Method for zinc ore extraction
    91.
    发明授权
    Method for zinc ore extraction 失效
    锌矿石提取方法

    公开(公告)号:US4171250A

    公开(公告)日:1979-10-16

    申请号:US909432

    申请日:1978-05-25

    CPC classification number: C22B19/22 C25C1/16 C25C7/04 Y02P10/234 Y02P10/236

    Abstract: A method and apparatus for extraction of zinc ore is disclosed. The zinc ore is mixed with a dilute acid, typically sulfuric acid, in a leaching process and is thereafter filtered through an appropriate number of stages. The filtration removes some of the heavier metals such as lead. Purification removes other elements, typically copper and cadmium. After purification, the filtrate is introduced on the cathode side of a tank having an anode and cathode separated by a permeable diaphragm. The elemental zinc deposits on the cathode while reconstituted acid accumulates on the anode side. The acid is recovered and recycled to the leaching step. The rate of recovery of zinc at the cathode is substantial.

    Abstract translation: 公开了一种提取锌矿的方法和装置。 在浸出过程中将锌矿石与稀酸(通常为硫酸)混合,然后通过适当数量的阶段过滤。 过滤除去一些较重的金属,如铅。 净化除去其他元素,通常是铜和镉。 纯化后,将滤液引入具有通过可渗透隔膜隔开的阳极和阴极的罐的阴极侧。 阴极上的元素锌沉积在阳极侧,而重构的酸积聚在阳极上。 将酸回收并再循环至浸出步骤。 阴极锌的回收率很大。

    Mass-transfer membrane and processes using same
    92.
    发明授权
    Mass-transfer membrane and processes using same 失效
    质量转移膜及其使用方法

    公开(公告)号:US4124458A

    公开(公告)日:1978-11-07

    申请号:US814715

    申请日:1977-07-11

    Applicant: Karl Moeglich

    Inventor: Karl Moeglich

    CPC classification number: C25C7/04 B01D61/46 B01D69/12 C25B13/04

    Abstract: A porous layer is provided on one or both surfaces of a mass-transfer membrane to enhance or modify the passage of ions. The membrane may be a film of any of a variety of polymeric materials, and the porous layer may be a surface layer on the membrane or a separate porous structure placed in contact therewith. The porous layer or layers render certain normally ion-impermeable polymeric films capable of passing ions in an electrodialysis-type system.

    Abstract translation: {PG,1A多孔层设置在质量转移膜的一个或两个表面上,以增强或改变离子的通过。 膜可以是各种聚合材料中的任一种的膜,并且多孔层可以是膜上的表面层或与其接触放置的单独的多孔结构。 多孔层或多层使某些通常离子不可渗透的聚合物膜能够在电渗析型体系中通过离子。

    Apparatus for electrowinning multivalent metals
    93.
    发明授权
    Apparatus for electrowinning multivalent metals 失效
    电渗析多价金属的装置

    公开(公告)号:US4116801A

    公开(公告)日:1978-09-26

    申请号:US722916

    申请日:1976-09-13

    CPC classification number: C25C7/04 C25C3/28

    Abstract: An apparatus to electrolytically produce multivalent metals, such as titanium, from compounds thereof. The apparatus includes a suitable containing body with an anode and a cathode in compartments therein spaced apart by a foraminous metallic diaphragm. The diaphragm has a diaphragm coefficient of greater than zero to about 0.5 when the coefficient of flow is about 0.1 to about 25. A multivalent metal compound feed means is combined with the cathode compartment to supply a multivalent metal compound to a molten salt electrolyte in the cathode compartment. The apparatus is sealed from the atmosphere to avoid contamination of the bath and metal product with certain atmospheric gases. Means of providing sufficient electrical and thermal energy to operate the cell are provided.

    Abstract translation: 从其化合物电解制造多价金属如钛的设备。 该装置包括适当的容纳体,其中隔室中具有阳极和阴极,其间隔有多孔金属隔膜。 当流动系数为约0.1至约25时,膜片具有大于零至约0.5的膜片系数。多价金属化合物进料装置与阴极室结合,以将多价金属化合物供应至熔融盐电解质 阴极室。 该装置与大气密封,以避免浴和金属产品被某些大气气体污染。 提供了提供足够的电和热能来操作电池的手段。

    Method to produce multivalent metals from fused bath and metal
electrowinning feed cathode apparatus
    94.
    发明授权
    Method to produce multivalent metals from fused bath and metal electrowinning feed cathode apparatus 失效
    从熔池和金属电解提取阴极装置制备多价金属的方法

