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11.发明授权Thermoplastic elastomer composition, process for producing the same, and pneumatic tire and hose made with the same 有权热塑性弹性体组合物及其制造方法，以及由其制成的充气轮胎和软管公开(公告)号：US06359071B1
公开(公告)日：2002-03-19
申请号：US09380588
申请日：1999-12-07
Applicant: Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
Inventor： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
IPC: C08L7700
CPC classification number: C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (&phgr;A/&phgr;B)×(&eegr;B/&eegr;A)
Abstract translation: 一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透 预防层。 特别地，通过混合在橡胶组合物（A）/（A）的熔体粘度的比例的条件下混合的组合物（C），通过使用具有高橡胶比的材料来制造具有减小的领域橡胶粒径的热塑性弹性体组合物， 在橡胶组合物（D）/组合物（C）的熔融粘度比为0.8〜1.2的条件下，树脂（B）为0.8〜1.2，式（phiA / phiB）x（etaB / etaA） 公式（phiD / phiC）x（etaC / etaD）<1.0，其中phiA：橡胶组合物（A）的体积分数，phiB：树脂（B）的体积分数，etaA：橡胶组合物（A）的熔融粘度，etaB： 树脂（B）的熔融粘度，phiC：组合物（C）的体积分数，phiD：橡胶组合物的体积分数（D），etaC：组合物（C）的熔融粘度，etaD：橡胶组合物（D）的熔融粘度。
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12.发明授权公开(公告)号：US06179008B2
公开(公告)日：2001-01-30
申请号：US08930205
申请日：1997-10-09
Applicant: Tetsuji Kawazura , Osamu Ozawa , Yoshihiro Soeda , Katuhiro Tanaka , Takashi Satoh , Shigeru Yamauchi , Noriaki Kuroda , Shuji Takahashi , Daisuke Irii , Kazunori Ishikawa , Susumu Hatanaka
Inventor： Tetsuji Kawazura , Osamu Ozawa , Yoshihiro Soeda , Katuhiro Tanaka , Takashi Satoh , Shigeru Yamauchi , Noriaki Kuroda , Shuji Takahashi , Daisuke Irii , Kazunori Ishikawa , Susumu Hatanaka
IPC: F19L1108
CPC classification number: B32B25/10 , B29C47/0023 , B29C47/0064 , B29C47/021 , B29C47/023 , B29C47/061 , B29C47/065 , B29C53/58 , B29C70/086 , B29C70/088 , B29C70/222 , B29K2021/00 , B29K2101/12 , B29K2105/0827 , B29K2995/0072 , B29L2009/00 , B29L2023/005 , B32B1/08 , B32B7/12 , B32B2262/0276 , B32B2305/72 , B32B2597/00 , C08L13/00 , C08L23/02 , C08L23/08 , C08L33/06 , C08L33/08 , C08L67/00 , C08L67/02 , C08L67/025 , C08L67/04 , C08L83/00 , C08L83/04 , F16L11/085 , F16L11/086 , Y10T428/31913 , C08L33/00 , C08L2666/02 , C08L2666/08
Abstract: A thermoplastic elastomer composition which, when used for the inner tube and/or outer cover of a hose, can improve the hose flexibility at an ordinary temperature and low temperature, oil resistance, and cold resistance and can reduce the production costs since it does not require a vulcanization step and a hose having said properties using this elastomer composition for its inner tube and/or outer cover and a process and apparatus for the production thereof.
