Solid polymer electrolyte and method of preparation
    121.
    发明申请
    Solid polymer electrolyte and method of preparation 有权
    固体高分子电解质及其制备方法

    公开(公告)号:US20050019667A1

    公开(公告)日:2005-01-27

    申请号:US10496230

    申请日:2003-01-22

    摘要: Disclosed is an improved solid electrolyte made of an interpenetrating network type solid polymer comprised of two compatible phases: a crosslinked polymer for mechanical strength and chemical stability, and an ionic conducting phase. The highly branched siloxane polymer of the present invention has one or more poly(ethylene oxide) (“PEO”) groups as a side chain. The PEO group is directly grafted to silicon atoms in the siloxane polymer. This kind of branched type siloxane polymer is stably anchored in the network structure and provides continuous conducting paths in all directions throughout the IPN solid polymer electrolyte. Also disclosed is a method of making an electrochemical cell incorporating the electrolyte. A cell made accordingly has an extremely high cycle life and electrochemical stability.

    摘要翻译: 公开了一种由互穿网络型固体聚合物制成的改进的固体电解质,其包含两相相:用于机械强度和化学稳定性的交联聚合物和离子导电相。 本发明的高支化硅氧烷聚合物具有作为侧链的一个或多个聚(环氧乙烷)(“PEO”)基团。 PEO基团直接接枝到硅氧烷聚合物中的硅原子上。 这种支链型硅氧烷聚合物稳定地锚定在网状结构中,并且在整个IPN固体聚合物电解质中在所有方向上提供连续的导电路径。 还公开了制造结合电解质的电化学电池的方法。 相应制造的电池具有非常高的循环寿命和电化学稳定性。

    Lithium-air batteries, method for making lithium-air batteries
    126.
    发明授权
    Lithium-air batteries, method for making lithium-air batteries 有权
    锂空气电池,制造锂空气电池的方法

    公开(公告)号:US09496590B2

    公开(公告)日:2016-11-15

    申请号:US14042203

    申请日:2013-09-30

    摘要: The invention provides a method for generating Li2O2 or composites of it, the method uses mixing lithium ions with oxygen ions in the presence of a catalyst. The catalyst comprises a plurality of metal clusters, their alloys and mixtures, each cluster consisting of between 3 and 18 metal atoms. The invention also describes a lithium-air battery which uses a lithium metal anode, and a cathode opposing the anode. The cathode supports metal clusters, each cluster consisting of size selected clusters, taken from a range of between approximately 3 and approximately 18 metal atoms, and an electrolyte positioned between the anode and the cathode.

    摘要翻译: 本发明提供了一种生成Li 2 O 2或其复合物的方法,该方法在催化剂存在下使用锂离子与氧离子混合。 催化剂包括多个金属簇,它们的合金和混合物,每个簇由3至18个金属原子组成。 本发明还描述了使用锂金属阳极和与阳极相对的阴极的锂空气电池。 阴极支撑金属簇,每个簇由尺寸选定的簇组成,取自大约3至大约18个金属原子之间的范围,以及位于阳极和阴极之间的电解质。