Refrigerant mixture substitute for chlorodifluoromethane
    11.
    发明授权
    Refrigerant mixture substitute for chlorodifluoromethane 失效
    制冷剂混合物代替氯二氟甲烷

    公开(公告)号:US06231780B1

    公开(公告)日:2001-05-15

    申请号:US09410058

    申请日:1999-10-01

    Abstract: A refrigerant composition useful as a substitute for chlorodifluoromethane (CHCIF2, HCFC-22). The refrigerant mixture has a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent selected from perfluoropropane (C3F8, PFC-218), cyclopropane (C3H6, RC-270) and butane (C4H10, R-600); and a third constituent selected from 1,1-difluoroethane (CH3CHF2, HFC-152a), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb) and bis(difluoromethyl)ether (CHF2OCHF2, HFE-134).

    Abstract translation: 用作氯代二氟甲烷(CHCIF2,HCFC-22)的替代物的制冷剂组合物。 制冷剂混合物具有二氟甲烷的第一组分(CH 2 F 2,HFC-32); 选自全氟丙烷(C3F8,PFC-218),环丙烷(C3H6,RC-270)和丁烷(C4H10,R-600)的第二种成分; 和选自1,1-二氟乙烷(CH 3 CHF 2,HFC-152a),1,1,1,2,2-五氟丙烷(CH 3 CF 2 CF 3,HFC-245cb)和双(二氟甲基)醚(CHF 2 OCH 2,HFE-134) 。

    Method for concurrently producing 1,1,1,2-tetrafluoroethane and
pentafluoroethane
    13.
    发明授权
    Method for concurrently producing 1,1,1,2-tetrafluoroethane and pentafluoroethane 失效
    同时生产1,1,1,2-四氟乙烷和五氟乙烷的方法

    公开(公告)号:US5723700A

    公开(公告)日:1998-03-03

    申请号:US708466

    申请日:1996-09-05

    CPC classification number: C07C19/08 C07C17/10 C07C17/206 C07C17/21

    Abstract: There is a method for concurrently producing 1,1,1,2-tetrafluoroethane and pentafluoroethane, which comprises (A) reacting 1,1,1-trifluoro-2-chloroethane, hydrogen fluoride and chlorine in a first reactor in the presence of flurorination catalyst at a temperature in the range of from 300.degree. C. to 450.degree. C.; (B) transfering the products of step (A) together with trichloroethylene to a second reactor and reacting them at a temperature in the range of from 200.degree. C. to 400.degree. C.; (C) separating 1,1,1,2-tetrafluoroethane and pentafluoroethane from the resultant products; and (D) feeding the remaining products from step (C) back to the first reactor, wherein the molar ratio of chlorine/1,1,1-trifluoro-2-chloroethanethe in step (A) is in the range of from 0.001 to 0.05

    Abstract translation: 有一种同时生产1,1,1,2-四氟乙烷和五氟乙烷的方法,该方法包括(A)在第一反应器中在氟化物存在下使1,1,1-三氟-2-氯乙烷,氟化氢和氯反应 催化剂在300℃至450℃的温度范围内。 (B)将步骤(A)的产物与三氯乙烯一起转移到第二反应器中,并在200℃至400℃的温度下反应。 (C)从所得产物中分离1,1,1,2-四氟乙烷和五氟乙烷; 和(D)将来自步骤(C)的剩余产物反馈回第一反应器,其中步骤(A)中氯/ 1,1,1-三氟-2-氯乙烷的摩尔比在0.001至 0。

    Method for producing silver salt-containing facilitated transport membrane for olefin separation having improved stability
    16.
    发明授权
    Method for producing silver salt-containing facilitated transport membrane for olefin separation having improved stability 失效
    一种具有改善的稳定性的含银盐促进烯烃分离输送膜的方法

    公开(公告)号:US06878409B2

    公开(公告)日:2005-04-12

    申请号:US10773257

    申请日:2004-02-09

    CPC classification number: C10G31/11 B01D53/228 B01D69/142 C07C7/144 C07C11/02

    Abstract: The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1) wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.

    Abstract translation: 本发明涉及用于从具有相似分子大小和接近沸点的石蜡中分离烯烃的聚合物膜。 更具体地说,本发明涉及一种用于烯烃分离的含银盐的促进输送膜,以及它们的制造方法。 本发明的目的是提供一种具有改进的稳定性的含银盐的促进烯烃分离的输送膜以及其制备方法,即使长时间操作也不会降低膜性能。 本发明的促进烯烃/石蜡分离的输送膜包括由下式(1)表示的聚合物,银盐和邻苯二甲酸酯化合物,其中R表示2至8个碳原子的烷基或苯基。

    Refrigerant composition for replacing chlorodifluoromethane
    17.
    发明授权
    Refrigerant composition for replacing chlorodifluoromethane 失效
    用于替代氯二氟甲烷的制冷剂组合物

    公开(公告)号:US06800216B2

    公开(公告)日:2004-10-05

    申请号:US10205264

    申请日:2002-07-24

    CPC classification number: C09K5/045 C09K2205/12 C09K2205/22 C09K2205/43

    Abstract: A refrigerant composition that can be a substitute for chlorodifluoromethane (HCFC-22) comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1-trifluoroethane, (c) a third constituent of 1,1,1,2,3,3,3-heptafluoropropane and (d) a fourth constituent selected from the group consisting of isobutane, 1,1,1,2,3,3-hexafluropropane and butane; or comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1,2-tetrafluoroethane, (c) a third constituent of 1,1,-difluoroethane, and (d) a fourth constituent selected from the group consisting of 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3-hexafluropropane and butane.

    Abstract translation: 可以代替氯二氟甲烷(HCFC-22)的制冷剂组合物包括:(a)二氟甲烷的第一组分,(b)1,1,1-三氟乙烷的第二组分,(c)1的第三组分, 1,1,2,3,3,3-七氟丙烷和(d)选自异丁烷,1,1,1,2,3,3-六氟丙烷和丁烷的第四组分; 或者包括:(a)二氟甲烷的第一组分,(b)1,1,1,2-四氟乙烷的第二组分,(c)1,1,1-二氟乙烷的第三组分,和(d)第四组分 选自1,1,1,2,3,3,3-七氟丙烷,1,1,1,2,3,3-六氟丙烷和丁烷。

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