Abstract translation: 一种热塑性弹性体组合物，当用于软管的内管和/或外盖时，可以在常温和低温，耐油性和耐寒性方面提高软管柔性，并且可以降低生产成本，因为它不 需要硫化步骤和具有使用该弹性体组合物的所述性质的软管作为其内管和/或外盖，以及用于生产它的方法和装置。
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13.发明授权Thermoplastic elastomer composition, hose comprising thermoplastic elastomer composition and process of production thereof 失效热塑性弹性体组合物，软管包含热塑性弹性体组合物及其生产方法
公开(公告)号：US6166143A
公开(公告)日：2000-12-26
申请号：US101204
申请日：1998-07-02
Applicant: Jiro Watanabe , Yuichi Hara , Daisuke Irii , Takashi Satoh , Gou Kawaguchi , Shigeru Yamauchi , Susumu Hatanaka , Noriaki Kuroda
Inventor： Jiro Watanabe , Yuichi Hara , Daisuke Irii , Takashi Satoh , Gou Kawaguchi , Shigeru Yamauchi , Susumu Hatanaka , Noriaki Kuroda
CPC classification number: F16L11/08 , C08L23/02 , Y10T428/1386 , Y10T428/1393 , Y10T428/31855 , C08L2666/04 , C08L2666/24
Abstract: A thermoplastic elastomer composition containing a component (A) (thermoplastic polyolefin resin), component (B) (epoxy-group-containing ethylene acrylic ester copolymer rubber), and component (C) (acid-modified polyolefin resin) comprising a continuous phase of the component (A) in which the component (B) is dispersed as a dispersed phase and is cross-linked by a peroxide; a thermoplastic elastomer composition comprising a continuous phase of a thermoplastic polyolefin resin (A) and a dispersed phase of an epoxy-group-containing ethylene-acrylic ester copolymer rubber component (B) and acrylonitrile butadiene rubber component (C), which is dynamically cross-linked; and a hose having an inner tube, at least one reinforcing layer, and an outer cover, wherein the inner tube and the outer cover contain a thermoplastic elastomer composition comprised of a thermoplastic resin in which is blended an at least partially cross-linked elastomer component, the reinforcing layer is a brass-plated wire, and the reinforcing layer and inner tube and the reinforcing layer and outer cover have between them a maleic-acid-modified polyolefin thermoplastic resin.
Abstract translation: PCT No.PCT / JP97 / 03987第 371日期：1998年7月2日 102（e）日期1998年7月2日PCT 1997年10月31日PCT公布。 WO98 / 20068 PCT出版物 日期1998年5月14日一种含有组分（A）（热塑性聚烯烃树脂），组分（B）（含环氧基的乙烯丙烯酸酯共聚物橡胶）和组分（C）（酸改性聚烯烃树脂）的热塑性弹性体组合物， 组分（A）的连续相，其中组分（B）作为分散相分散并通过过氧化物交联; 包含热塑性聚烯烃树脂（A）的连续相和含环氧基的乙烯 - 丙烯酸酯共聚物橡胶组分（B）和丙烯腈丁二烯橡胶组分（C）的分散相的热塑性弹性体组合物，其动态交联 链接 以及具有内管，至少一个加强层和外盖的软管，其中内管和外盖包含由热塑性树脂组成的热塑性弹性体组合物，其中将至少部分交联的弹性体组分 加强层是镀黄铜丝，并且增强层和内管以及增强层和外盖之间具有马来酸改性的聚烯烃热塑性树脂。
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14.发明授权Method of immobilizing biofunctional material, and element prepared thereby, and measurement by using the same element 失效固定生物功能材料的方法及其制备的元件，并使用相同的元件进行测量
公开(公告)号：US5256271A
公开(公告)日：1993-10-26
申请号：US714901
申请日：1992-06-17
Applicant: Yoshihito Ikariyama , Shigeru Yamauchi , Tomoaki Yukiashi
Inventor： Yoshihito Ikariyama , Shigeru Yamauchi , Tomoaki Yukiashi
CPC classification number: C12N11/14 , C12Q1/003 , Y10S435/817
Abstract: A microbioelectrode having high performance produced by immobilization by incorporating a biologically active substance in the interior or on the surface of a porous conductive material layer or fine particle layer which has been deposited on the surface of a transducing material. The inventive microbioelectrode demonstrates sufficient output even if the sensor using the electrode is very small in size.
