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    Preparation of amines from olefins over oxides of group IVB or VIB or mixtures thereof on carriers
    11.
    发明授权
    Preparation of amines from olefins over oxides of group IVB or VIB or mixtures thereof on carriers 失效
    IVB或VIB族氧化物或其混合物在载体上从烯烃制备胺

    公开(公告)号：US5780681A

    公开(公告)日：1998-07-14

    申请号：US869759

    申请日：1997-06-05

    Applicant: Karsten Eller ,  Rudolf Kummer ,  Michael Hesse

    Inventor： Karsten Eller ,  Rudolf Kummer ,  Michael Hesse

    IPC: B01J21/08 ,  B01J23/24 ,  B01J23/30 ,  B01J35/10 ,  C07B61/00 ,  C07C209/02 ,  C07C209/60 ,  C07C211/03 ,  C07C211/16 ,  C07C211/21 ,  C07C211/33 ,  C07C211/43

    CPC classification number: C07C209/60 ,  B01J23/24 ,  Y02P20/582

    Abstract: Amines of general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl, R.sup.1 and R.sup.2 together form a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene chain and R.sup.3 or R.sup.5 is C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl, or R.sup.3 and R.sup.5 together form a C.sub.2 -C.sub.12 -alkylene chain, are prepared by reacting an olefin of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the above-mentioned meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 have the abovementioned meanings, at from 200.degree. to 350.degree. C. and from 100 to 300 bar in the presence of a heterogeneous catalyst, by a process in which the heterogeneous catalyst used is an oxide of group IVB or VIB or a mixture thereof on a carrier.

    Abstract translation: 通式I（I）的胺其中R 1，R 2，R 3，R 4，R 5和R 6各自为氢，C 1 -C 20 - 烷基，C 2 -C 20 - 烯基，C 2 -C 20 - 炔基，C 3 -C 20 - 环烷基 C 4 -C 20烷基环烷基，C 4 -C 20环烷基烷基，芳基，C 7 -C 20烷基芳基或C 7 -C 20芳烷基，R 1和R 2一起形成饱和或不饱和的C 3 -C 9 - 亚烷基链，并且R 3或R 5是C 21 -C 200 - 烷基或C 21 -C 2-链烯基，或者R 3和R 5一起形成C 2 -C 12亚烷基链，通过使通式II的烯烃（II）反应，其中R3，R4，R5和R6具有 在具有上述含义的氨基或伯或仲胺中，其中R1和R2具有上述含义，在200-350℃和100-300巴的存在下， 的非均相催化剂，其中使用的非均相催化剂是IVB或VIB的氧化物或其载体上的混合物的方法。

    Preparation of amines
    12.
    发明授权
    Preparation of amines 失效
    胺的制备

    公开(公告)号：US5530127A

    公开(公告)日：1996-06-25

    申请号：US509997

    申请日：1995-08-01

    Applicant: Wolfgang Reif ,  Lothar Franz ,  Peter Stops ,  Volkmar Menger ,  Rainer Becker ,  Rudolf Kummer ,  Siegfried Winderl

    Inventor： Wolfgang Reif ,  Lothar Franz ,  Peter Stops ,  Volkmar Menger ,  Rainer Becker ,  Rudolf Kummer ,  Siegfried Winderl

    IPC: B01J23/88 ,  B01J21/06 ,  B01J23/885 ,  B01J37/03 ,  C07C209/08 ,  C07C209/16 ,  C07C209/18 ,  C07C211/03 ,  C07D295/023

    CPC classification number: C07C209/18 ,  C07C209/16 ,  B01J21/066 ,  B01J23/885 ,  B01J37/03 ,  Y02P20/582

    Abstract: A process for the preparatiion of an amine which comprises reacting a primary or secondary alcohol and a nitrogen compound selected from the group consisting of ammonia and primary and secondary amines, at temperatures of from 80.degree. to 250.degree. C. and pressures of from 1 to 400 bar using hydrogen in the presence of a zirconium/copper/nickel catalyst, wherein the catalytically active material contains from 20 to 85 wt % of oxygen-containing zirconium compounds, calculated as ZrO.sub.2, from 1 to 30 wt % of oxygen-containing compounds of copper, calculated as CuO, from 30 to 70 wt % of oxygen-containing compounds of nickel, calculated as NiO, from 0.1 to 5 wt % of oxygen-containing compounds of molybdenum, calculated as MoO.sub.3 and from 0 to 10 wt % of oxygen-containing compounds of aluminum and/or manganese, calculated as Al.sub.2 O.sub.3 or MnO.sub.2, respectively.

