Organofunctional siloxane mixtures
    111.
    发明申请
    Organofunctional siloxane mixtures 有权
    有机官能硅氧烷混合物

    公开(公告)号:US20070032622A1

    公开(公告)日:2007-02-08

    申请号:US10555984

    申请日:2004-03-18

    IPC分类号: C08G77/04

    CPC分类号: C08G77/26 C07F7/21 C08G77/04

    摘要: The present Invention relates to a mixture comprising catenary, branched andfor cyclic siloxanes of the general formula (I) where x is 1, 2 or 3, the substituents R are (i) organofunctional groups selected from —CH2—SH, —CH2—S—(CO)—R′, —CH2(O—C2H4)a—OH with a =1 to 10, —CH2(O—C2H4)b—OR′ with b =1 to 40, —(CH2)—NH2, —(CH2)—NHR′, —(CH2)—NR′2, —(CH2)—NH(CH2)2—NH2, —(CH2)—N[(CH2)2—NH2]2 and —(CH2) —NH(CH2)2—NH(CH2)2—NH2, In which R′ is a linear, branched or cyclic alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 12 carbon atoms, (ii) hydroxyl, methoxy, ethoxy, 2-methoxyethoxy, isopropoxy, n-propoxy, isobutoxy andfor n-butoxy groupe, and (iii) where appropriate, alkyl, alkenyl, isoalkyl, cycloalkyl or fluorcalkyl groups having 1 to 18 carbon atoms or aryl groups having 6 to 12 carbon atoms, whit the proviso that not more than one organofunctional group (i) is attached per silicon atom, the quotient of the molar ratio of the moiety (ii) to silicon le from I to 2, and the degree of oligornerization for compounds of the general formula I is in the range from 2 to 50. The present invention also relates to a specific process for preparing said siloxane mixtures and also to their use.

    摘要翻译: 本发明涉及包含通式(I)的链状,支链和环状硅氧烷的混合物,其中x为1,2或3,取代基R为(i)选自-CH 2的有机官能团 > -SH,-CH 2 -S-(CO)-R',-CH 2(OC 2 H 4) 其中a = 1至10,-CH 2(OC 2 H 4) )b = 1至40, - (CH 2)2 NH 2 - , - (CH 2) ) - NHR', - (CH 2) - NR'2, - (CH 2) - NH(CH

    Composition acting as coupling agent for filled and peroxidically crosslinking rubber compounds
    112.
    发明申请
    Composition acting as coupling agent for filled and peroxidically crosslinking rubber compounds 失效
    用作填充和过氧化交联橡胶化合物的偶联剂的组合物

    公开(公告)号:US20070032609A1

    公开(公告)日:2007-02-08

    申请号:US10524689

    申请日:2003-06-20

    摘要: The present invention relates to a composition acting as coupling agent between fillers and peroxidically crosslinking elastomers in rubber compounds, which comprises, as component comprising silicon compounds, a mixture a) of vinylalkoxysiloxanes with alkylalkoxy-siloxanes, or b) of vinylalkoxysiloxanes with phenylalkoxy-siloxanes, or c) of vinylalkoxysiloxanes with phenyl/alkyl-alkoxysiloxanes or d) of acrylic or methacrylic alkoxysiloxanes with alkylalkoxysiloxanes, or e) of acrylic or methacrylic alkoxysiloxanes with phenylalkoxysiloxanes, or f) of acrylic or methacrylic alkoxysiloxanes with phenyl/alkylalkoxysiloxanes, or g) of at least one co-oligomeric organosiloxane which, as organofunctional groups, bears at least one group from the series vinyl, acrylic and methacrylic, and at least one group from the series alkyl and phenyl, and at least one alkoxy or hydroxy group. The present invention further relates to the use of a composition of the invention as a coupling agent in filled and peroxidically crosslinking rubber compounds, to rubber compounds obtained in this way, and to items made therefrom.

