Flame-retardant polyester polymer dyeable with cationic dye, method of producing the same, and copolyester fiber using the same
    12.
    发明申请
    Flame-retardant polyester polymer dyeable with cationic dye, method of producing the same, and copolyester fiber using the same 失效
    用阳离子染料染色的阻燃聚酯聚合物,其制备方法和使用其的共聚酯纤维

    公开(公告)号:US20060052574A1

    公开(公告)日:2006-03-09

    申请号:US10952764

    申请日:2004-09-30

    CPC classification number: C08G63/6886 C08G63/6926 C08G63/83 D01F1/07 D01F6/84

    Abstract: Disclosed is a flame-retardant polyester polymer dyeable with a cationic dye, a method of producing the same, a copolyester fiber using the same, and fiber products using the copolyester fiber. In the method, after a dimethyl isophthalate component containing metal sulfonate of Formula 2 separately reacts with ethylene glycol so that an extent of the ester interchange reaction is 95% or more to synthesize bis(hydroxyethyl terephthalate) containing metal sulfonate of Formula 3, bis(hydroxyethyl terephthalate) is fed so that a content of bis(hydroxyethyl terephthalate) is 0.01-5 mol % based on a diacid component in a polymer in a course of producing polyester, a phosphorus-based flame retardant of Formula 1 is fed so that a content of a phosphorus atom is 500-40000 ppm based on the polymer, and the mixture is copolymerized. The polyester polymer is dyeable with cationic dye while having excellent flame retardancy, and can be melt-spun like other polymers capable of being melt-spun. The copolyester fiber using the polyester polymer is capable of being processed according to processes through which conventional polyester fibers are processed, and is dyeable with cationic dye while having excellent flame retardancy.

    Abstract translation: 公开了一种可用阳离子染料染色的阻燃聚酯聚合物,其制备方法,使用其的共聚酯纤维和使用该共聚酯纤维的纤维产品。 在该方法中,在含有式2的金属磺酸酯的二甲基间苯二甲酸酯成分分别与乙二醇反应,使得酯交换反应的程度为95%以上以合成含有式3的金属磺酸盐的双(对羟基苯甲酸羟乙酯),双 (对苯二甲酸羟乙酯)),使得在制造聚酯的过程中,基于聚合物中的二元酸成分,双(对苯二甲酸羟乙酯)的含量为0.01-5mol%,供给式1的磷系阻燃剂, 基于聚合物,磷原子的含量为500-40000ppm,并且混合物共聚。 聚酯聚合物可以用阳离子染料染色,同时具有优异的阻燃性,并且可以像能够熔融纺丝的其它聚合物一样熔融纺丝。 使用聚酯聚合物的共聚酯纤维能够根据加工常规聚酯纤维的方法进行加工,并且可以用阳离子染料染色,同时具有优异的阻燃性。

    High tenacity polyethylene-2,6-naphthalate fibers
    13.
    发明申请
    High tenacity polyethylene-2,6-naphthalate fibers 审中-公开
    高强度聚乙烯-2,6-萘二甲酸纤维

    公开(公告)号:US20050148756A1

    公开(公告)日:2005-07-07

    申请号:US10481475

    申请日:2003-10-24

    Abstract: The present invention relates to a high strength polyethylene-2,6-naphthalate fiber produced by a method comprising controlling the stress-strain curve and fine structure of an undrawn yarn such that the drawability of the undrawn yarn in a drawing step is improved. The industrial polyethylene-2,6-naphthalate fiber with high strength according to the present invention shows high strength and low shrinkage, and a treated cord formed from this fiber has improved dimensional stability and high strength, such that it can be advantageously employed as a fibrous reinforcement material of rubber products such as tires.

    Abstract translation: 本发明涉及一种高强度的聚2,6-萘二甲酸乙二醇酯纤维,它是通过控制未拉伸丝的应力 - 应变曲线和精细结构的方法制成的,使拉伸步骤中未拉伸丝的拉伸性提高。 根据本发明的具有高强度的工业聚2,6-萘二甲酸乙二醇酯纤维显示出高强度和低收缩率,并且由该纤维形成的处理帘线具有改进的尺寸稳定性和高强度,使得其可有利地用作 橡胶制品如轮胎的纤维增强材料。

    Lyocell multifilament
    14.
    发明申请
    Lyocell multifilament 有权
    Lyocell复丝

    公开(公告)号:US20050019564A1

    公开(公告)日:2005-01-27

    申请号:US10874222

    申请日:2004-06-24

    CPC classification number: D01F2/00 D02G3/48 Y10T428/2913 Y10T428/2965

    Abstract: The present invention relates to a high tenacity, high modulus and low shrinkage lyocell multifilament yarn suitable for use in tire cords and MRG (mechanical rubber goods). The lyocell multifilament yarn is a cellulose-based fiber for industrial applications, which is produced by dissolving pulp having a degree of polymerization (DPW) of 700-2,000 and preferably 800-1,400, and a α-cellulose content of more than 90% and preferably more than 92%, in N-methylmorpholine N-oxide (NMMO) hydrate, at a pulp concentration of 5-15% by weight and preferably 8-13% by weight. The lyocell monofilament according to the present invention is characterized by the following stress-strain profile: (1) the lyocell monofilament analyzed after drying is elongated by less than 3.0% and has an initial modulus of 150-400 g/d, when it was subjected to an initial stress of 3.0 g/d; (2) it is elongated by 3.0-7.0% when it was subjected to a stress greater than the initial stress but smaller than 6.0 g/d; and (3) it is elongated from a tensile tenacity of at least 6.0 g/d until the yarn is broken.