    Abstract translation: 一种制备胺的方法，其包括使伯醇或仲醇与选自氨和伯胺和仲胺的氮化合物在80-250℃的温度和1至 400巴，在锆/铜/镍催化剂存在下使用氢，其中催化活性材料含有20至85重量％的以ZrO 2计算的含氧锆化合物，1至30重量％的含氧化合物 以CuO计，以NiO计的含氧化合物的含量为30-70重量％的以氧化钼计的含氧​​化合物的重量百分比为0.1-70重量％，以氧化钼计为0.0-10重量％ 分别以Al2O3或MnO2计算的铝和/或锰的含氧化合物。

    Preparation of 5-methylbutyrolactone
    13.
    发明授权
    Preparation of 5-methylbutyrolactone 失效
    5-甲基丁酰胺的制备

    公开(公告)号：US5189182A

    公开(公告)日：1993-02-23

    申请号：US236199

    申请日：1988-08-25

    Applicant: Rudolf Kummer ,  Heinz-Walter Schneider ,  Werner Bertleff ,  Rolf Fischer ,  Uwe Vagt ,  Fritz Naeumann ,  Wolfgang Hoelderich ,  Matthias Schwarzmann

    Inventor： Rudolf Kummer ,  Heinz-Walter Schneider ,  Werner Bertleff ,  Rolf Fischer ,  Uwe Vagt ,  Fritz Naeumann ,  Wolfgang Hoelderich ,  Matthias Schwarzmann

    IPC: C07D315/00

    CPC classification number: C07D315/00

    Abstract: 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.

    Abstract translation: 通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐 催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％ 的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为 催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

    Process for the preparation of dialkyl carbonates
    14.
    发明授权
    Process for the preparation of dialkyl carbonates 失效
    制备碳酸二甲酯的方法

    公开(公告)号：US5151541A

    公开(公告)日：1992-09-29

    申请号：US562708

    申请日：1990-08-06

    Applicant: Klaus Joerg ,  Rudolf Kummer ,  Franz-Josef Mueller

    Inventor： Klaus Joerg ,  Rudolf Kummer ,  Franz-Josef Mueller

    IPC: B01J27/122 ,  B01J31/02 ,  C07B61/00 ,  C07C68/00 ,  C07C69/96

    CPC classification number: C07C68/005

    Abstract: A process for the preparation of dialkyl carbonates of the general formula I ##STR1## in which R.sup.1 denotes C.sub.1 -C.sub.10 -alkyl, by reaction of alcohols R.sup.1 OH with a gaseous carbon monoxide/oxygen mixture in the presence of a copper catalyst and a co-solvent at elevated temperature and pressure wherein the co-solvent used is a cyclic urea of the general formula II ##STR2## in which n is equal to 2, 3 or 4 and R.sup.2 denotes hydrogen or C.sub.1 -C.sub.4 -alkyl.

    Abstract translation: 在铜催化剂存在下，通过醇R 1 OH与气态一氧化碳/氧混合物的反应，制备通式I（II）的二烷基碳酸酯的方法，其中R1表示C1-C10-烷基;和 在升高的温度和压力下的共溶剂，其中所用的助溶剂是通式II的环脲（II），其中n等于2,3或4，并且R 2表示氢或C 1 -C 4 - 烷基。

    Preparation of 5-formylvaleric esters
    15.
    发明授权
    Preparation of 5-formylvaleric esters 失效
    5-甲酰戊酸酯的制备

    公开(公告)号：US5003102A

    公开(公告)日：1991-03-26

    申请号：US206751

    申请日：1988-06-15

    Applicant: Werner Bertleff ,  Rolf Fischer ,  Rudolf Kummer ,  Franz Merger ,  Heinz-Walter Schneider