Abstract translation: 通过将生物活性物质并入已经沉积在换能材料的表面上的多孔导电材料层或细颗粒层的内部或表面上，通过固定产生的具有高性能的微电极。 即使使用电极的传感器的尺寸非常小，本发明的微电极也显示出足够的输出。
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Patent Agency Ranking
公开(公告)号：US4654314A
公开(公告)日：1987-03-31
申请号：US628600
申请日：1984-07-06
Applicant: Shigehide Takagi , Shigeru Yamauchi
Inventor： Shigehide Takagi , Shigeru Yamauchi
CPC classification number: A61L27/12 , A61L27/56 , C04B38/065 , C04B38/106 , A61F2310/00293 , A61L2400/18 , C04B2111/00836 , C04B2111/00844
Abstract: A porous ceramic material composed of a sintered porous body of a calcium phosphate compound is described. A multiplicity of capillary void paths having a diameter of 1 to 30 .mu.m and a multiplicity of pores having a diameter of 1 to 600 .mu.m are formed in the sintered porous body. At least part of the pores are connected to the exterior space of the sintered porous body through at least a part of the capillary voids. The porous ceramic material is valuable as a medical material, e.g., a substitute or prosthesis for bone or dental root, and also an electronic material and a genetic engineering material.When the porous ceramic material is embedded in a bone defect of human or animals, osteolytic cells, osteoblasts, erythrocytes and body fluid are selectively allowed to intrude through the porous ceramic material while almost no intrusion of osteoclasts and collagen fibers is allowed. Accordingly, the porous ceramic material can be utilized for inducing new-born bone, controlling resorption of bone with age, remedying bone defects.
Abstract translation: 描述了由磷酸钙化合物的烧结多孔体组成的多孔陶瓷材料。 在烧结多孔体中形成直径为1〜30μm的多个毛细管空隙路径和多个直径为1〜600μm的孔。 孔的至少一部分通过毛细孔隙的至少一部分连接到烧结多孔体的外部空间。 多孔陶瓷材料作为医疗材料是有价值的，例如用于骨或牙根的替代物或假体，以及电子材料和遗传工程材料。 当多孔陶瓷材料嵌入人或动物的骨缺损中时，选择性地允许溶骨细胞，成骨细胞，红细胞和体液侵入多孔陶瓷材料，同时几乎不允许破骨细胞和胶原纤维的侵入。 因此，多孔陶瓷材料可用于诱导新生骨，控制骨龄随着年龄的吸收，修复骨缺损。
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公开(公告)号：US20090023841A1
公开(公告)日：2009-01-22
申请号：US11744333
申请日：2007-05-04
Applicant: Shigeru Yamauchi
Inventor： Shigeru Yamauchi
CPC classification number: C08L67/02 , C08K5/053 , C08L23/0846 , C08L67/00 , C08L93/04 , C08L2666/02 , C08L2666/06
Abstract: A molding resin composition which includes (a) an aromatic polyester, (b) a tackifier, (c) a polyol compound having two or more hydroxy groups per molecule and (d) a polyolefin, wherein the polyolefin (d) is present in an amount of 5 to 40 parts by weight per 100 parts by weight of the aromatic polyester (a) and the polyolefin (d) combined, has an excellent adhesion to polyolefins, metals and PVC, and also has an excellent gasoline resistance.
Abstract translation: 一种成型树脂组合物，其包含（a）芳族聚酯，（b）增粘剂，（c）每分子具有两个或多个羟基的多元醇化合物和（d）聚烯烃，其中所述聚烯烃（d）存在于 相对于100重量份芳族聚酯（a）和聚烯烃（d）组合的量为5〜40重量份，对聚烯烃，金属和PVC具有优异的粘合性，并且还具有优异的耐汽油性。
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17.发明申请Thermoplastic elastomer composition and process for producing the same and pneumatic tire and hose using the same 有权热塑性弹性体组合物及其制造方法及使用其的充气轮胎和软管公开(公告)号：US20050103417A1
公开(公告)日：2005-05-19
申请号：US11008962
申请日：2004-12-13
Applicant: Jiro Watanabe , Yuichi Hara , Shigeru Yamauchi , Hideo Nemoto
Inventor： Jiro Watanabe , Yuichi Hara , Shigeru Yamauchi , Hideo Nemoto
CPC classification number: C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. In particular, a thermoplastic elastomer composition having a reduced particle size of the domain rubber is produced by a material having a high rubber ratio by mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (φA/φB)×(ηB/ηA)
