Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system
    5.
    发明申请
    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system 审中-公开
    通过碳氢化合物和电化学膜反应器系统通过二氧化碳的内部重整来共同生产合成气和电力的固体氧化物燃料电池(SOFC)

    公开(公告)号:US20090061078A1

    公开(公告)日:2009-03-05

    申请号:US12222478

    申请日:2008-08-11

    CPC classification number: H01M4/9066 H01M4/8621 H01M4/8885 H01M4/90 H01M4/9033

    Abstract: The present invention relates to a solid oxide fuel cell for internal reforming of hydrocarbons and carbon dioxide, in particular, to a solid oxide fuel cell in which one side of solid oxide electrolyte (YSZ) is attached to an air electrode (La0.8Sr0.2MnO3) and its other side is attached to a catalyst electrode of Ni-YSZ type or perovskite type metal oxide. The electrochemical conversion system using the solid oxide fuel cell permits the occurrence of internal reforming of hydrocarbons and carbon dioxide concomitantly with the coproduction of a syngas and electricity, and overcomes the shortcomings associated with the catalytic deactivation due to carbon deposition and the high-energy consumption.

    Abstract translation: 本发明涉及一种用于碳氢化合物和二氧化碳的内部重整的固体氧化物燃料电池,特别是固体氧化物燃料电池,其中固体氧化物电解质(YSZ)的一侧附着到空气电极(La0.8Sr0。 2MnO3),其另一面附着在Ni-YSZ型或钙钛矿型金属氧化物的催化剂电极上。 使用固体氧化物燃料电池的电化学转化系统允许在合成气和电力的共同生成的同时发生碳氢化合物和二氧化碳的内部重整,并且克服了由于碳沉积和高能量消耗引起的催化失活相关的缺点 。

    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system
    6.
    发明授权
    Solid oxide fuel cell(SOFC) for coproducing syngas and electricity by the internal reforming of carbon dioxide by hydrocarbons and electrochemical membrane reactor system 失效
    通过碳氢化合物和电化学膜反应器系统通过二氧化碳的内部重整来共同生产合成气和电力的固体氧化物燃料电池(SOFC)

    公开(公告)号:US07410717B2

    公开(公告)日:2008-08-12

    申请号:US10830225

    申请日:2004-04-23

    CPC classification number: H01M4/9066 H01M4/8621 H01M4/8885 H01M4/90 H01M4/9033

    Abstract: The present invention relates to a solid oxide fuel cell for internal reforming of hydrocarbons and carbon dioxide, in particular, to a solid oxide fuel cell in which one side of solid oxide electrolyte (YSZ) is attached to an air electrode (La0.8Sr0.2MnO3) and its other side is attached to a catalyst electrode of Ni-YSZ type or perovskite type metal oxide. The electrochemical conversion system using the solid oxide fuel cell permits the occurrence of internal reforming of hydrocarbons and carbon dioxide concomitantly with the coproduction of a syngas and electricity, and overcomes the shortcomings associated with the catalytic deactivation due to carbon deposition and the high-energy consumption.

    Abstract translation: 本发明涉及一种用于碳氢化合物和二氧化碳的内部重整的固体氧化物燃料电池,特别涉及一种固体氧化物燃料电池,其中固体氧化物电解质(YSZ)的一侧连接到空气电极(La 0.8 Sr 2 O 2 MnO 3 3),其另一面与Ni-YSZ型或钙钛矿型金属氧化物的催化剂电极连接。 使用固体氧化物燃料电池的电化学转化系统允许在合成气和电力的共同生成的同时发生碳氢化合物和二氧化碳的内部重整,并且克服了由于碳沉积和高能量消耗引起的催化失活相关的缺点 。

    Refrigerant mixture comprising difluromethane, pentafluroethane and 1,1,1-trifluoroethane
    7.
    发明授权
    Refrigerant mixture comprising difluromethane, pentafluroethane and 1,1,1-trifluoroethane 失效
    包含二氟甲烷,五氟乙烷和1,1,1-三氟乙烷的制冷剂混合物

    公开(公告)号:US06524495B1

    公开(公告)日:2003-02-25

    申请号:US09710578

    申请日:2000-11-09

    Abstract: A novel refrigerant composition useful as a substitute for HCFC-22, comprising a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent of pentafluoroethane (CHF2CF3, HFC-125); a third constituent of 1,1,1-trifluoroethane (CH3CF3, HFC-143a); a fourth constituent selected from the group consisting of cyclopropane (C3H6, RC-270), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), isobutane (CH(CH3)2CH3, R-600a), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), butane (C4H10, R-600), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134) and pentafluoroethylmethylether (CF3CF2OCH3, HFE-245).

