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11.
公开(公告)号:US5147947A
公开(公告)日:1992-09-15
申请号:US429551
申请日:1989-10-31
申请人: Yuji Yamamoto , Takashi Kurata , Kazuyoshi Nakazawa , Yusuke Tsuda , Junichiro Watanabe , Makoto Matsumoto , Akitsugu Kurita , Yuichi Funahashi
发明人: Yuji Yamamoto , Takashi Kurata , Kazuyoshi Nakazawa , Yusuke Tsuda , Junichiro Watanabe , Makoto Matsumoto , Akitsugu Kurita , Yuichi Funahashi
IPC分类号: C08F283/12 , C08L51/08
CPC分类号: C08F283/124 , C08L51/085
摘要: A polyorganosiloxane series thermoplastic resin comprising a graft copolymer obtained from a vinyl monomer and a modified polyorganosiloxane, and a thermoplastic resin composition containing the same. The resin and the composition thereof have excellent slidability, abrasion resistance, weather resistance, cold resistance and impact resistance, and can be applied to new fields such as sliding parts, parts for cold district, outdoor parts, etc.
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公开(公告)号:US4467068A
公开(公告)日:1984-08-21
申请号:US495860
申请日:1983-05-18
申请人: Kazo Maruyama , Akitsugu Kurita
发明人: Kazo Maruyama , Akitsugu Kurita
IPC分类号: C03C17/30 , C09D183/04 , C08G77/42 , B32B17/10 , C08L83/10
CPC分类号: C03C17/30 , C09D183/04 , Y10T428/31612
摘要: A composition for concealing grazes or scratches on glass surfaces comprising an emulsion of composition (A) and composition (B), said composition (A) comprising the emulsion-polymerization product of:(1) 0.1-60 weight percent of (A) of the reaction product of:(a) 0.1-50 weight percent of (a) and (b) of the product obtained by reacting:(i) 1 mole of a compound of the formula Q.sup.1 NHR.sup.1 SiR.sub.a.sup.2 (OR).sub.3-a with(ii) 0.5-3.0 moles of a compound of the formula Q.sup.2 R.sup.4 SiR.sub.a.sup.2 (OR).sup.6).sub.3-b ;(b) 50-99.9 weight percent of (a) and (b) of a polydiorganosiloxane having at least one silanol group and a viscosity at 25.degree. C. of 5-10,000 cSt;(2) 1-50 weight percent of (A) of a compound of the formula (R.sup.7 R.sup.8 SiO).sub.n ;(3) 0.1-20 weight percent of (A) of a cationic surfactant or mixture of cationic and nonionic surfactants;(4) 20-90 weight percent of (A) of water; and(5) an effective amount of alkali metal hydroxide having catalytic ability; andsaid composition (B) being obtained by emulsifying in water a polydiorganosiloxane having a viscosity at 25.degree. C. of 10-100,000 cSt in the presence of a cationic or nonionic surfactant or mixture thereof.
摘要翻译: 一种用于在包含组合物(A)和组合物(B)的乳液的玻璃表面上隐藏玻璃或划痕的组合物,所述组合物(A)包含乳液聚合产物:(1)0.1-60重量%的(A) 反应产物:(a)通过以下反应获得的(a)和(b)的0.1-50重量%:(i)1摩尔式Q1NHR1SiRa2(OR)3-a的化合物与(ii) 0.5-3.0摩尔式Q2R4SiRa2(OR)6)3-b的化合物; (b)50-99.9重量%的(a)和(b)具有至少一个硅烷醇基团的聚二有机硅氧烷和25℃下的粘度为5-10,000cSt; (2)1-50重量%的(A)式(R7R8SiO)n的化合物; (3)0.1-20重量%的(A)阳离子表面活性剂或阳离子和非离子表面活性剂的混合物; (4)20-90重量%的(A)水; 和(5)有效量的具有催化能力的碱金属氢氧化物; 并且所述组合物(B)通过在阳离子或非离子表面活性剂或其混合物的存在下在水中乳化在25℃下具有10-100,000cSt的粘度的聚二有机硅氧烷获得。
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公开(公告)号:US4412035A
公开(公告)日:1983-10-25
申请号:US381488
申请日:1982-05-24
申请人: Akitsugu Kurita
发明人: Akitsugu Kurita
摘要: The present invention relates to a silicone cationic emulsion composition of a polydioganosiloxane containing amino, epoxy, and hydroxyl groups as functional groups, and which may be used as a releasing agent, stripping agent, paint component, and anti-foaming agent.
