公开(公告)号：US10584192B2

公开(公告)日：2020-03-10

申请号：US16097103

申请日：2017-04-24

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Simona Guidotti ,  Tiziano Dall'Occo ,  Dario Liguori ,  Giampiero Morini

IPC: C08F10/02

Abstract: The present disclosure provides a solid catalyst component obtainable by a process including: (a) a first step in which Ti(OEt)4, is reacted with a Mg based compound of formula MgCln(ORI)2-n, where n is from about 0.5 to about 1.5, RI is a C1-C10 alkyl groups, the Ti(OEt)4 and the Mg compound are used in amounts such that the Ti/Mg molar ratio is of about 0.2 to about 0.4, the reaction temperature is about 110 to about 130° C., and the reaction time is about 2 to about 5 hours; and (b) a subsequent step in which the product obtained in step (a) is reacted with a Ti compound of the formula Ti(ORI)4-yCly, where y is a number between 3 and 4.

公开(公告)号：US10562990B2

公开(公告)日：2020-02-18

申请号：US15759143

申请日：2016-08-30

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Fabrizio Piemontesi ,  Gianni Vitale ,  Dario Liguori ,  Giampiero Morini

IPC: B01J23/18 ,  C08F4/20 ,  C08F4/18 ,  B01J21/06 ,  C08F10/06

Abstract: A catalyst for the homopolymerization or copolymerization of CH2═CHR olefins, made from or containing the product obtained by contacting: (i) a solid catalyst component made from or containing Ti, Mg, Cl, and an internal electron donor compound, wherein the solid catalyst component contains from about 0.1 to about 50 wt % of Bi, based upon the total weight of the solid catalyst component; (ii) an alkyl aluminum compound and, (iii) an external electron donor compound having the formula: (R1)aSi(OR2)b wherein R1 and R2 are independently selected from the group consisting of alkyl radicals with 1-8 carbon atoms and a is 0 or 1 and a+b=4.

公开(公告)号：US10544271B2

公开(公告)日：2020-01-28

申请号：US15435014

申请日：2017-02-16

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Giampaolo Pellegatti ,  Michele Grazzi ,  Nicolas Kokel ,  Antonella Angelini

IPC: C08J5/18 ,  B29C48/10 ,  B29C48/88 ,  C08F210/06 ,  C08F10/00 ,  B29C49/00 ,  B29C49/04 ,  B29C49/64 ,  B29C48/00 ,  B29C48/21 ,  B29K23/00 ,  B29K105/00

Abstract: A copolymer of propylene with hexene-1 containing from 5 to 9% by weight of recurring units derived from hexene-1, having a melting temperature from 125 to 140° C. and Melt Flow Rate (ASTM D1238, 230/2.16 Kg) from 0.1 to 3 g/10 min., is used to produce blown films having valuable mechanical and optical properties.

公开(公告)号：US10435490B2

公开(公告)日：2019-10-08

申请号：US15750391

申请日：2016-07-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Giuseppina Maria Algozzini ,  Diego Brita ,  Massimo Cenci ,  Gianni Collina ,  Tiziano Dall'occo ,  Maria Di Diego ,  Benedetta Gaddi ,  Ofelia Fusco ,  Giampiero Morini ,  Lorella Pedriali

IPC: C08F110/02 ,  C08F110/06 ,  C08F10/06 ,  C08F2/34 ,  C08F4/649 ,  C08F4/651

Abstract: A Prepolymerized catalyst component for the polymerization of olefins comprising a solid catalyst component which comprises Mg, Ti, and chlorine atoms and an electron donor (ID) said prepolymerized catalyst component being characterized by the fact that: the electron donor (ID) is constituted by at least 80% mol of 1,3 diethers with respect to the total molar amount of electron donor compounds; the prepolymerized catalyst has a porosity due to pores with diameters up to 1 μm of less than 0.2 cm3/g; it contains an amount of ethylene prepolymer of less than 45% with respect to the total weight of prepolymerized catalyst.

公开(公告)号：US20190284316A1

公开(公告)日：2019-09-19

申请号：US16317676

申请日：2017-07-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： TIZIANO DALL'OCCO ,  SIMONA GUIDOTTI ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F210/16

Abstract: A catalyst component for the polymerization of olefins, comprising Ti, Mg, halogen, an electron donor (ID) selected from the group consisting of aliphatic cyclic ethers and alkyl esters of aliphatic monocarboxylic acids and a compound of a metal selected from the group consisting of Zn and Cu, wherein the catalyst component is devoid of Zn—C or Cu—C bonds and the Mg/Ti molar ratio ranges from 4.0 to 50.0.