    Abstract translation: 一种可用作HCFC-22替代物的新型制冷剂组合物,其包含二氟甲烷(CH 2 F 2,HFC-32)的第一组分; 五氟乙烷(CHF 2 CF 3,HFC-125)的第二组分; 1,1,1-三氟乙烷(CH 3 CF 3,HFC-143a)的第三组分; 选自环丙烷(C 3 H 6,RC-270),1,1,1,2,3,3,3-七氟丙烷(CF 3 CHFCF 3,HFC-227ea),1,1,1,2,2 (CH 3 CF 2 CF 3,HFC-245cb),异丁烷(CH(CH 3)2 CH 3,R-600a),八氟环丁烷(C 4 F 8,RC-318),1,1,1,2,3,3-六氟丙烷(CHF 2 CHFCF 3, 236EA),丁烷(C4H10,R-600),双(二氟甲基)醚(CHF2OCHF2,HFE-134)和五氟乙基甲基醚(CF3CF2OCH3,HFE-245)。

    Refrigerant mixtures containing difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-Tetrafluoroethane (HFC-134a)
    8.
    发明授权
    Refrigerant mixtures containing difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-Tetrafluoroethane (HFC-134a) 失效
    含有二氟甲烷(HFC-32),五氟乙烷(HFC-125)和1,1,1,2-四氟乙烷(HFC-134a)的制冷剂混合物,

    公开(公告)号:US06508950B1

    公开(公告)日:2003-01-21

    申请号:US09692189

    申请日:2000-10-20

    CPC classification number: C09K5/045 C09K2205/12 C09K2205/43

    Abstract: The present invention relates to novel refrigerant mixtures as a substitute for chlorodifluoromethane (CHClF2, HCFC-22). More specifically, the invention is directed to refrigerant mixtures that comprise: difluoromethane (CH2F2, HFC-32) as the first component; pentafluoroethane (CHF2CF3, HFC-125) as the second component; 1,1,1,2-tetrafluoroethane (CH2FCF3, HFC-134a) as the third component; any one of cyclopropane (C3H6, RC-270), 1,1-difluoroethane (CH3CHF2, HFC-152a), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), octafluorocyclobutane (C4F8, RC-318), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134), pentafluoroethylmethylether (CF3CF2OCH3, HFE-245), n-pentane (C5H12, R-601) and isopentane ((CH3)2CHCH2CH3, R-601a) as the fourth component. The refrigerant mixtures of the invention have working effects equal to that of HCFC-22 but does not have the risk of causing destruction to the ozone layer and can therefore be used as alternative refrigerants to HCFC-22.

    Abstract translation: 本发明涉及作为氯二氟甲烷(CHClF 2,HCFC-22)的替代物的新型制冷剂混合物。 更具体地说,本发明涉及制冷剂混合物,其包含:作为第一组分的二氟甲烷(CH 2 F 2,HFC-32);作为第二组分的五氟乙烷(CHF 2 CF 3,HFC-125); 1,1,1,2-四氟乙烷 ,HFC-134a)作为第三成分;环丙烷(C 3 H 6,RC-270),1,1-二氟乙烷(CH 3 CHF 2,HFC-152a),1,1,1,2,3,3,3-七氟丙烷 (CF 3 CHFCF 3,HFC-227ea),1,1,1,2,2-五氟丙烷(CH 3 CF 2 CF 3,HFC-245cb),八氟环丁烷(C 4 F 8,RC-318),1,1,1,2,3,3-六氟丙烷 CHF2CHFCF3,HFC-236ea),双(二氟甲基)醚(CHF2OCHF2,HFE-134),五氟乙基甲基醚(CF3CF2OCH3,HFE-245),正戊烷(C5H12,R-601)和异戊烷((CH 3)2CHCH2CH3,R-601a )作为第四个组成部分。 本发明的制冷剂混合物具有与HCFC-22相当的工作效果,但不具有对臭氧层造成破坏的风险,因此可用作HCFC-22的替代制冷剂。

    Refrigerant mixture comprising difluoromethane and 1,1,1-trifluoroethane
    10.
    发明授权
    Refrigerant mixture comprising difluoromethane and 1,1,1-trifluoroethane 失效
    包含二氟甲烷和1,1,1-三氟乙烷的制冷剂混合物

    公开(公告)号:US06231781B1

    公开(公告)日:2001-05-15

    申请号:US09410059

    申请日:1999-10-01

    Abstract: A refrigerant composition useful as a substitute for chlorodifluoromethane (CHClF2, HCFC-22). The refrigerant composition has a first constituent of difluoromethane (CH2F2, HFC-32); a second constituent of 1,1,1-trifluoroethane (CH3CF3; namely, HFC-143a); and a third constituent selected from cyclopropane (C3H6, RC-270), 1,1,1,2,3,3,3-heptafluoropropane (CF3CHFCF3, HFC-227ea), 1,1,1,2,2-pentafluoropropane (CH3CF2CF3, HFC-245cb), 1,1,1,2,3,3-hexafluoropropane (CHF2CHFCF3, HFC-236ea), butane (C4H10, R-600), bis(difluoromethyl)ether (CHF2OCHF2, HFE-134) and pentafluoroethylmethylether (CF3CF2OCH3, HFE-245).

    Abstract translation: 用作氯代二氟甲烷(CHClF 2,HCFC-22)的替代物的制冷剂组合物。 制冷剂组合物具有二氟甲烷(CH 2 F 2,HFC-32)的第一组分。 1,1,1-三氟乙烷(CH 3 CF 3,即HFC-143a)的第二组分; 和选自环丙烷(C 3 H 6,RC-270),1,1,1,2,3,3,3-七氟丙烷(CF 3 CHFCF 3,HFC-227ea),1,1,1,2,2-五氟丙烷( CH3CF2CF3,HFC-245cb),1,1,1,2,3,3-六氟丙烷(CHF2CHFCF3,HFC-236ea),丁烷(C4H10,R-600),双(二氟甲基)醚(CHF2OCHF2,HFE-134)和 五氟乙基甲基醚(CF 3 CF 2 OCH 3,HFE-245)。

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