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    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIALS TO BIOFUELS
    171.
    发明申请
    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIALS TO BIOFUELS 审中-公开

    公开(公告)号：US20180298288A1

    公开(公告)日：2018-10-18

    申请号：US15569432

    申请日：2016-04-25

    Applicant: SHELL OIL COMPANY

    Inventor： Vikrant Nanasaheb URADE ,  Alan Anthony DEL PAGGIO ,  Laxmi Narasimhan CHILKOOR SOUNDARARAJAN

    IPC: C10G1/06 ,  C10G1/00 ,  C10G1/08 ,  C10G3/00

    Abstract: The present invention provides a process for producing liquid hydrocarbon products from solid biomass and/or residual waste feedstocks, said process comprising the steps of: a) a first stage of hydropyrolysing the solid feedstock in a hydropyrolysis reactor vessel in the presence of molecular hydrogen and one or more deoxygenation catalysts, producing a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; b) removing said char and catalyst fines from said product stream; c) a second stage of hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalysts and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), producing a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases; d) condensing the vapour phase product of step d) to 20 provide a liquid phase product comprising substantially fully deoxygenated C4+ hydrocarbon liquid and aqueous material and separating said liquid phase product from a gas phase product comprising H2, CO, CO2, and C1-C3 gases; e) removing the aqueous material from the substantially fully deoxygenated C4+ hydrocarbon liquid; and f) a third stage comprising combining an aliphatic hydrocarbon precursor or an aromatic hydrocarbon precursor with at least a portion of the substantially fully deoxygenated C4+ hydrocarbon liquid and co-processing the resultant liquid in a hydroprocessing reactor vessel in the presence of hydrogen and one or more hydroprocessing catalysts.

    PROCESS FOR THE PRODUCTION OF GLYCOLS
    172.
    发明申请
    PROCESS FOR THE PRODUCTION OF GLYCOLS 审中-公开

    公开(公告)号：US20180297920A1

    公开(公告)日：2018-10-18

    申请号：US15768034

    申请日：2016-10-18

    Applicant: SHELL OIL COMPANY

    Inventor： Duraisamy MUTHUSAMY ,  Viet Quoc NGUYEN

    IPC: C07C29/132

    Abstract: A process for the production of glycols is provided, the process comprising contacting a saccharide-containing feedstock with hydrogen in the presence of a catalyst composition and a solvent, wherein the solvent comprises water and at least 25% by weight, based on the total weight of the solvent, of one or more alcohols selected from a C1 to C6 alcohol, a C1 to C6 polyalcohol, and a combination thereof.

    COOLING DEVICE FOR A BURNER OF A GASIFICATION REACTOR
    175.
    发明申请
    COOLING DEVICE FOR A BURNER OF A GASIFICATION REACTOR 审中-公开

    公开(公告)号：US20180292088A1

    公开(公告)日：2018-10-11

    申请号：US15766595

    申请日：2016-10-10

    Applicant: SHELL OIL COMPANY

    Inventor： Alfons HEITMANN ,  Roland REIMESCH ,  Thomas Paul VON KOSSAK-GLOWCZEWSKI

    IPC: F23D14/78 ,  C10J3/74

    Abstract: A gasification reactor comprises a pressure shell; a reaction zone partly bounded by a tubular membrane wall enclosed by the pressure shell; at least one burner having a burner head, said burner head protruding the membrane wall; at least one cooling device arranged in the membrane wall and enclosing the burner head of at least one burner, the at least one cooling device comprising several concentric rings of increasing diameter, forming a truncated cone shape having a largest diameter opening facing the reaction zone and a smallest diameter opening facing the burner head, each ring being a conduit having an inlet and an outlet for a cooling medium, the smallest diameter opening for the burner head being located between the pressure shell and the membrane wall; the cooling device comprising at least one part-circular outer ring having an interruption.

    Process for preparing furfural from biomass
    176.
    发明授权
    Process for preparing furfural from biomass 有权

    公开(公告)号：US10093639B2

    公开(公告)日：2018-10-09

    申请号：US15502845

    申请日：2015-08-13

    Applicant: SHELL OIL COMPANY

    Inventor： Juben Nemchand Chheda ,  Jean Paul Andre Marie Joseph Ghislain Lange ,  Paul Richard Weider ,  Robert Lawrence Blackbourn

    IPC: C07D307/50 ,  C13K1/02 ,  C13K13/00

    Abstract: Furfural is produced from biomass material containing pentosan, in high yields, in a production process comprising treating the biomass with a solution containing at least one α-hydroxysulfonic acid thereby hydrolyzing the biomass to produce a product stream containing at least one C5-carbohydrate compound in monomeric and/or oligomeric form, and dehydrating the C5-carbohydrate compound in the presence of an acid, in a biphasic reaction medium comprising an aqueous phase and a water-immiscible organic phase, at a temperature in the range of from about 100° C. to about 250° C. to produce a dehydration product stream containing furfural. An aqueous stream is separated from the dehydration product that can be optionally recycled to the hydrolysis step.

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