公开(公告)号：US20190256747A1

公开(公告)日：2019-08-22

申请号：US16312512

申请日：2017-07-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTA MARCHINI ,  STEFANO SPATARO ,  EMANUELE BURGIN ,  ROBERTA PICA

IPC: C09J123/20

Abstract: A butene-1 polymer composition having MFR values of from 400 to 2000 g/10 min, measured according to ISO 1133 at 190° C. with a load of 2.16 kg, made from or containing A) a butene-1 homopolymer or a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of up to 5% by mole; B) a copolymer of butene-1 with a comonomer selected from the group consisting of ethylene and higher alpha-olefins, having a copolymerized comonomer content of from 6% to 25% by mole; wherein the composition having a total copolymerized comonomer content from 5% to 18% by mole, referred to the sum of A) and B), and a content of fraction soluble in xylene at 0° C. of 65% by weight or more, determined on the total weight of A) and B).

公开(公告)号：US20190225720A1

公开(公告)日：2019-07-25

申请号：US16339091

申请日：2017-09-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTO DE PALO ,  CLAUDIO CAVALIERI

IPC: C08F110/08 ,  C08J5/18 ,  B29C64/245 ,  B33Y30/00

Abstract: A plate for use in an extrusion-based additive manufacturing system made from or containing a top layer made from or containing a sheet or film made from or containing 1-butene based copolymer made from or containing from 0 to 70 wt % of ethylene, propylene or alpha olefins of formula CH2═CHR, wherein R is a C3-C20 alkyl radical, based upon the weight of the 1-butene polymer.

公开(公告)号：US10316122B2

公开(公告)日：2019-06-11

申请号：US15768875

申请日：2016-10-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Paola Massari ,  Caroline Cathelin ,  Giampiero Morini ,  Fabrizio Piemontesi ,  Gianni Vitale ,  Marco Ciarafoni ,  Claudio Cavalieri ,  Roberto Pantaleoni ,  Michele Grazzi

IPC: C08F210/06 ,  C08L23/12 ,  C08L23/16 ,  C08F10/06 ,  C08F2/00 ,  C08F4/657 ,  C08F4/659

Abstract: A polypropylene composition made from or containing: A) from 50 wt % to 90 wt %; of a propylene homopolymer; B) from 10 wt % to 50 wt %; of a copolymer of propylene having from 30.0 wt % to 70.0 wt %, of ethylene derived units, based upon the total weight of the copolymer; the sum of the amount of component A) and B) being 100; the polypropylene composition having: i) an intrinsic viscosity of the fraction soluble in xylene at 25° C. between 2.2 to 4.0 dl/g; ii) a MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from 0.5 to 100 g/10 min; iii) a xylene soluble fraction ranging from 20 wt % to 50 wt %, based upon the total weight of the polypropylene composition; wherein the polypropylene composition being obtained by a polymerization process wherein the catalyst system contains bismuth.

公开(公告)号：US20190112732A1

公开(公告)日：2019-04-18

申请号：US16094647

申请日：2017-03-20

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTO DE PALO ,  CLAUDIO CAVALIERI

IPC: D01F6/30 ,  C08F210/06

CPC classification number: D01F6/30 ,  B29C64/118 ,  B33Y30/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12

Abstract: The present disclosure provides a filament for use in an extrusion-based additive manufacturing system made from or containing a propylene ethylene copolymer having: ethylene derived units content ranging from about 3.0 wt % to about 12.0 wt %, based upon the weight of the propylene ethylene copolymer; MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from about 4 to about 20 g/10 min; and xylene solubles measured at 25° C. from about 3 wt % to about 30 wt %, based upon the weight of the propylene ethylene copolymer. The disclosure further provides an extrusion-based additive manufacturing system made from or containing the filament as well as 3D printed articles prepared from the system.

公开(公告)号：US20190112402A1

公开(公告)日：2019-04-18

申请号：US16087731

申请日：2017-03-23

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTA MARCHINI ,  STEFANO SPATARO ,  STEFANO PASQUALI ,  GIANLUCA MUSACCHI

IPC: C08F210/16 ,  C08F210/02 ,  C08F210/08 ,  C08L23/20 ,  B65D53/06

Abstract: The present disclosure provides a polyolefin composition made from or containing: A) from about 60 to about 89% by weight based upon the total weight of the polyolefin composition of a copolymer of butene-1 with ethylene having a copolymerized ethylene content of up to about 18% by mole based upon the molar composition of the copolymer, and no melting peak detectable at the DSC at the second heating scan; and B) from about 11 to about 40% by weight based upon the total weight of the polyolefin composition of an ethylene polymer having density of from about 0.900 to about 0.970 g/cm3, measured according to ISO 1183 at 23° C.; wherein the amounts of A) and B) are referred to the total weight of A)+B) and the DSC second heating scan is carried out with a heating rate of 10° C. per minute. The composition is useful for preparing gaskets.