Abstract:
Disclosed is a printing plate precursor comprising a substrate and provided thereon, a layer containing a light heat conversion material, wherein the light heat conversion material does not substantially change in nature when allowed to stand in a temperature atmosphere of 400 to 500null C. for 10 minutes or a printing plate precursor comprising a substrate and provided thereon, a hydrophilic layer which is porous, wherein the hydrophilic layer contains a carbon atom-free material in an amount of not less than 91% by weight.
Abstract:
A negative image recording material on which an image is formable by exposure, comprising (A) a specific polymer compound that has at least one carbon-carbon double bond in a side chain thereof and a glass transition temperature of 80null C. or more, and is soluble in an aqueous alkaline solution, (B) a light-heat converting agent, and (C) a compound that generates radicals by exposure using light of a wavelength absorbable by the light-heat converting agent. The negative image recording material may also preferably includes (D) a radical-polymerizable compound. Preferably, the (A) specific polymer compound contains at least 1.5 meq/g of the carbon-carbon double bond in the side chain thereof.
Abstract:
There is provided a lithographic printing plate precursor having good on-machine development quality, and moreover high sensitivity and high printing durability, which comprises a support having provided thereon an image forming layer containing (1) at least one ingredient selected from the group consisting of fine particles containing a compound having two or more vinyloxy groups and microcapsules encapsulating a compound having two or more vinyloxy groups, (2) a light-to-heat conversion agent, (3) a hydrophilic resin and (4) an acid precursor.
Abstract:
The present invention provides an image recording material onto which images can be recorded with an infrared ray, the material comprising an infrared absorbent (A), a radical-generating agent (B) and a radically polymerizable compound (C), wherein the infrared absorbent is a cyanine dye in which at least one substituent on a nitrogen atom in a heterocyclic ring at each end forms a cyclic ring which includes a methine chain.
Abstract:
A method to reduce effluence during or immediately after imaging of a printing plate is described. In one embodiment of the invention, the method comprises: (a) applying to a substrate a coating composition comprising a photothermal converter and at least one polymer comprising thiosulfate groups to obtain a coating; and (b) applying a water soluble topcoat to the coating. Preferably, the water soluble topcoat does not comprise a photothermal converter. In another embodiment of the invention, the method comprises applying to a substrate a composition comprising: (a) a photothermal converter; (b) at least one polymer comprising thiosulfate groups; and (c) an additive selected from the group consisting of diazonium, iodonium, copper(I), alkoxypyridinium or maleimide additives.
Abstract:
This patent describes a lithographic printing plate comprising on a substrate a semisolid radiation-sensitive layer capable of hardening upon exposure to a suitable radiation, and a method of imaging such a plate using laser radiation. The utilization of a semisolid radiation-sensitive layer allows faster photospeed and better curing efficiency as desired for digital laser exposure. Several plate designs can be utilized to overcome the tackiness issue associate with the semisolid layer, such as conformally coating the radiation-sensitive layer on a rough substrate and utilizing an overcoat. Plates having an ink and/or fountain solution or dispersible semisolid radiation-sensitive layer can be directly developed with ink and/or fountain solution while solution while mounted on press, with the imagewise laser exposure being carried out on press or off press.
Abstract:
A lithographic printing plate precursor comprising a hydrophilic support having thereon a heat-sensitive layer containing at least one of a thermoplastic particulate polymer having Tg of not lower than 60° C., a particulate polymer having a heat-reactive group and a microcapsule containing a compound having a heat-reactive group incorporated therein.
Abstract:
Provided are methods of imaging a wet positive working lithographic printing member comprising the steps of providing a positive working printing member comprising a substrate, a hydrophilic layer, an infrared-absorbing layer, and, optionally, an ink-accepting surface layer; exposing the printing member to infrared layer imaging in an imagewise pattern removing by ablation not greater than 10% by weight, and most preferably none of the infrared-absorbing layer and optional ink-accepting surface layer; and removing with water the laser-exposed areas of the infrared-absorbing layer and optional ink-accepting surface layer to reveal the underlying hydrophilic layer. These methods are advantageous in reducing airborne debris and vapors during laser imaging, in increasing the speed of laser imaging, and in providing excellent cleanability and image quality. The printing member may further comprise a primer layer underlying the infrared-absorbing layer with an adhesion-promoting agent present in the primer layer. Also provided are methods of preparing a wet lithographic printing member and wet positive working lithographic printing members prepared according to the methods of this invention.
Abstract:
A lithographic printing plate precursor comprising: a support having a water-wettable surface; and a heat-sensitive layer comprising a first resin having a hydrogen-donating group and a second resin having a hydrogen-accepting group, wherein at least one of the first resin and the second resin is particles.
Abstract:
A photopolymerizable composition that is cured with visible light or an infrared laser and is used as a recording layer in a negative planographic printing plate precursor. The photopolymerizable composition is cured by exposure and includes (A) a polymerizable compound that is solid at 25null C. and has at least one radical-polymerizable ethylenically unsaturated double bond in a molecule, (B) a radical polymerization initiator, (C) a binder polymer and, as required, (D) a compound generating heat by infrared exposure.