Abstract:
A refrigerant composition useful as a substitute for chlorodifluoromethane (CHCIF2, HCFC-22). The refrigerant mixture has a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent selected from perfluoropropane (C3F8, PFC-218), cyclopropane (C3H6, RC-270) and butane (C4H10, R-600); and a third constituent selected from 1,1-difluoroethane (CH3CHF2, HFC-152a), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb) and bis(difluoromethyl)ether (CHF2OCHF2, HFE-134).
Abstract translation:用作氯代二氟甲烷(CHCIF2,HCFC-22)的替代物的制冷剂组合物。 制冷剂混合物具有二氟甲烷的第一组分(CH 2 F 2,HFC-32); 选自全氟丙烷(C3F8,PFC-218),环丙烷(C3H6,RC-270)和丁烷(C4H10,R-600)的第二种成分; 和选自1,1-二氟乙烷(CH 3 CHF 2,HFC-152a),1,1,1,2,2-五氟丙烷(CH 3 CF 2 CF 3,HFC-245cb)和双(二氟甲基)醚(CHF 2 OCH 2,HFE-134) 。
Abstract:
This invention relates to a method for preparing cycloaliphatic diamines by hydrogenating aromatic diamines in the presence of a supported ruthenium catalyst and a metal nitrite as a catalyst promoter to increase the rate of the hydrogenation reaction and decrease the amount of higher boiler by-products.
Abstract:
There is a method for concurrently producing 1,1,1,2-tetrafluoroethane and pentafluoroethane, which comprises (A) reacting 1,1,1-trifluoro-2-chloroethane, hydrogen fluoride and chlorine in a first reactor in the presence of flurorination catalyst at a temperature in the range of from 300.degree. C. to 450.degree. C.; (B) transfering the products of step (A) together with trichloroethylene to a second reactor and reacting them at a temperature in the range of from 200.degree. C. to 400.degree. C.; (C) separating 1,1,1,2-tetrafluoroethane and pentafluoroethane from the resultant products; and (D) feeding the remaining products from step (C) back to the first reactor, wherein the molar ratio of chlorine/1,1,1-trifluoro-2-chloroethanethe in step (A) is in the range of from 0.001 to 0.05
Abstract:
Disclosed are a dimethyl ether (DME)-floating, production, storage and offloading (FPSO) system that can be used in offshore oil fields or stranded gas fields and a method for producing dimethyl ether using the same. More particularly, the disclosure relates to a DME-FPSO system capable of producing dimethyl ether from gas extracted from stranded gas fields or from associated gas extracted from oil fields, which includes a reforming reactor and a dimethyl ether reactor equipped offshore, and a method for producing the same.
Abstract:
The present invention relates to a Ni-based catalyst for preparing syngas and a tri-reforming reaction of methane using the catalyst, particularly to a Ni-based catalyst, where an active ingredient (a nickel) is impregnated in a zirconia support and the zirconia is doped with a yttrium and a metal selected among a lanthanum and an alkaline earth metal to distort the crystal lattice of the zirconia, to facilitate the transfer of oxygen ion and to increase the storage and supply of oxygen, thus inhibiting the carbon deposition on the active nickel metal and maintaining the activity of the catalyst. Particularly, if the catalyst herein is used for the tri-reforming reaction of methane where a mixture of carbon dioxide, oxygen and steam is used as an oxidant, the molar ratio of hydrogen and carbon monoxide (H2/CO) in the syngas may be selectively controlled.
Abstract translation:本发明涉及一种用于制备合成气的Ni基催化剂和使用该催化剂,特别是Ni基催化剂的甲烷的三重整反应,其中活性成分(镍)浸渍在氧化锆载体中,氧化锆 掺杂有选自镧和碱土金属的钇和金属,以扭曲氧化锆的晶格,以促进氧离子的转移和增加氧的储存和供应,从而抑制碳沉积在 活性镍金属并保持催化剂的活性。 特别地,如果将本文的催化剂用于二氧化碳,氧气和蒸汽的混合物作为氧化剂的甲烷的三重整反应,则氢和一氧化碳的摩尔比(H 2 N 2 / CO)可以选择性地控制。
Abstract:
The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1) wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.
Abstract:
A refrigerant composition that can be a substitute for chlorodifluoromethane (HCFC-22) comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1-trifluoroethane, (c) a third constituent of 1,1,1,2,3,3,3-heptafluoropropane and (d) a fourth constituent selected from the group consisting of isobutane, 1,1,1,2,3,3-hexafluropropane and butane; or comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1,2-tetrafluoroethane, (c) a third constituent of 1,1,-difluoroethane, and (d) a fourth constituent selected from the group consisting of 1,1,1,2,3,3,3-heptafluoropropane, 1,1,1,2,3,3-hexafluropropane and butane.
Abstract:
A refrigerant composition that can be a substitute for chlorodifluoromethane (HCFC-22) comprises: (a) a first constituent of difluoromethane, (b) a second constituent of 1,1,1-trifluoroethane, (c) a third constituent of 1,1-difluoroethane, and (d) a fourth constituent selected from the group consisting of 1,1,1,2,3,3,3-heptafluoropropane, isobutane, 1,1,1,2,3,3-hexafluropropane and butane.
Abstract:
A catalyst of the formula (1) for the synthesis of alkylene carbonate by reacting alkylene oxide and carbon dioxide LmMXn (1) wherein L is selected from a group of pyridines; M is a metal atom selected from Zn, Fe, Mn, Pb and In; X is a halogen atom selected from Cl, Br and I; m is 1 or 2, and n is 2 or 3.
Abstract:
A catalyst for fluorination of 1,1-dichloro-1-fluoroethane which is obtained by mixing chromic hydroxide and an aqueous solution of magnesium chloride, reacting the mixture with an aqueous solution of HF and then calcining the resulting product and a process for preparing 1,1,1,-trifluoroethane by reacting 1,1-dichloro-1-fluoroethane with HF in the presence of the above catalyst are provided.