公开(公告)号：US10513479B2

公开(公告)日：2019-12-24

申请号：US15578405

申请日：2016-05-27

申请人： Central Glass Company, Limited

发明人： Takamasa Kitamoto ,  Satoru Okamoto ,  Masahiko Tani ,  Masatomi Kanai ,  Kohei Sumida

IPC分类号： C07C17/358 ,  C07C21/18 ,  B01J27/125 ,  B01J27/135 ,  B01J37/26 ,  B01J21/04 ,  B01J21/06

摘要： A method for isomerizing a hydrohalofluoroolefin isomer to produce a corresponding hydrohalofluoroolefin isomer includes a step contacting a composition that contains at least a hydrohalofluoroolefin isomer and that has been adjusted to 100 ppm or lower in moisture concentration, with a catalyst in a gas phase, thereby obtaining a product. This method makes it possible to suppress the catalyst performance lowering.

公开(公告)号：US20190177252A1

公开(公告)日：2019-06-13

申请号：US16004515

申请日：2018-06-11

申请人： HONEYWELL INTERNATIONAL INC.

发明人： Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Hsueh S. Tung

IPC分类号： C07C17/358 ,  C07C5/22 ,  C07C21/18 ,  C07B35/08 ,  C07C17/007

摘要： Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.

公开(公告)号：US20190169102A1

公开(公告)日：2019-06-06

申请号：US16324806

申请日：2017-08-28

申请人： Arkema France

发明人： Dominique GARRAIT ,  Anne PIGAMO ,  Laurent WENDLINGER

IPC分类号： C07C17/358 ,  B01J27/32 ,  B01J27/12 ,  B01J27/128 ,  B01J27/132 ,  B01J27/138 ,  B01J35/10 ,  B01J37/26 ,  B01J38/12 ,  C07C17/25 ,  C07C17/20

摘要： The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound in the presence of a catalyst, characterized by the use, as catalyst, of a solid composition comprising at least one component containing chromium oxyfluoride or fluoride of empirical formula CrxM(1-x)OrFs, where 2r+s is greater than or equal to 2.9 and less than 6, M is a metal chosen from columns 2 to 12 of the Periodic Table of the Elements, x has a value from 0.9 to 1, s is greater than 0 and less than or equal to 6 and r is greater than or equal to 0 and less than 3, the said solid composition having a crystallinity of less than 20% by weight. The present invention also relates to the solid composition per se.

公开(公告)号：US20190016652A1

公开(公告)日：2019-01-17

申请号：US16026149

申请日：2018-07-03

申请人： Honeywell International Inc.

发明人： Daniel C. Merkel ,  Peter Scheidle ,  Haiyou Wang ,  Christian Jungong

IPC分类号： C07C17/358

摘要： The present disclosure includes various manufacturing and separation processes for the production of (Z)-1-chloro-3,3,3-trifluoropropene from (E)-1-chloro-3,3,3-trifluoropropene. The efficient separation of (Z)-1-chloro-3,3,3-trifluoropropene from unreacted (E)-1-chloro-3,3,3-trifluoropropene may allow for the ability to recycle unreacted starting materials and to maximize raw material utilization and product yields.

公开(公告)号：US10059673B2

公开(公告)日：2018-08-28

申请号：US15504294

申请日：2015-08-14

申请人： BAYER CROPSCIENCE AKTIENGESELLSCHAFT

发明人： Sergii Pazenok

IPC分类号： C07D231/16 ,  C07D231/38 ,  C07D403/04 ,  C07C17/358 ,  C07C17/26

CPC分类号： C07D231/16 ,  C07C17/26 ,  C07C17/358 ,  C07D231/12 ,  C07D231/38 ,  C07D403/04

摘要： A new process for the preparation of 5-fluoro-1H-pyrazoles of the general formula (I) as described herein and further reactions with this compound.

公开(公告)号：US20180208528A1

公开(公告)日：2018-07-26

申请号：US15745471

申请日：2016-07-14

申请人： MEXICHEM FLUOR S.A. DE C.V.

发明人： CLIVE ROBERT GIDDIS ,  FIONA LOUISE SMITH ,  JONATHAN JUNHAY MAN ,  CARA JOY CRONSHAW

IPC分类号： C07C17/358 ,  C07C17/25 ,  C07C17/21 ,  C07C19/10 ,  C07C21/18

CPC分类号： C07C17/358 ,  C07C17/04 ,  C07C17/21 ,  C07C17/25 ,  C07C19/10 ,  C07C21/18 ,  C07C2523/06 ,  C07C2523/26 ,  C07C19/08

摘要： The present invention provides a method of producing 2,3,3,3-tetrafluoropropene (HFO-1234yf), wherein the method comprises two or more reaction steps, at least one of said reaction steps comprising the production of 1,3,3,3-tetrafluoropropene (HFO-1234ze) and/or one or more HFO-1234ze precursors from one or more HFO-1234yf precursors, wherein at least a portion of the HFO-1234ze is recovered.

