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公开(公告)号：US5093509A
公开(公告)日：1992-03-03
申请号：US702523
申请日：1991-05-20
申请人： Robert A. Meyer , Edward T. Marquis
发明人： Robert A. Meyer , Edward T. Marquis
IPC分类号： B01J31/34 , B01J31/40 , B01J38/00 , B01J38/48 , C07B61/00 , C07C27/00 , C07C29/04 , C07C31/12 , C07D301/19 , C07D301/32
CPC分类号： C07D301/19 , B01J31/0202 , B01J31/34 , B01J31/4015 , B01J38/48 , C07D301/32 , B01J21/16 , B01J2231/72 , Y02P20/52 , Y02P20/584
摘要： An epoxidation reaction product formed by the molybdenum catalyzed reaction of propylene with tertiary butyl hydroperoxide to provide propylene oxide and tertiary butyl alcohol is separated by distillation into a propylene fraction, a propylene oxide fraction, a tertiary butyl alcohol fraction and a heavy liquid distillation fraction composed primarily of tertiary butyl hydroperoxide, tertiary butyl alcohol, dissolved molybdenum catalyst, and impurities including lower aliphatic C.sub.1 -C.sub.4 carboxylic acids, and the dissolved molybdenum content of the heavy distillation fraction is adjusted to about 300 to 500 ppm of dissolved molybdenum, if necessary, by treatment with a precipitating agent and contacted with a solid adsorbent consisting essentially of a synthetic, porous, high surface area amorphous magnesium silicate.
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12.发明授权Simultaneous epoxide and carboxylic acid manufacture by co-oxidation in the presence of a cobalt catalyst 失效在钴催化剂存在下通过共同氧化制备环氧化物和羧酸
公开(公告)号：US5068366A
公开(公告)日：1991-11-26
申请号：US563237
申请日：1990-08-06
IPC分类号： C07C51/235 , C07C51/25 , C07D301/06
CPC分类号： C07D301/06 , C07C51/235 , C07C51/252
摘要： A process for the preparation of isobutylene oxide and isobutyric acid from isobutylene and isobutyraldehyde, respectively, by a co-oxidation process conducted in the presence of oxygen and a cobalt salt catalyst at a temperature of about 20.degree. to about 180.degree. C. is disclosed.
摘要翻译： 公开了通过在约20℃至约180℃的温度下在氧和钴盐催化剂存在下进行的共氧化方法从异丁烯和异丁醛制备异丁烯和异丁酸的方法。 。
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公开(公告)号：US4980514A
公开(公告)日：1990-12-25
申请号：US444211
申请日：1989-12-01
CPC分类号： C07C49/175 , C07C45/29 , C07C45/30
摘要： Diketones useful as intermediates for reaction with carboxylic acids to provide surfactants and for reaction with amine adducts to provide fuel additives are prepared from polyoxyalkylene glycols having a molecular weight of about 200 to about 2,000 and having the formula: ##STR1## wherein R is hydrogen or methyl and wherein n is a positive number having a value of 1 to about 50,The polyoxyalkylene polyol is oxidized in the presence of a halogenated alkane solvent and a ruthenium catalyst with an alkali metal or alkaline earth metal hypochlorite at a temperature of about 10.degree. to about 50.degree. C. and a pressure of about 0 to 1,000 psig. over a period of about 10 to about 20 hours to provide the corresponding diketone having the formula: ##STR2## wherein R and n have the meaning given above.
摘要翻译： 可用作与羧酸反应以提供表面活性剂和与胺加合物反应以提供燃料添加剂的中间体的二酮由具有约200至约2,000的分子量的聚氧亚烷基二醇制备，具有下式：其中R 是氢或甲基，其中n为1至约50的正数。聚氧化烯多元醇在卤化烷烃溶剂和钌催化剂存在下，在碱金属或碱土金属次氯酸盐的存在下，在 约10℃至约50℃，压力为约0至1,000psig。 在约10至约20小时的时间内提供具有下式的相应二酮：其中R和n具有上述含义。
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14.发明授权
公开(公告)号：US4978799A
公开(公告)日：1990-12-18
申请号：US428812
申请日：1989-10-30
摘要： A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal porphyrin catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal porphyrin catalyst may be transition metal phthalocyanines, transition metalloporphines and the like. The transition metal itself may be iron, manganese, cobalt and mixtures thereof. Suitable ligands include, but are not limited to imidazoles and lithium borate. Other useful additives include alkali metal perchlorates, such as sodium perchlorate, iodosylbenzene and alkali metal superoxides, such as potassium superoxide, and phase transfer catalysts such as tetrabutyl ammonium bromide.