    Abstract translation: 本发明涉及适用于轮胎帘线和MRG(机械橡胶制品)的高韧性,高模量和低收缩率的莱赛尔复丝纱线。 莱赛尔复丝纱是用于工业应用的纤维素基纤维,其通过将具有700-2,000,优选800-1,400的聚合度(DPW)和大于90%的α-纤维素含量的纸浆溶解而制备,以及 优选大于92%的N-甲基吗啉N-氧化物(NMMO)水合物,纸浆浓度为5-15重量%,优选为8-13重量%。 根据本发明的裂解液单丝的特征在于以下应力 - 应变曲线:(1)干燥后分析的裂解细胞单丝伸长小于3.0%,初始模量为150-400g / d,当为 经受3.0g / d的初始应力; (2)当其施加大于初始应力但小于6.0g / d的应力时,其伸长3.0-7.0%; 和(3)从至少6.0g / d的拉伸强度拉伸至纱线断裂为止。

    Flame-retardant polyester polymer dyeable with cationic dye, method of producing the same, and copolyester fiber using the same
    15.
    发明授权
    Flame-retardant polyester polymer dyeable with cationic dye, method of producing the same, and copolyester fiber using the same 失效
    用阳离子染料染色的阻燃聚酯聚合物,其制备方法和使用其的共聚酯纤维

    公开(公告)号:US07399799B2

    公开(公告)日:2008-07-15

    申请号:US10952764

    申请日:2004-09-30

    CPC classification number: C08G63/6886 C08G63/6926 C08G63/83 D01F1/07 D01F6/84

    Abstract: Disclosed is a flame-retardant polyester polymer dyeable with a cationic dye, a method of producing the same, a copolyester fiber using the same, and fiber products using the copolyester fiber. In the method, after a dimethyl isophthalate component containing metal sulfonate of Formula 2 separately reacts with ethylene glycol so that an extent of the ester interchange reaction is 95% or more to synthesize bis(hydroxyethyl terephthalate) containing metal sulfonate of Formula 3, bis(hydroxyethyl terephthalate) is fed so that a content of bis(hydroxyethyl terephthalate) is 0.01-5 mol % based on a diacid component in a polymer in a course of producing polyester, a phosphorus-based flame retardant of Formula 1 is fed so that a content of a phosphorus atom is 500-40000 ppm based on the polymer, and the mixture is copolymerized. The polyester polymer is dyeable with cationic dye while having excellent flame retardancy, and can be melt-spun like other polymers capable of being melt-spun. The copolyester fiber using the polyester polymer is capable of being processed according to processes through which conventional polyester fibers are processed, and is dyeable with cationic dye while having excellent flame retardancy.

    Abstract translation: 公开了一种可用阳离子染料染色的阻燃聚酯聚合物,其制备方法,使用其的共聚酯纤维和使用该共聚酯纤维的纤维产品。 在该方法中,在含有式2的金属磺酸酯的二甲基间苯二甲酸酯成分分别与乙二醇反应,使得酯交换反应的程度为95%以上以合成含有式3的金属磺酸盐的双(对羟基苯甲酸羟乙酯),双 (对苯二甲酸羟乙酯)),使得在制造聚酯的过程中,基于聚合物中的二元酸成分,双(对苯二甲酸羟乙酯)的含量为0.01-5mol%,供给式1的磷系阻燃剂, 基于聚合物,磷原子的含量为500-40000ppm,并且混合物共聚。 聚酯聚合物可以用阳离子染料染色,同时具有优异的阻燃性,并且可以像能够熔融纺丝的其它聚合物一样熔融纺丝。 使用聚酯聚合物的共聚酯纤维能够根据加工常规聚酯纤维的方法进行加工,并且可以用阳离子染料染色,同时具有优异的阻燃性。

    Crosslinked polyvinyl alcohol fiber and method for producing the same
    19.
    发明申请
    Crosslinked polyvinyl alcohol fiber and method for producing the same 审中-公开
    交联聚乙烯醇纤维及其制造方法

    公开(公告)号:US20050118419A1

    公开(公告)日:2005-06-02

    申请号:US10815955

    申请日:2004-04-02

    Abstract: The present invention relates to crosslinked polyvinyl alcohol raw cord and method for producing the same, and more particularly, to crosslinked polyvinyl alcohol fiber, in which PVA resin having a degree of polymerization of more than 1,000 and a degree of saponification of more than 97.0 mol % is dissolved in dimethyl sulfoxide, the solution is subjected to dry and wet gel spinning using methanol as a coagulation solution, drawn and thermally treated, the resulting polyvinyl alcohol drawn yarn with 500-3,000 deniers is twisted to produce a cabling yarn, the cabling yarn is plied into a 2-ply or 3-ply yarn to produce a raw cord, the raw cord is wound on a bobbin for crosslinking and crosslinked in an aqueous crosslinking solution containing an aromatic aldehyde compound and an acid catalyst. Moreover, the present invention relates to a crosslinker-introducing apparatus, which is used in the above method and can effectively induce the crosslinking reaction of the wound raw cord.

    Abstract translation: 本发明涉及交联聚乙烯醇原丝及其制造方法,更具体地说,涉及交联聚乙烯醇纤维,其中聚合度大于1000的PVA树脂和皂化度大于97.0mol 将%溶解于二甲基亚砜中,用甲醇作为凝固溶液进行干燥和湿式凝胶纺丝,拉伸和热处理,得到500-3,000旦尼尔的聚乙烯醇拉伸纱线,扭曲生产布线纱线,布线 将纱线拼合成2层或3层纱以产生生绳,将生绳缠绕在线轴上,以在含有芳族醛化合物和酸催化剂的交联水溶液中进行交联和交联。 此外,本发明涉及一种交联剂引入装置,其用于上述方法中并且可以有效地诱导伤口原始绳索的交联反应。

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