公开(公告)号：US09975823B2

公开(公告)日：2018-05-22

申请号：US15515322

申请日：2015-10-08

申请人： SYNGENTA PARTICIPATIONS AG

发明人： Helmars Smits

IPC分类号： C07C17/04 ,  C07C17/06 ,  C07C17/12 ,  C07C17/35 ,  C07C17/358 ,  C07C25/10

CPC分类号： C07C17/04 ,  C07C17/06 ,  C07C17/12 ,  C07C17/35 ,  C07C17/358 ,  C07C25/10 ,  C07C25/02

摘要： The present invention relates to a process for the preparation of a compound of formula I (I), comprising reacting a compound of formula II (II), with a brominating agent in the presence of an acidic catalyst to a compound of formula III (III), and reacting the compound of formula III in tetrahydrofuran or 2-methyl-tetrahydrofuran with potassium tert-butoxide to a compound of formula I.

公开(公告)号：US09567275B2

公开(公告)日：2017-02-14

申请号：US14876384

申请日：2015-10-06

申请人： MEXICHEM AMANCO HOLDING S.A. DE C.V.

发明人： Andrew Paul Sharratt ,  Leslie Richard Seddon

IPC分类号： C07C21/18 ,  C07C17/25 ,  C07B39/00 ,  C07C17/04 ,  C07C17/087 ,  C07C17/18 ,  C07C17/20 ,  C07C17/275 ,  C07C17/358 ,  C07C45/63 ,  C09K5/04 ,  C07C17/23

CPC分类号： C07C17/25 ,  B01J23/06 ,  B01J23/26 ,  C07B39/00 ,  C07B2200/09 ,  C07C17/04 ,  C07C17/087 ,  C07C17/18 ,  C07C17/206 ,  C07C17/21 ,  C07C17/23 ,  C07C17/275 ,  C07C17/358 ,  C07C21/18 ,  C07C45/63 ,  C09K5/045 ,  C09K2205/126 ,  C07C19/10 ,  C07C19/01 ,  C07C19/08 ,  C07C49/16

摘要： The invention relates to a process for preparing a C3-6 (hydro)fluoroalkene comprising dehydrohalogenating a C3-6 hydro(halo)fluoroalkane in the presence of a zinc/chromia catalyst, wherein the C3-6 (hydro)fluoroalkene produced is isomerized in the presence of the zinc/chromia catalyst.

摘要翻译： 本发明涉及一种制备C3-6（氢）氟代烯烃的方法，该方法包括在锌/氧化铬催化剂存在下使C3-6氢（卤代）氟代烷烃脱卤化氢，其中所生产的C 3-6（氢）氟代烯烃异构化为 存在锌/氧化铬催化剂。

公开(公告)号：US09463432B2

公开(公告)日：2016-10-11

申请号：US14697788

申请日：2015-04-28

申请人： Honeywell International Inc.

发明人： Hsueh Sung Tung ,  Konstantin A. Pokrovski ,  Daniel C. Merkel ,  Robert Johnson

IPC分类号： C07C17/20 ,  B01J19/24 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  B01J23/26 ,  B01J37/26

CPC分类号： B01J19/245 ,  B01J23/26 ,  B01J37/26 ,  B01J2219/00006 ,  B01J2219/24 ,  C07B2200/09 ,  C07C17/206 ,  C07C17/25 ,  C07C17/358 ,  C07C17/383 ,  Y02P20/125 ,  Y02P20/582 ,  C07C21/18

摘要： The present invention relates to methods, process, and integrated systems for economically producing (E)-1-chloro-3,3,3-trifluoropropene via vapor phase and/or liquid processes.

公开(公告)号：US20160009615A1

公开(公告)日：2016-01-14

申请号：US14770860

申请日：2014-02-27

申请人： BLUE CUBE IP LLC

发明人： Matthew L. GRANDBOIS ,  Brian MURDOCH ,  Matthew M. MEYER

IPC分类号： C07C17/269 ,  C07C17/358

CPC分类号： C07C17/269 ,  C07C17/25 ,  C07C17/278 ,  C07C17/358 ,  C07C2601/02 ,  Y02P20/582 ,  C07C23/04 ,  C07C21/04

摘要： Processes for the production of chlorinated propenes are provided. The processes proceed through the production of cyclic intermediate that is thereafter readily converted to a desired chloropropane, e.g., via selective pyrolysis. The process may be conducted using starting materials that are readily commercially available and/or that may be reacted safely in standard laboratory equipment so that capital cost savings may be seen. The process does not require the use of catalysts and yet, process conditions less extreme than many conventional processes for the production of chlorinated propenes are suitable, so that raw material and utility cost savings are also possible.

摘要翻译： 提供了生产氯化丙烯的方法。 该方法通过制备环状中间体进行，其随后易于转化为所需的氯丙烷，例如通过选择性热解。 该方法可以使用容易商业获得的起始材料和/或可以在标准实验室设备中安全地反应，从而可以看到资本成本节省。 该方法不需要使用催化剂，但是，与用于生产氯化丙烯的许多常规方法相比，工艺条件更不合适，因此也可以节省原材料和公用事业成本。