摘要翻译： 描述了在过渡金属卟啉催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属卟啉催化剂可以是过渡金属酞菁，过渡金属卟啉等。 过渡金属本身可以是铁，锰，钴及其混合物。 合适的配体包括但不限于咪唑和硼酸锂。 其它有用的添加剂包括碱金属高氯酸盐如高氯酸钠，碘代苯和碱金属超氧化物如超氧化钾，以及相转移催化剂如四丁基溴化铵。
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15.发明授权
公开(公告)号：US4910349A
公开(公告)日：1990-03-20
申请号：US94173
申请日：1987-09-08
IPC分类号： C07C29/132
CPC分类号： C07C29/132
摘要： Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).
摘要翻译： 通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇， 元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。
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公开(公告)号：US4722919A
公开(公告)日：1988-02-02
申请号：US916075
申请日：1986-10-06
IPC分类号： B01J31/22
CPC分类号： B01J31/223 , B01J31/4092 , B01J2231/72 , B01J2531/56
摘要： Complexes made by reacting propylene glycol with a vanadium compound soluble therein at an elevated temperature. Mild stripping of the water subsequent to complex formation is preferred. The ratio of moles of propylene glycol to gram atoms of vanadium in the complex forming reaction ranges from 7:1 to 20:1.
摘要翻译： 通过使丙二醇与可溶于其中的钒化合物在升高的温度下反应制得的络合物。 复合物形成后水的轻度汽提是优选的。 络合物形成反应中丙二醇与钒原子数的摩尔比为7:1至20:1。
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17.发明授权Purification of propylene oxide by treatment with a selected base and inert salt 失效通过用选择的碱和惰性盐处理来纯化环氧丙烷
公开(公告)号：US4691035A
公开(公告)日：1987-09-01
申请号：US851846
申请日：1986-04-14
IPC分类号： C07D301/32
CPC分类号： C07D301/32
摘要： Methyl formate is removed from propylene oxide by treatment with a selected base such as sodium hydroxide in water and glycerol. Selected inert salts may be added. The rate of methyl formate hydrolysis by selected bases was increased to commercially acceptable levels by addition of the glycerol. The glycerol and inert salts reduced the amount of residual water in the propylene oxide.
摘要翻译： 通过用选择的碱如氢氧化钠在水和甘油中处理，从环氧丙烷中除去甲酸甲酯。 可以加入选择的惰性盐。 通过加入甘油将选择的碱的甲酸甲酯水解速率提高到商业上可接受的水平。 甘油和惰性盐减少环氧丙烷中残留水的量。
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公开(公告)号：US4287364A
公开(公告)日：1981-09-01
申请号：US190531
申请日：1980-09-24
IPC分类号： B01J23/28 , C07C85/145
CPC分类号： B01J23/28
摘要： Covers a method of preparing diaminodiphenylmethanes and higher homologues thereof which comprises the step of condensing aniline and formaldehyde in the presence of a molybdenum aluminide catalyst.
摘要翻译： 包括制备二氨基二苯基甲烷及其高级同系物的方法，其包括在钼铝化物催化剂存在下使苯胺和甲醛缩合的步骤。
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公开(公告)号：US4284815A
公开(公告)日：1981-08-18
申请号：US189474
申请日：1980-09-22
IPC分类号： B01J23/30 , B01J27/047 , C07C85/18
CPC分类号： B01J27/047 , B01J23/30
摘要： Covers a method of preparing diaminodiphenylmethanes and higher homologues thereof which comprises the step of condensing aniline and formaldehyde in the presence of a tungsten boride or sulfide catalyst.
摘要翻译： 包括制备二氨基二苯基甲烷及其高级同系物的方法，其包括在硼化钨或硫化物催化剂存在下使苯胺和甲醛缩合的步骤。
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公开(公告)号：US06703033B2
公开(公告)日：2004-03-09
申请号：US09842451
申请日：2001-04-26
IPC分类号： A01N2534
CPC分类号： C11D3/2068 , A61K8/0208 , A61K8/4973 , A61Q19/10 , C11D3/201 , C11D3/2093 , C11D17/049 , Y10T442/2525
摘要： Provided herein are moist towelettes useful for cleansing, among other things, hard surfaces and human skin. The moist towelettes of the invention comprise a towelette portion which is moistened with a liquid composition of matter wherein the liquid composition includes an alkylene carbonate as one of its components. According to one preferred form of the invention, the liquid composition from which the towelettes are made moist are alcohol-free. In another embodiment, a substantial portion of the alcohol in a given formulation is replaced with an alkylene carbonate component. Preferred alkylene carbonate components include propylene carbonate, butylene carbonate, and glycerine carbonate.
摘要翻译： 本文提供了用于清洁（尤其是）硬表面和人体皮肤的湿润湿巾。 本发明的湿润毛巾包括用液体组合物润湿的毛巾部分，其中液体组合物包含碳酸亚烷基酯作为其组分之一。 根据本发明的一个优选形式，将湿巾制成湿巾的液体组合物不含醇。 在另一个实施方案中，给定制剂中的大部分醇被碳酸亚烃酯组分代替。 优选的碳酸亚烃酯组分包括碳酸亚丙酯，碳酸亚丁酯和碳酸甘油酯。
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