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公开(公告)号：US4503272A
公开(公告)日：1985-03-05
申请号：US496696
申请日：1983-05-20
Applicant: James G. Bennett, Jr. , Freddie L. Tungate , John J. Kokoszka
Inventor： James G. Bennett, Jr. , Freddie L. Tungate , John J. Kokoszka
CPC classification number: C07C37/16
Abstract: A process for making ortho-alkylated phenols by reacting in the vapor phase an alkyl alcohol and a phenolic compound in the presence of an alkylation catalyst, said catalyst provided by a calcination residue of mixture comprising a magnesium-containing material and manganese hydroxide formed as a precipitate by bringing together an aqueous solution of a manganese salt and an aqueous solution of ammonium hydroxide in the presence of said magnesium-containing material.
Abstract translation: 一种通过在烷基醇和酚类化合物的存在下在烷基化催化剂的存在下在气相中反应制备邻烷基化酚的方法，所述催化剂由包含含镁材料和氢氧化锰的混合物的煅烧残余物提供，所述氢氧化物形成为 在所述含镁材料存在下，将锰盐水溶液和氢氧化铵水溶液接合在一起沉淀。
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12.发明授权Method for preparing compositions of a polyphenylene ether resin and an alkenyl aromatic addition polymer using an alkenyl aromatic monomer as the solvent 失效使用亚苄基芳族单体作为溶剂制备聚苯乙烯树脂和亚苄基芳族添加聚合物的组合物的方法
公开(公告)号：US4152369A
公开(公告)日：1979-05-01
申请号：US401987
申请日：1973-10-01
Applicant: James G. Bennett , Glenn D. Cooper , Arthur Katchman
Inventor： James G. Bennett , Glenn D. Cooper , Arthur Katchman
IPC: C08L25/00 , C08F2/00 , C08F2/44 , C08F212/00 , C08F283/08 , C08G65/00 , C08G65/38 , C08L71/00 , C08L71/12
CPC classification number: C08F283/08
Abstract: A novel process is provided for preparing a blend of a polyphenylene ether resin and an alkenyl aromatic addition polymer which comprises using an alkenyl aromatic monomer as a solvent for the oxidative coupling of a phenol to form a polyphenylene ether resin and thereafter polymerizing the alkenyl aromatic monomer to form said blend of alkenyl aromatic addition polymer and a polyphenylene ether resin.
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公开(公告)号：US5084551A
公开(公告)日：1992-01-28
申请号：US626598
申请日：1990-12-12
Applicant: Timothy D. Shaffer , James G. Bennett, Jr. , Mark R. Denniston
Inventor： Timothy D. Shaffer , James G. Bennett, Jr. , Mark R. Denniston
IPC: C08G65/38 , C08G65/44 , C08L23/00 , C08L67/00 , C08L69/00 , C08L71/00 , C08L71/12 , C08L77/00 , C08L79/08
Abstract: The invention provides a process for producing a polyphenylene ether by subjecting a 2,6-dialkyl-4-halophenol to oxygen in the presence of a water-immiscible solvent, an aqueous alkali, a phase transfer agent, and a molecular-weight-controlling amount of an amine having at least one hydrogen on the amine nitrogen. The polyphenylene ether thus produced has improved flow properties, color and odor, and is suitable for polymer blending with styrenic resins.
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14.发明授权Ortho-alkylation catalysts based on magnesium and prepared by calcining in presence of feed mixture of reactants 失效基于镁的正烷基化催化剂，并通过在反应物的进料混合物存在下煅烧制备
公开(公告)号：US4900708A
公开(公告)日：1990-02-13
申请号：US547482
申请日：1983-11-01
Applicant: James G. Bennett , Freddie L. Tungate
Inventor： James G. Bennett , Freddie L. Tungate
Abstract: Ortho-alkylated phenols are prepared by reacting phenol unsubstituted in at least one ortho position with an alcohol in the presence of an ortho-alkylation catalyst consisting of magnesium carbonate, magnesium hydroxide or a mixture of both. The catalyst is used in the absence of a promoter compound and with or without polymeric binder.
Abstract translation: 在由碳酸镁，氢氧化镁或它们的混合物组成的邻位烷基化催化剂的存在下，使至少一个邻位的未取代苯酚与醇反应来制备正烷基化酚。 该催化剂用于不存在助催化剂化合物并且具有或不具有聚合物粘合剂。
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15.发明授权Magnesium-containing catalyst activated under vacuum, in nitrogen, or in air, and use in an ortho-alkylation process 失效在真空，氮气或空气中活化的含镁催化剂，并用于邻位烷基化工艺
公开(公告)号：US4851591A
公开(公告)日：1989-07-25
申请号：US133748
申请日：1987-12-16
Applicant: Richard A. Battista , James G. Bennett, Jr. , John J. Kokoszka , Freddie L. Tungate
Inventor： Richard A. Battista , James G. Bennett, Jr. , John J. Kokoszka , Freddie L. Tungate
Abstract: A catalyst precursor comprising a magnesium compound or material, optionally also containing other metal compounds, is activated for use by calcining at an elevated temperature in the presence of air or nitrogen, or under vacuum. The active catalyst which results may be used in processes for the ortho-alkylation of phenolic compounds, with good yields of and selectivity to the ortho-alkylated end product.