摘要翻译: 本发明涉及含有氨基,环氧基和羟基作为官能团的聚二有机硅氧烷的有机阳离子乳液组合物,可用作脱模剂,汽提剂,涂料组分和消泡剂。
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公开(公告)号:US4602959A
公开(公告)日:1986-07-29
申请号:US724131
申请日:1985-04-17
申请人: Akitsugu Kurita , Shinji Kida , Masaaki Otsuki
发明人: Akitsugu Kurita , Shinji Kida , Masaaki Otsuki
CPC分类号: C08G77/26 , C09D5/1675 , Y10T428/31663
摘要: Disclosed is a method for preventing multiplication of algae which is characterized by coating the surfaces of solid materials with a silicone emulsion composition prepared by emulsion polymerization of:(1) 0.1 to 60% by weight of a reaction product prepared by reacting(A) 50 to 99.9% by weight of a polydiorganosilozane having more than one silanol group on the average in each molecule and having a viscosity of 5 to 10,000 cSt at 25.degree. C. with(B) 0.1 to 50% by weight of a product prepared by reacting (a) 1 mol of a compound represented by the formula: ##STR1## wherein Q.sup.1 is a monovalent group selected from the group consisting of a hydrogen atom, --CH.sub.3, --CH.sub.2 CH.sub.2 NH.sub.2 and --CH.sub.2 CH.sub.2 NHCH.sub.2 CH.sub.2 NH.sub.2, R.sup.1 is a divalent hydrocarbon group having 1 to 4 carbon atoms, R.sup.2 and R.sup.3 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and a is an integer of 0 or 1,with (b) 0.5 to 3.0 mol of a compound represented by the formula: ##STR2## wherein Q.sup.2 is an epoxy group-containing group selected from a glycidoxy group and an epoxycyclohexyl group, R.sup.4 is a divalent hydrocarbon group having 2 to 4 carbon atoms, R.sup.5 and R.sup.6 are monovalent hydrocarbon groups each having 1 to 4 carbon atoms, and b is an integer of 0 or 1, and (2) 1 to 50% by weight of a compound represented by the formula: ##STR3## wherein R.sup.7 and R.sup.8 are same or different substituted or unsubstituted hydrocarbon groups each having 1 to 50 carbon atoms, and n is an integer of 3 or more, in the presence of(3) 0.1 to 20% by weight of a quaternary ammonium salt surface active agent and(4) 20 to 90% by weight of water.
摘要翻译: 公开了一种防止藻类繁殖的方法,其特征在于用通过乳液聚合制备的硅氧烷乳液组合物涂覆固体材料的表面:(1)0.1至60重量%的反应产物,其通过使(A)50 至99.9重量%的在每个分子中平均具有多于一个硅烷醇基团的聚二有机基硅烷,并且在25℃下的粘度为5至10,000cSt。(B)0.1至50重量%的通过使 (a)1摩尔由下式表示的化合物:其中Q1是选自氢原子,-CH 3,-CH 2 CH 2 NH 2和-CH 2 CH 2 NHCH 2 CH 2 NH 2的一价基团,R 1是具有1至 4个碳原子,R 2和R 3是各自具有1至4个碳原子的一价烃基,a是0或1的整数,(b)0.5-3.0mol由下式表示的化合物:其中Q2 是选自f的环氧基团 缩水甘油氧基和环氧基环己基,R4是具有2至4个碳原子的二价烃基,R5和R6是各自具有1至4个碳原子的一价烃基,b是0或1的整数,和(2 )1〜50重量%的由下式表示的化合物:其中R 7和R 8是相同或不同的取代或未取代的碳原子数1〜50的烃基,n为3以上的整数, 存在(3)0.1〜20重量%的季铵盐表面活性剂和(4)20〜90重量%的水。
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公开(公告)号:US4559319A
公开(公告)日:1985-12-17
申请号:US711863
申请日:1985-03-14
申请人: Akitsugu Kurita , Tetsuo Fujimoto
发明人: Akitsugu Kurita , Tetsuo Fujimoto
CPC分类号: C08J3/24 , C08K5/57 , C08J2383/04 , Y10S528/901
摘要: A curing agent composition for silicone elastomers, comprising an organic tin compound which is solubilized in water with the use of a nonionic surfactant selected from the group consisting of polyoxyethylene sorbitol fatty acid esters and polyoxyethylene sorbitan fatty acid esters and a polyvalent alcohol.
摘要翻译: 一种硅氧烷弹性体的固化剂组合物,其包含使用选自聚氧乙烯山梨糖醇脂肪酸酯和聚氧乙烯脱水山梨糖醇脂肪酸酯的非离子表面活性剂和多元醇溶解在水中的有机锡化合物。
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公开(公告)号:US4502889A
公开(公告)日:1985-03-05
申请号:US562801
申请日:1983-12-19
申请人: Akitsugu Kurita
发明人: Akitsugu Kurita
IPC分类号: C08K3/22 , C08L83/00 , C08L83/04 , C08L83/06 , C09J7/02 , C10M173/02 , C10N10/06 , C10N20/02 , C10N30/06 , C10N40/36 , C10N50/02 , C10N50/08 , D06M11/00 , D06M11/45 , D06M13/02 , D06M13/224 , D06M13/322 , D06M13/463 , D06M13/51 , D06M13/513 , D06M15/643 , D06M15/647 , D06M15/65 , D21H19/32 , C09K3/00
摘要: A silicone emulsion composition containing a reinforcing amount of alumina sol blended in an emulsion precursor obtained by emulsifying a polydiorganosiloxane having at least one silanol group per molecule, one nonionic surfactant and the remainder water.
