ELECTRODE MATERIALS
    115.
    发明申请
    ELECTRODE MATERIALS 有权
    电极材料

    公开(公告)号:US20110294006A1

    公开(公告)日:2011-12-01

    申请号:US13115308

    申请日:2011-05-25

    IPC分类号: H01M4/02 B05D5/12 H01M4/525

    摘要: A process for forming a surface-treatment layer on an electroactive material includes heating the electroactive material and exposing the electroactive material to a reducing gas to form a surface-treatment layer on the electroactive material, where the surface-treatment layer is a layer of partial reduction of the electroactive material.

    摘要翻译: 在电活性材料上形成表面处理层的方法包括加热电活性材料并将电活性材料暴露于还原气体,以在电活性材料上形成表面处理层,其中表面处理层是部分 还原电活性材料。

    Overcharge protection for electrochemical cells
    116.
    发明授权
    Overcharge protection for electrochemical cells 有权
    电化学电池过充保护

    公开(公告)号:US07785740B2

    公开(公告)日:2010-08-31

    申请号:US11097810

    申请日:2005-04-01

    IPC分类号: H01M10/056

    摘要: The invention relates to an improvement in a cell which is normally susceptible to damage from overcharging comprised of a negative electrode, a positive electrode, and an electrolyte comprised of an overcharge protection salt carried in a carrier or solvent. Representative overcharge protection salts are embraced by the formula: MaQ where M is an electrochemically stable cation selected from the group consisting of alkali metal, alkaline earth metal, tetraalkylammonium, or imidazolium groups, and Q is a borate or heteroborate cluster and a is the integer 1 or 2.

    摘要翻译: 本发明涉及电池的改进,该电池通常容易受到由负载电极,正电极和包含负载在载体或溶剂中的过充电保护盐构成的电解质的过充电的损害。 代表性的过充电保护盐包括下式:其中M是选自碱金属,碱土金属,四烷基铵或咪唑鎓基团的电化学稳定阳离子,Q是硼酸盐或异硼酸盐簇,a是整数 1或2。

    Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries
    119.
    发明授权
    Method and apparatus for preparation of spherical metal carbonates and lithium metal oxides for lithium rechargeable batteries 有权
    用于锂可充电电池的球形金属碳酸盐和锂金属氧化物的制备方法和装置

    公开(公告)号:US07435402B2

    公开(公告)日:2008-10-14

    申请号:US10903514

    申请日:2004-07-30

    IPC分类号: C01B31/24

    摘要: A number of materials with the composition Li1+xNiαMnβCoγM′δO2−zFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, α is between about 0.2 and 0.6, β is between about 0.2 and 0.6, γ is between about 0 and 0.3, δ is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling. Another aspect of the invention includes materials with the composition Li1+xNiαCoβMnγM′δOyFz (M′=Mg,Zn,Al,Ga,B,Zr,Ti), where the x is between 0 and 0.2, the α between 0 and 1, the β between 0 and 1, the γ between 0 and 2, the δ between about 0 and about 0.2, the y is between 2 and 4, and the z is between 0 and 0.5.

    摘要翻译: 具有以下组成的多种材料:Li 1 + x Ni 2 O 3 N 2 N 2 C 1 N 2 (M'= Mg,Zn,Al,Ga,B,Zr,Ti),用于可再充电电池,其中 x在约0和0.3之间,α在约0.2和0.6之间,β在约0.2和0.6之间,γ在约0和0.3之间,δ在约0和0.15之间,z在约0和0.2之间。 添加上述金属和氟掺杂剂影响电化学循环期间层状氧化物结构的能力,阻抗和稳定性。 本发明的另一方面包括具有以下组成的材料:具有下式的材料:Li 1 + x Ni 2 O 3 M 1 M 2 M 2 M' (M'= Mg,Zn,Al,Ga,B,Zr,Ti),其中x在 0和0.2之间,α在0和1之间,β在0和1之间,γ在0和2之间,δ在约0和约0.2之间,y在2和4之间,z在0和0.5之间 。

    Solid polymer electrolyte and method of preparation
    120.
    发明授权
    Solid polymer electrolyte and method of preparation 有权
    固体高分子电解质及其制备方法

    公开(公告)号:US07226702B2

    公开(公告)日:2007-06-05

    申请号:US10496230

    申请日:2003-01-22

    IPC分类号: H01M6/18

    摘要: Disclosed is an improved solid electrolyte made of an interpenetrating network type solid polymer comprised of two compatible phases: a crosslinked polymer for mechanical strength and chemical stability, and an ionic conducting phase. The highly branched siloxane polymer of the present invention has one or more poly(ethylene oxide) (“PEO”) groups as a side chain. The PEO group is directly grafted to silicon atoms in the siloxane polymer. This kind of branched type siloxane polymer is stably anchored in the network structure and provides continuous conducting paths in all directions throughout the IPN solid polymer electrolyte. Also disclosed is a method of making an electrochemical cell incorporating the electrolyte. A cell made accordingly has an extremely high cycle life and electrochemical stability.

    摘要翻译: 公开了一种由互穿网络型固体聚合物制成的改进的固体电解质,其包含两相相:用于机械强度和化学稳定性的交联聚合物和离子导电相。 本发明的高支化硅氧烷聚合物具有作为侧链的一个或多个聚(环氧乙烷)(“PEO”)基团。 PEO基团直接接枝到硅氧烷聚合物中的硅原子上。 这种支链型硅氧烷聚合物稳定地锚定在网状结构中,并且在整个IPN固体聚合物电解质中在所有方向上提供连续的导电路径。 还公开了制造结合电解质的电化学电池的方法。 相应制造的电池具有非常高的循环寿命和电化学稳定性。