IMPROVED PROCESS FOR THE HYDROLYSIS OF DICARBOXYLIC ACID TRIGLYCERIDES

    公开(公告)号:US20200325094A1

    公开(公告)日:2020-10-15

    申请号:US16306154

    申请日:2017-06-05

    Abstract: This invention relates to an improved hydrolysis process for the preparation of dicarboxylic acids in which an organic phase comprising triglycerides of carboxylic acids having more than one acid functional group and a mixture comprising dicarboxylic acids, glycerine and partial esters of glycerine are mixed with water and hydrolysed at temperatures of between 50 and 350° C., and at pressures of or above the equilibrium vapor pressure. This process makes it possible to obtain high hydrolysis yields, even in short times.

    Process for the oxidative cleavage of vicinal diols

    公开(公告)号:US10421925B2

    公开(公告)日:2019-09-24

    申请号:US16306122

    申请日:2017-06-05

    Abstract: This invention relates to a process for obtaining monocarboxylic and dicarboxylic acids from unsaturated carboxylic acids and/or their derivatives. The said process comprises an oxidative cleavage reaction of vicinal diols into which are fed at least some of the aqueous phase separated out at the end of the reaction itself and at least one base so that the pH of the aqueous solution at the start of the oxidative cleavage reaction is between 4 and 7.

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