    公开(公告)号:US4113584A

    公开(公告)日:1978-09-12

    申请号:US722851

    申请日:1976-09-13

    Inventor: David R. Johnson

    CPC classification number: C25C3/28 C25C3/00 C25C7/00 C25C7/005 C25C7/04

    Abstract: Feed cathode for an electrolytic cell with a feed conduit suited to pass a metal compound therethrough from a source to an electrolyte in the cell. The feed cathode includes a member surrounding and substantially entirely enclosing at least an outlet of the conduit. The member is at least partially formed of an electrically conductive foraminous body suited to pass the electrolyte and ions of a multivalent metal compound therethrough. Preferably, the foraminous body has an electrical coefficient of greater than zero to about 1 and a flow coefficient of from about 0.1 to about 300.

    Abstract translation: 用于具有适于使金属化合物从源极通过电池中的电解质的馈电导管的电解池的进料阴极。 进料阴极包括围绕并基本上完全包围导管的至少一个出口的构件。 该构件至少部分地由适于使电解质和多价金属化合物的离子通过的导电多孔体形成。 优选地,多孔体具有大于零至约1的电系数和约0.1至约300的流动系数。

    Method for eliminating solution-level attack on cathodes during
electrolysis
    95.
    发明授权
    Method for eliminating solution-level attack on cathodes during electrolysis 失效
    电解过程中消除阴极溶液级攻击的方法

    公开(公告)号:US4104132A

    公开(公告)日:1978-08-01

    申请号:US818183

    申请日:1977-07-22

    CPC classification number: C25C7/04 C25C1/16 Y02P10/234

    Abstract: A method for electrolytic deposition of metals, particularly zinc, in which the tendency for the cathode to be attacked in the immediate vicinity of the solution level is eliminated or greatly reduced by positioning a barrier structure in the cell assembly in a manner such that it extends from slightly above to slightly below the level of the solution in the cell. The barrier, which may be of any material resistant to attack by the electrolytic solution, prevents the migration of the oxygen at the solution level and thus protects the cathode from solution level attack.

    Abstract translation: {PG,1一种用于电解沉积金属,特别是锌的方法,其中通过以一种方式将隔离结构定位在电池组件中来消除或大大降低阴极在溶液水平附近被侵蚀的趋势 使得其从略高于稍高于电池中的溶液的水平延伸。 可能具有抵抗电解溶液侵蚀的任何材料的阻挡层防止氧在溶液水平上迁移,从而保护阴极不受溶液水平的侵蚀。

    Anode assembly for electrodeposition cell
    98.
    发明授权
    Anode assembly for electrodeposition cell 失效
    电沉积池阳极组件

    公开(公告)号:US4085026A

    公开(公告)日:1978-04-18

    申请号:US694324

    申请日:1976-06-09

    CPC classification number: C25C7/04

    Abstract: An anode, particularly an anode basket, having on its exterior surface a layer of open, non-woven fibrous mat to protect the anode from accidental contact with a cathode or with an electrically conducting member in contact with the cathode.

    Abstract translation: 阳极,特别是阳极筐,在其外表面上具有一层开放的非织造纤维垫,以保护阳极不与阴极意外接触或与阴极接触的导电构件。

    Electrolytic recovery of nickel and zinc
    99.
    发明授权
    Electrolytic recovery of nickel and zinc 失效
    镍和锌的电解回收

    公开(公告)号:US4073709A

    公开(公告)日:1978-02-14

    申请号:US609812

    申请日:1975-09-02

    CPC classification number: C25C1/00

    Abstract: An electrolyte process for the recovery of nickel or zinc from solutions wherein the anions are substantially purely chloride comprises introducing the solution into a cathode compartment of an electrolytic cell which is divided into three compartments namely an anode compartment, a cathode compartment, and an electrolyte compartment therebetween, the anode compartment being defined by a porous diaphragm of low permeability which separates the anolyte from the electrolyte, the anolyte comprising a solution containing anions which have an oxidation potential sufficiently high to ensure that substantially only the decomposition of water takes place at the anode under operating conditions and wherein the cathode compartment is defined by a diaphragm of relatively high permeability.

    Abstract translation: 用于从其中阴离子基本上纯氯化物的溶液中回收镍或锌的电解质方法包括将溶液引入电解池的阴极室中,该阴极室被分成三个室,即阳极室,阴极室和电解质室 在此之间,阳极室通过将阳极电解液与电解质分离的低渗透性的多孔隔膜限定,阳极电解液包含含有足够高的氧化电位的阴离子的溶液,以确保在阳极基本上只发生水的分解 在操作条件下,并且其中阴极室由具有较高磁导率的隔膜限定。

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