摘要:
HIGH TEMPERATURE SHIFT CATALYSTS COMPRISING IRON OXIDE ARE PREPARED FROM SOLUTIONS OF SOLUBLE IRON SALTS BY PRECIPITATION WITH AN ORGANIC ACID REAGENT, SUCH AS OXALIC ACID, GIVING PRECIPITATES IN A VERY COARSE, EASILY-WASHED FORM. TREATMENT OF THE WELL-WASHED PRECIPITATE WITH ALKALLI REGENERATES THE ORGANIC ACID REAGENT AND GIVES A HIGHLY FLOCCULENT IRON OXIDE OF HIGH SPECIFIC SURFACE AND EXTREMELY LOW SULPHUR CONTENT. THIS IS PARTICULARLY SUITABLE FOR PROMOTION WITH PBO, WHICH IS NOTED AS BEING VERY SENSITIVE TO SULPHUR CONTAMINATION.
摘要:
A process for the preparation of non-pyrophoric nickel skeleton catalysts, in which 30 to 80 percent by weight of metallic zinc, 60 to 20 percent by weight of metallic nickel and 0 to 40 percent by weight of one or more further metals soluble in alkaline solutions are heat-treated at temperatures in the range of 880* to 1,120* C for at least 3 minutes, preferably for 10 to 30 minutes, with simultaneous protection of the surface of the melt against oxidation, the melt thus obtained is cooled at a rate not exceeding 120* /minute in the average, the alloy thus obtained is powdered or granulated, and the powdered or granulated alloy is treated with an alkali hydroxide solution of 10 - 50 percent by weight at temperatures not exceeding the boiling point of the alkaline solution.
摘要:
A Group VIII metal-tin catalyst is described in which the molar ratio of Group VIII metal to tin is about 1.7 to 15. The catalyst is prepared by heating reducible compounds of a Group VIII metal and tin in oxygen and then reducing the resulting product with hydrogen. A metallic nickel-tin composition is an example of this catalyst.
摘要:
Disclosed is a process for the production of polyhydric alcohols from carbohydrates. Also disclosed is a catalyst comprising finely divided metallic nickel and finely divided tungsten oxide supported on an inert carrier wherein the metallic nickel is from 15 to 45 percent by weight, based on total weight of catalyst, and wherein the tungsten oxide is from 0.5 to 16 percent by weight, based on the total weight of catalyst.
摘要:
THIS DISCLOSURE DESCRIBES HYDROGENATION CATALYSTS COMPRISING NICKEL OR COPPER DEPOSITED ON A HIGHLY PURE SILICA CARRIER. THE CATALYSTS ARE PREPARED BY REACTION BETWEEN A WATER SOLUBLE SALT OF THE METAL AND AN ALKALINE REAGENT SUCH AS SODIUM HYDROXIDE IN WATER. THE INSOLUBLE METALLIC COMPOUND WHICH PRECIPITATES IS WASHED AND DRIED. IT IS THEN REDUCED WITH HYDROGEN AT AN ELEVATED TEMPERATURE.
摘要:
BIMETALIC SALTS, HAVING THE GENERIC FORMULA MM''XN WHEREIN M IS A GROUP I-B METAL, M'' IS A GROUP III-A METAL, X IS A HALIDE AND N IS EQUAL TO THE SUM OF THE VALENCES OF M AND M'', ARE PREPARED BY REACTING THE HALOGEN SALTS OF THE INDIVIDUAL METALS, M AND M'', IN A SUITABLE SOLVENT. THE BIMETALLIC SALT FORMED THEREBY IS A DISCRETE MONOMERIC SPECIES AND CAN BE UTILIZED IN THE SEPARATION AND RECOVERY OF VARIOUS LIGANDS, BY PREFERENTIAL COMPLEXATION. COMPLEXATION CAN BE CONDUCTED WITH THE BIMETALLIC
SALT IN THE SOLID STATE, IN SOLUTION, OR AS A SLURRY, AND WITH THE COMPLEXIBLE LIGAND IN THE GASES OR LIQUID STATE. THE LIGAND IS RECOVERED BY DECOMPLEXATION OF THE BIMETALLIC SALT-LIGAND COMPLEX OR BY DISPLACEMENT OF THE COMPLEXED LIGAND WITH ANOTHER LIGAND.
摘要:
A novel hydrogenation catalyst, especially useful for the catalytic hydrogenation of an anthraquinone working compound in the process for producing hydrogen peroxide, is described containing at least 0.05 percent by weight of metallic palladium dispersed on alumina supporting spheres, wherein the major crystalline structure of the alumina spheres is in the form of delta-alumina, theta-alumina, or mixtures of delta- and thetaaluminas and is substantially free of alpha-alumina, gammaalumina or alpha-alumina monohydrate, wherein the alumina spheres have substantially no pores larger than about 0.06 micron, a BET surface area of over 20 m.2/gm., and wherein the palladium metal penetration into the pores of the supporting alumina surface is no more than about 40 or 50 microns.
摘要:
COMPLEXIBLE LIGANDS CONTAINED IN A FEED STREAM ARE COMPLEXED WITH A LIQUID SORBENT SOLUTION OF CUPROUS ALUMINUM HALIDE. THE COMPLXED COMPLEXIBLE LIGANDS ARE THEN SEPARATED BY A LIGAND EXCHANGE OPERATIONS GENERALLY REQUIRING N-1 LIGAND EXCHANGE OPERATIONS FOR N COMPLEXED COMPLEXIBLE LIGANDS TO BE SEPARATED. THE SEPARATION IN EACH LIGAND EXCHANGE OPERATION IS EFFECTED BY CONTACTING THE SEVERAL COMPLEXED COMPLEXIBLE LIGANDS WITH A STRIPPING LIGAND WHICH FORMS A MORE STABLE COMPLEX WITH THE SORBENT THAT THE COMPLEXIBLE LIGAND OR LIGANDS TO BE SEPARATED AND RECOVERED, AND EXCHANGING THE STRILPPING LIGAND FOR THE COMPLEXIBLE LIGAND OR LIGANDS IN THE SORBENT COMPLEX.
摘要:
A GERMANIUM COMPONENT IS UNIFORMLY DISPERSED THROUGHOUT A POROUS, HIGH SURFACE AREA CARRIER MATERIAL BY THE STEPS OF: FIRST, REDUCING GERMANIUM DIOXIDE WITH HYDROGEN; SECOND, DISSOLVING THE RESULTING REDUCED MATERIAL IN AN AQUEOUS SOLUTIONOF CHLORINE TO FORM A SOLUTION THEREOF; THIRD, IMPREGNATING A HIGH SURFACE AREA, POROUS CARRIER MATERIAL WITH THE RESULTING SOLTUION; AND, FINALLY DRYING AND CALCINING THE RESULTING IMPREGGNATED CARRIER MATERIAL. KEY FEATURE OF THIS METHOD OF PREPARATION INVOLVES THE USE OF THIS SOLUTION OF THE REDUCED GERMANIUM COMPOUND IN CHLORINE WATER TO IMPREGNATE THE CARRIER MATERIAL, THEREBY ACHIEVING UNIFORM DISPERSION OF THE GERMANIUM COMPONENT IN THE CARRIER MATERIAL.
摘要:
THE PYROPHORISM OF A NICKEL-ALUMINUM OR COBALTALUMINUM CATALYST CAN BE SUBSTANTIALLY LOWERED BY CONTACTING THE CATALYST WITH AN AQUEOUS SOLUTION CONTAINING AN EFFECTIVE PASSIVATING AMOUNT OF DICHROMATE OR PERMANGANATE ION.