    摘要翻译: 本发明涉及在橡胶化合物中作为填料和过氧化交联弹性体之间的偶联剂的组合物,其包含作为包含硅化合物的组分的乙烯基烷氧基硅氧烷与烷基烷氧基硅氧烷的混合物,或b)乙烯基烷氧基硅氧烷与苯基烷氧基硅氧烷 或c)具有苯基/烷基 - 烷氧基硅氧烷的乙烯基烷氧基硅氧烷或d)丙烯酸或甲基丙烯酸烷氧基硅氧烷与烷基烷氧基硅氧烷,或e)丙烯酸或甲基丙烯酸烷氧基硅氧烷与苯基烷氧基硅氧烷,或f)丙烯酸或甲基丙烯酸烷氧基硅氧烷与苯基/烷基烷氧基硅氧烷,或g) 的至少一种共低聚有机硅氧烷,其作为有机官能团,从乙烯基,丙烯酸和甲基丙烯酸系列中至少包含一个基团,以及至少一个来自烷基和苯基的基团,以及至少一个烷氧基或羟基。 本发明还涉及本发明的组合物作为填充和过氧化交联的橡胶化合物中的偶联剂,以这种方式获得的橡胶化合物以及由其制备的物质的用途。

    Surface-modified flame retardants containing an organic silicon composition, their use, and process for their preparation
    114.
    发明授权

    公开(公告)号:US06444315B1

    公开(公告)日:2002-09-03

    申请号:US09347534

    申请日:1999-07-06

    IPC分类号: B32B516

    摘要: An encapsulated flame retardant is made by a process including applying an organic silicon composition to a powder flame retardant. The organic silicon composition is an organofunctional-silane or a mixture of organofunctional silanes, an oligomeric organosiloxane or a mixture of oligomeric organosiloxanes, or a solvent-containing preparation based on monomeric organosilanes and/or on oligomeric organosiloxanes, or a preparation based on water-soluble organopolysiloxanes, or mixtures of any or all of these. These surface-modified flame retardants are used in particular in polymers and polymer compounds, for rendering naturally occurring materials flame retardant, and also for the intumescent coating of combustible materials.

    摘要翻译: 包封的阻燃剂通过包括将有机硅组合物施用于粉末阻燃剂的方法制备。 有机硅组合物是有机官能硅烷或有机官能硅烷,低聚有机硅氧烷或低聚有机硅氧烷的混合物或基于单体有机硅烷和/或低聚有机硅氧烷的含溶剂的制剂的混合物,或基于水溶性有机硅烷的制剂, 可溶性有机聚硅氧烷,或其中任何一种或全部的混合物。 这些表面改性阻燃剂特别用于聚合物和聚合物化合物中,用于使天然存在的材料阻燃,也用于可燃材料的膨胀涂层。

    Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use
    116.
    发明授权
    Stable compositions of water-soluble amino-and alkenyl-functional organosiloxanes, process for their preparation and their use 有权
    水溶性氨基和烯基官能的有机硅氧烷的稳定组合物,其制备方法及其应用

    公开(公告)号:US06255513B1

    公开(公告)日:2001-07-03

    申请号:US09300448

    申请日:1999-04-28

    IPC分类号: C07F710

    摘要: The present invention relates to a stable composition of water-soluble organosiloxanes obtained by reacting a) a water-soluble amino-functional alkoxysilane with at least one water-insoluble alkenyl-functional alkoxysilane b) by adding water to form a mixture, and c) removing the alcohol formed during step b) from the mixture, where the amino-functional alkoxysilane and the water are used in the reaction at least in amounts such that substantially all of the alkoxy groups of the water-insoluble silane can react and such that when a resulting composition is diluted with water, essentially no alcohol is liberated by hydrolysis, and the composition, during an/or after the reaction, has a pH of from 2 to 6, the pH being preferably adjusted by adding an organic or inorganic, optionally aqueous, acid. In addition, the present invention discloses a process for the preparation of such a composition and also its use.

    摘要翻译: 本发明涉及水溶性有机硅氧烷的稳定组合物,该组合物通过使水溶性氨基官能化烷氧基硅烷与至少一种水不溶性烯基官能烷氧基硅烷b)反应而得到,所述组合物通过加入水以形成混合物,和c)除去醇 在步骤b)中形成的步骤b)中,其中氨基官能的烷氧基硅烷和水在反应中使用至少使得水不溶性硅烷的基本上所有的烷氧基基本上可以反应,并且使得当得到的组合物 用水稀释,基本上没有通过水解释出醇,并且在反应过程中或之后,组合物的pH为2-6,优选通过加入有机或无机的任选含水酸来调节pH 。 此外,本发明公开了一种制备这种组合物的方法及其用途。