Abstract translation: 包含镁化合物或材料（任选地还含有其它金属化合物）的催化剂前体通过在空气或氮气存在下或在真空下在升高的温度下煅烧而被活化。 所得的活性催化剂可用于酚类化合物的邻烷基化方法，具有良好的邻烷基化终产物的产率和选择性。
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Patent Agency Ranking16.发明授权
公开(公告)号：US4554267A
公开(公告)日：1985-11-19
申请号：US500684
申请日：1983-06-03
Applicant: Gregory R. Chambers , James G. Bennett, Jr.
Inventor： Gregory R. Chambers , James G. Bennett, Jr.
IPC: B01J23/72 , B01J23/74 , B01J23/78 , C07B61/00 , C07C27/00 , C07C37/11 , C07C37/16 , C07C39/06 , C07C67/00 , B01J23/76
Abstract: Hydroxyaromatic compounds such as phenol are alkylated with alkanols such as methanol in the presence of a catalyst comprising magnesium oxide with up to about 0.1% by weight of copper deposited thereon in a layer of submicroscopic thickness. The catalyst is prepared by preparing a slurry of a substantially water-insoluble magnesium reagent such as magnesium hydroxide or magnesium carbonate in an aqueous solution of at least one copper salt, removing and drying the solid phase, and calcining the same at a temperature within the range of about 350.degree.-550.degree. C. The catalyst promotes ortho-alkylation of the hydroxyaromatic compound in high yield, minimizes decomposition of the alkanol, and has long life.
Abstract translation: 羟基芳族化合物如苯酚在含有氧化镁的催化剂存在下，用链烷醇如甲醇进行烷基化，其中沉积有至少约0.1％（重量）的铜在亚显微厚度的层中。 通过在至少一种铜盐的水溶液中制备基本上不溶于水的镁试剂如氢氧化镁或碳酸镁的浆料来制备催化剂，除去和干燥固相，并在其内的温度下煅烧催化剂 范围约350〜-550℃。催化剂以高产率促进羟基芳族化合物的邻位烷基化，使链烷醇的分解最小化，寿命长。
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17.发明授权
公开(公告)号：US4458031A
公开(公告)日：1984-07-03
申请号：US356309
申请日：1982-03-09
Applicant: Richard A. Battista , James G. Bennett, Jr. , John J. Kokoszka
Inventor： Richard A. Battista , James G. Bennett, Jr. , John J. Kokoszka
Abstract: Disclosed are a catalyst comprising a magnesium-containing moiety, a method for preparing the catalyst, and a process for the vapor phase ortho-alkylation of phenols in the presence of the catalyst.
Abstract translation: 公开了包含含镁部分的催化剂，制备催化剂的方法，以及在催化剂存在下苯酚的气相邻烷基化方法。
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公开(公告)号：US4373064A
公开(公告)日：1983-02-08
申请号：US246383
申请日：1981-03-23
Applicant: James G. Bennett, Jr. , Gim F. Lee, Jr.
Inventor： James G. Bennett, Jr. , Gim F. Lee, Jr.
CPC classification number: C08L51/04 , C08L71/123
Abstract: There are provided thermoplastic compositions comprising a polyphenylene ether and a rubber modified polystyrene resin having a discontinuous phase of polystyrene particles englobed in diene rubber membranes, the particles being between about 0.1 and 0.7 microns in diameter. Such compositions provide molded articles with substantial and unexpected improvements in impact resistance and ability to transmit light in comparison with known compositions of such rubber modified polystyrenes alone or those of other polystyrenes combined with polyphenylene ethers.
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公开(公告)号：US4097459A
公开(公告)日：1978-06-27
申请号：US428450
申请日：1973-12-26
Applicant: James G. Bennett , Glenn D. Cooper
Inventor： James G. Bennett , Glenn D. Cooper
CPC classification number: C08G65/46
Abstract: An improved process is disclosed for preparing polyphenylene ethers in which a polyamine complexing agent is employed to terminate the oxidative coupling reaction and to remove the metal component of the catalyst from the polymer.
Abstract translation: 公开了用于制备聚苯醚的改进方法，其中使用多胺络合剂终止氧化偶联反应并从聚合物中除去催化剂的金属组分。
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公开(公告)号：US4032512A
公开(公告)日：1977-06-28
申请号：US564127
申请日：1975-04-01
Applicant: James G. Bennett , Glenn D. Cooper
Inventor： James G. Bennett , Glenn D. Cooper
IPC: C08G65/44
CPC classification number: C08G65/44
Abstract: An improved process is provided for preparing polyphenylene ethers by oxidatively coupling a di-ortho substituted phenolic precursor in a reaction system containing oxygen at a pressure of more than one atmosphere, and a complex catalyst formed from a cupric halide and a primary or secondary amine catalyst.
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