    Inventor： Werner Bertleff ,  Rolf Fischer ,  Rudolf Kummer ,  Franz Merger ,  Heinz-Walter Schneider

    IPC: C07B61/00 ,  C07C67/313 ,  C07C69/66 ,  C07C69/67

    CPC classification number: C07C67/347

    Abstract: 5-Formylvaleric esters are prepared by a process which comprises the following steps:(a) Hydroformylation of a pentenoic ester by reaction with carbon monoxide and hydrogen at elevated temperatures and under superatmospheric pressure in the presence of a carbonyl complex of a metal of group 8 of the Periodic Table with formation of a mixture of 5-, 4- and 3-formylvaleric esters,(b) Isolation of the 5-formylvaleric ester from the resulting mixture of 5-, 4- and 3-formylvaleric esters, a mixture essentially consisting of 4- and 3-formylvaleric esters remaining,(c) Cleavage of the mixture essentially consisting of 4- and 3-formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of a catalyst to give pentenoic esters and(d) Recycling of the pentenoic esters to stage (a).

    Abstract translation: 5-甲酰戊酸酯通过包括以下步骤的方法制备：（a）在升高的温度和超大气压下，在第8组的金属的羰基络合物存在下，通过与一氧化碳和氢气反应来进行戊烯基酯的加氢甲酰化 的化合物，形成5-，4-和3-甲酰基戊酸酯的混合物，（b）从得到的5-，4-和3-甲酰基戊酸酯混合物中分离5-甲酰基戊酸酯，基本上 由4-和3-甲酰基戊酸酯组成，（c）在催化剂存在下，在50-400℃下将基本上由4-和3-甲酰基戊酸酯组成的混合物切割，得到戊烯酸酯和（d ）将戊烯酸酯循环回到（a）阶段。

    Working up of hydroformylation or carbonylation reaction mixtures
    19.
    发明授权
    Working up of hydroformylation or carbonylation reaction mixtures 失效
    加工甲酰化或羰基化反应混合物

    公开(公告)号：US4568653A

    公开(公告)日：1986-02-04

    申请号：US222893

    申请日：1981-01-06

    Applicant: Kurt Schwirten ,  Rudolf Kummer ,  Wolfgang Richter

    Inventor： Kurt Schwirten ,  Rudolf Kummer ,  Wolfgang Richter

    IPC: C07C45/49 ,  C07C29/16 ,  C07C29/76 ,  C07C29/86 ,  C07C45/00 ,  C07C45/50 ,  C07C45/78 ,  C07C67/00 ,  C07C67/38 ,  C07C67/58 ,  B01J31/40 ,  C07C51/14

    CPC classification number: C07C29/16 ,  C07C29/76 ,  C07C29/86 ,  C07C45/50 ,  C07C45/78

    Abstract: Reaction mixtures which are obtained on hydroformylation or carbonylation of olefinically unsaturated compounds and which contain dissolved non-volatile complex compounds of metals of group VIII of the periodic table are worked up by a method wherein the products, after distillative removal of low-boiling constituents alone, or of these constituents plus a part of the high-boiling residue, or a part of the high-boiling residue after distillative removal of the desired products, are or is extracted with carbon dioxide, a C.sub.2 -C.sub.4 -paraffin, a C.sub.2 -C.sub.4 -olefin or a normally gaseous halohydrocarbon at above the critical temperature and above the critical pressure of these (extractant) compounds.

    Abstract translation: 在烯属不饱和化合物的加氢甲酰化或羰基化获得并且含有周期表第VIII族金属的溶解的非挥发性络合物的反应混合物通过一种方法来处理，其中产物在蒸馏除去低沸点组分之后 ，或这些成分加上一部分高沸点残余物，或蒸馏除去所需产物后的一部分高沸点残余物，用二氧化碳，C2-C4-链烷烃，C2- 在高于临界温度并高于这些（萃取剂）化合物的临界压力的C4-烯烃或正常气态的卤代烃。

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