electrode, a negative electrode formed from a carbon composition intercalating lithium reversibly and a non-aqueous electrolyte. The non-aqueous electrolyte includes a lithium salt and a mixture of a low boiling point solvent having the boiling point of 150.degree. C. or lower and an organic solvent of vinylene carbonate or its derivative. The negative electrode may comprise a graphite, and the positive electrode may comprise a material being selected from a group consisting of metal chalcogen and metal oxide, such as V.sub.2 O.sub.5, TiS.sub.2, MoS.sub.2, LiCoO.sub.2, LiMnO.sub.2, LiNiO.sub.2, LiCrO.sub.2, LiMn.sub.2 O.sub.4 and LiFeO.sub.2. The low boiling point solvent may be selected from a group consisting of dimethyl carbonate, diethyl carbonate, 1,2-dimethoxy ethane, 1,2-diethoxy ethane and ethoxymethoxy ethane. The derivative may be provided by replacing at least one of two hydrogen atoms of the vinylene carbonate with one selected from a group consisting of a methyl group, an ethyl group and one halogen atom.

    摘要翻译： 二次电池由正电极，由可逆锂嵌入的碳组合物形成的负极和非水电解质构成。 非水电解质包括锂盐和沸点为150℃以下的低沸点溶剂与碳酸亚乙烯酯或其衍生物的有机溶剂的混合物。 负极可以包括石墨，正极可以包括选自金属硫族元素和金属氧化物如V2O5，TiS2，MoS2，LiCoO2，LiMnO2，LiNiO2，LiCrO2，LiMn2O4和LiFeO2的材料。 低沸点溶剂可以选自碳酸二甲酯，碳酸二乙酯，1,2-二甲氧基乙烷，1,2-二乙氧基乙烷和乙氧基甲氧基乙烷。 可以通过将碳酸亚乙烯酯的两个氢原子中的至少一个替换为选自甲基，乙基和一个卤素原子的一个来提供。

    Positive electrode and non-aqueous electrolyte secondary battery
    99.
    发明授权
    Positive electrode and non-aqueous electrolyte secondary battery 有权
    正极和非水电解质二次电池

    公开(公告)号：US08815449B2

    公开(公告)日：2014-08-26

    申请号：US11883815

    申请日：2006-01-20

    申请人： Takao Inoue ,  Masahisa Fujimoto ,  Kumiko Kanai

    发明人： Takao Inoue ,  Masahisa Fujimoto ,  Kumiko Kanai

    IPC分类号： H01M4/505 ,  H01M4/64 ,  H01M10/056

    CPC分类号： H01M4/134 ,  H01M4/0404 ,  H01M4/0409 ,  H01M4/0426 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/1395 ,  H01M4/505 ,  H01M4/621 ,  H01M4/625 ,  H01M4/661 ,  H01M4/70 ,  H01M10/054 ,  H01M10/0568 ,  H01M10/0569

    摘要： A material (hereinafter referred to as “positive electrode material”) including sodium manganate powder as a positive electrode active material, carbon black powder as a conductive agent, and polytetrafluoroethylene as a binder is prepared. The positive electrode material is mixed in an N-methylpyrrolidone solution to produce slurry as a positive electrode mixture. A working electrode is produced by applying the slurry on a positive electrode collector. A negative electrode containing tin or germanium is produced. The non-aqueous electrolyte is produced by adding sodium hexafluorophosphate as an electrolyte salt in a non-aqueous solvent produced by mixing ethylenecarbonate and diethyl carbonate.

    摘要翻译： 制备包含锰酸钠粉末作为正极活性物质的材料（以下称为“正极材料”），作为导电剂的炭黑粉末和作为粘合剂的聚四氟乙烯。 将正极材料混合在N-甲基吡咯烷酮溶液中以产生作为正极混合物的浆料。 通过将浆料涂布在正极集电体上来制造工作电极。 制造含有锡或锗的负极。 非水电解质是通过将六氟磷酸钠作为电解质盐加入到通过混合碳酸亚乙酯和碳酸二乙酯制备的非水溶剂中制备的。