摘要:
Disclosed is a method for preparing a cathode active material for a lithium secondary battery, and the preparing method includes: adding a phosphorus compound to a transition metal oxide dispersion liquid to prepare a coating liquid; drying the coating liquid to prepare a powder including phosphorus oxide coated on the surface of the transition metal oxide; and dry-mixing the powder coated with the phosphorus oxide with a lithium intercalation compound, and then firing the mixture to form a solid solution compound of Li-M1-M2-P—O (where M1 is a transition metal derived from transition metal oxide, and M2 is a metal derived from lithium intercalation compound) on the surface of the lithium intercalation compound.The method for preparing a cathode active material for a lithium secondary battery simplifies the conventional preparing process to save process cost, and it provides comparable electrochemical characteristics to a cathode active material obtained from a wet process.
摘要:
Provided are a method for forming a cathode active material powder for a lithium secondary cell, and a cathode active material powder prepared using the method. According to the method, a coating layer consisting of a combination of a water-soluble polymer and a metal oxide may be formed on the particle surface of the cathode active material, thereby forming a uniform thickness of the coating layer. Thus, the elution of manganese may be prevented, thereby improving the capacity of the cathode active material and providing excellent cycle characteristics.
摘要:
The present invention relates to a positive active material for an electrochemical cell including a compound having a nano-shape and represented by the following Formula 1. Lix[Li1-y-zM1yM2z]O2-αDα [Formula 1] wherein, 0.8≦x≦1.1, 0≦y≦0.5, 0≦z≦0.5, and 0≦α≦0.05, M1 and M2 are independently selected from transition elements, and D is selected from the group consisting of O, F, S, P, and combinations thereof. The positive active material of the present invention has high reversible capacity and an excellent cycle life characteristic, and in particular, an excellent cycle life characteristic at a high rate.
摘要翻译:本发明涉及一种用于电化学电池的正极活性材料,其包括具有纳米形状并由下式1表示的化合物.Lix [Li1-y-zM1yM2z] O2-αDalpha[式1]其中0.8 <= x <= 1.1,0 <= y <= 0.5,0 <= z <= 0.5,0 <=α<= 0.05,M1和M2独立地选自过渡元素,D选自O, F,S,P及其组合。 本发明的正极活性物质具有高的可逆容量和优异的循环寿命特性,特别是高速率的优异的循环寿命特性。
摘要:
The present invention relates to negative-electrode active material for a lithium secondary battery exhibiting excellent capacity property and cycle life property, a method of preparing the same, and a lithium secondary battery using the negative-electrode active material, wherein the negative-electrode active material for a lithium secondary battery comprises a nanotube having a tube shape defined by an outer wall with a thickness of nanoscale, the outer wall of the nanotube comprises at least one non-carbonaceous material selected from the group consisting of silicon, germanium and antimony, and an amorphous carbon layer with a thickness of 5 nm or less is formed on the outer wall of the nanotube.
摘要:
The positive active material according to one embodiment of the present invention includes a composite metal oxide of the following Formula 1, and a compound being capable of intercalating and deintercalating lithium having the composite metal oxide coated on the surface thereof. M1-xAlO2 [Chemical Formula 1] Wherein, in the above Formula 1, M is selected from the group consisting of an alkali metal, an alkaline-earth metal, and combinations thereof, and 0.03≦x≦0.95. The composite metal oxide increases impregnation of an electrolyte, improves lithium mobility, and decreases internal resistance of a rechargeable lithium battery, and thereby improves discharge capacity and cycle-life characteristics.
摘要:
The positive active material according to one embodiment of the present invention includes a composite metal oxide of the following Formula 1, and a compound being capable of intercalating and deintercalating lithium having the composite metal oxide coated on the surface thereof. M1-xAlO2 [Chemical Formula 1] Wherein, in the above Formula 1, M is selected from the group consisting of an alkali metal, an alkaline-earth metal, and combinations thereof, and 0.03≦x≦0.95. The composite metal oxide increases impregnation of an electrolyte, improves lithium mobility, and decreases internal resistance of a rechargeable lithium battery, and thereby improves discharge capacity and cycle-life characteristics.
摘要翻译:根据本发明的一个实施方案的正极活性物质包括下式1的复合金属氧化物和能够在其表面上涂覆复合金属氧化物的锂的嵌入和脱嵌化合物。 <?in-line-formula description =“In-line Formulas”end =“lead”?> M 1-x A 2 O 2化学式1 < -line-formula description =“In-line Formulas”end =“tail”?>其中,在上述式1中,M选自碱金属,碱土金属及其组合,以及 0.03 <= x <= 0.95。 复合金属氧化物增加电解质的浸渍,提高锂的迁移率,降低可再充电锂电池的内阻,从而提高放电容量和循环寿命特性。
摘要:
The present invention provides a method of preparing a negative active material for a rechargeable lithium battery, comprising the steps of: mixing a silicon precursor, a surfactant comprising an ammonium halide salt having a organic group, an initiator, and a solvent; heat-treating the mixture; cooling the heat-treated mixture to room temperature; washing the cooled, heat treated mixture; and calcining the washed product.
摘要:
The present invention relates to a method for preparing a silicon-based negative electrode active material, a negative electrode active material for a lithium secondary battery, and a lithium secondary battery comprising the same. More particularly, the method for preparing the silicon-based negative electrode active material comprises: preparing a porous silica (SiO2) and a thin metal film; coating the porous silica onto the thin metal film; reducing the porous silica to a porous silicon by performing heat-treatment of the thin metal film and the porous silica; and obtaining the porous silicon.
摘要:
Disclosed is a positive active material for a rechargeable lithium battery and a rechargeable lithium battery including the positive active material. The positive active material includes a lithiated intercalation compound capable of reversibly intercalating and deintercalating lithium and a metal oxide represented by the following Chemical Formula 1. LixMyM′1-yO4 [Chemical Formula 1] In the above Chemical Formula M, M′, x, and y are the same as defined in the detailed description. The positive active material easily provides lithium needed for the irreversible chemical/physical reaction at a negative electrode during the initial charge reaction, and thus increases charge capacity of a battery, decreases its irreversible capacity, and resultantly improves its cycle life.
摘要:
The present invention relates to negative-electrode active material for rechargeable lithium battery comprising: a core comprising material capable of doping and dedoping lithium; and, a carbon layer formed on the surface of the core, wherein the carbon layer has a three dimensional porous structure comprising nanopores regularly ordered on the carbon layer with a pore wall of specific thickness placed therebetween.