Abstract translation: 一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透 预防层。 特别地，通过混合在橡胶组合物（A）/（A）的熔体粘度的比例的条件下混合的组合物（C），通过使用具有高橡胶比的材料来制造具有减小的领域橡胶粒径的热塑性弹性体组合物， 树脂（B）为0.8〜1.2，通式（i> i i i i i <<<<<<<<<<<<<<<<<<<<<<<<<<< 橡胶组合物（D）/组合物（C）的熔体粘度比为0.8〜1.2和式（phi / D / C / C）的条件下， /SUB>）x(etaC/etaD)1.0，其中橡胶组合物（A）的体积分数，phi B：树脂（B）的体积分数，ηA：橡胶组合物（A）的熔融粘度，乙烯B：树脂的熔融粘度 （B），化合物（C）的体积分数，橡胶组合物（D）的体积分数，ηC ：组合物（C）的熔融粘度，η的熔体粘度：r的熔体粘度 ubber组成（D）。 另外，具有作为分散相的弹性体组合物（A）和热塑性树脂组合物（B）作为基质并具有由至少两种热塑性树脂的共混物组成的热塑性树脂组合物的热塑性弹性体组合物。
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18.发明授权Thermoplastic elastomer composition and process for producing the same and pneumatic tire and hose using the same 有权热塑性弹性体组合物及其制造方法及使用其的充气轮胎和软管公开(公告)号：US06861470B2
公开(公告)日：2005-03-01
申请号：US10347283
申请日：2003-01-21
Applicant: Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
Inventor： Jiro Watanabe , Kazuto Yamakawa , Daisuke Kanenari , Noriaki Kuroda , Gou Kawaguchi , Yuichi Hara , Tetsuji Kawazura , Shigeru Yamauchi , Hideo Nemoto
CPC classification number: C08L23/02 , B60C1/00 , B60C1/0008 , C08L23/283 , C08L77/00 , C08L2312/00 , Y10T152/10495 , C08L2666/04 , C08L2666/20
Abstract: A thermoplastic elastomer composition dynamically vulcanized to a gelation rate of 50 to 95% which is superior in heat resistance and durability while maintaining flexibility and superior in air permeation preventive property which can be efficiently used as, for example, a pneumatic tire as an air permeation preventive layer. The method includes mixing a composition (C) mixed under conditions of a ratio of melt viscosities of the rubber composition (A)/resin (B) of 0.8 to 1.2 and the formula (φA/φB)×(ηB/ηA)
Abstract translation: 一种热塑性弹性体组合物，其动态硫化至50至95％的凝胶化速率，其耐热性和耐久性优异，同时保持柔软性和优异的防透气性，可有效地用作例如充气轮胎作为空气渗透 预防层。 该方法包括将橡胶组合物（A）/树脂（B）的熔融粘度比为0.8〜1.2，式（phiA / phiB）×（etaB / etaA））1.0的混合条件下混合的组合物（C） 在橡胶组合物（D）/组合物（C）的熔体粘度比为0.8至1.2和式（phiD / phiC）x（etaC / etaD）<1.0的条件下，其中phiA：橡胶组合物的体积分数 A），phiB：树脂（B）的体积分数，etaA：橡胶组合物（A）的熔融粘度，etaB：树脂（B）的熔融粘度，phiC：组合物的体积分数（C），phiD：橡胶体积分数 组成（D），etaC：组合物（C）的熔融粘度，etaD：橡胶组合物（D）的熔融粘度。
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公开(公告)号：US4963145A
公开(公告)日：1990-10-16
申请号：US325098
申请日：1989-03-20
Applicant: Shigehide Takagi , Shigeru Yamauchi
Inventor： Shigehide Takagi , Shigeru Yamauchi
CPC classification number: A61L27/12 , A61L27/56 , C04B38/065 , C04B38/106 , A61F2310/00293 , A61L2400/18 , C04B2111/00836 , C04B2111/00844
Abstract: A porous ceramic material composed of a sintered porous body of a calcium phosphate compound is described. A multiplicity of capillary void paths having a diameter of 1 to 30 .mu.m and a multiplicity of pores having a diameter of 1 to 600 .mu.m are formed in the sintered porous body. At least part of the pores are connected to the exterior space of the sintered porous body through at least a part of the capillary voids. The porous ceramic material is valuable as a medical material, e.g., a substitute or prosthesis for bone or dental root, and also an electronic material and a genetic engineering material.When the porous ceramic material is embedded in a bone defect of human or animals, osteolytic cells, osteoblasts, erythrocytes and body fluid are selectively allowed to intrude through the porous ceramic material while almost no intrusion of osteoclasts and collagen fibers is allowed. Accordingly, the porous ceramic material can be utilized for inducing new-born bone, controlling resorption of bone with age, remedying bone defects.
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