摘要翻译: 一种含有增溶量的氧化铝溶胶的硅氧烷乳液组合物,其通过乳化每分子具有至少一个硅烷醇基的聚二有机硅氧烷得到的乳化前体,一种非离子表面活性剂和剩余的水。
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公开(公告)号:US5032643A
公开(公告)日:1991-07-16
申请号:US434143
申请日:1989-11-08
摘要: There is disclosed a process for producing polyorganosiloxanes, comprising that an organosiloxane having a structural unit represented by the following general formula: ##STR1## (in which R.sup.1 represents a substituted or unsubstituted monovalent organic group; and n represents an integer of 0 tp 3) is subjected to emulsion polymerization in an aqueous medium in the presence of an organic sulfonic acid and a trihalogenated acetic acid.
摘要翻译: 公开了一种制备聚有机硅氧烷的方法,其包括具有下列通式表示的结构单元的有机硅氧烷:其中R1表示取代或未取代的一价有机基团,n表示0tp 3的整数) 在水性介质中在有机磺酸和三卤代乙酸的存在下进行乳液聚合。
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18.
公开(公告)号:US4656221A
公开(公告)日:1987-04-07
申请号:US745345
申请日:1985-06-14
申请人: Akitsugu Kurita , Kazou Maruyama , Akira Okusa , Haruo Hayashi
发明人: Akitsugu Kurita , Kazou Maruyama , Akira Okusa , Haruo Hayashi
IPC分类号: C08L83/00 , C03C17/30 , C08L83/04 , C08L83/06 , C08L83/08 , C09D183/04 , C09D183/06 , C09D183/08 , C08L83/10 , C08K5/24
CPC分类号: C03C17/30 , C08L83/04 , C08G77/70 , Y10T428/31612
摘要: Disclosed is a composition for concealing graze marks on a transparent glass bottle which comprises:(A) 100 parts by weight of polydiorganosiloxane having a viscosity of 10 to 100,000 cSt at 25.degree. C. in which 15 to 60 mole percent of an organic group bonded to a silicon atom is an organic group selected from the group consisting of a phenyl group, an aralkyl group and an alkyl group having carbon atoms of 6 or more,(B) 1 to 100 parts by weight of film-forming polyorganosiloxane comprising:(1) two or more straight-chain diorganosiloxane portion constituted by 10 or more diorganosiloxane units, and(2) one or two or more cross-linking portion or portions formed by a reaction of an amino group bonded to a silicon atom through at least one carbon atom and zero or at least one nitrogen atom bonded indirectly to a silicon atom, with an epoxy group bonded to an other silicon atom through at least one carbon atom and zero or at least one oxygen atom bonded indirectly to a silicon atom, wherein the proportional ratio of Part (2) in Component (B) is 0.1 to 30 % by weight,(C) 1 to 30 % by weight of a cationic surfactant or a surfactant mixture in which a part of the cationic surfactant is replaced with a nonionic surfactant based on the total amount of Components (A) and (B),(D) 60-1,000 % by weight of water based on the total amount of Components (A) and (B), whereby forming a film having refractive index of 1.42 to 1.55 on the surfaces of glass bottles.
摘要翻译: 公开了一种用于在透明玻璃瓶上隐藏放牧痕迹的组合物,其包括:(A)在25℃下粘度为10至100,000cSt的聚二有机硅氧烷100重量份,其中15至60摩尔%的有机基团键合 硅原子是选自苯基,芳烷基和碳原子数为6以上的烷基的有机基团,(B)1〜100重量份成膜聚有机硅氧烷,其包含:( 1)由10个以上的二有机硅氧烷单元构成的2个以上的直链二有机硅氧烷部分,和(2)通过与硅原子键合的氨基的反应而形成的1个或2个以上的交联部分, 碳原子和与氮原子间接连接的零个或至少一个氮原子,其中环氧基通过至少一个碳原子键合到另一个硅原子上,零个或至少一个氧原子与硅原子间接键合, 组分(B)中部分(2)的比例比例为0.1至30重量%,(C)1至30重量%的阳离子表面活性剂或表面活性剂混合物,其中阳离子表面活性剂的一部分被 基于组分(A)和(B)的总量的非离子表面活性剂,(D)基于组分(A)和(B)的总量的60-1,000重量%的水,由此形成具有折射 玻璃瓶表面的指数为1.42〜1.55。
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公开(公告)号:US4378389A
公开(公告)日:1983-03-29
申请号:US238237
申请日:1981-02-25
申请人: Kazo Maruyama , Shuhei Kosaka , Akitsugu Kurita
发明人: Kazo Maruyama , Shuhei Kosaka , Akitsugu Kurita
IPC分类号: C08G77/26 , C09D183/08 , C09D183/10 , B05D3/02
CPC分类号: C09D183/10 , C08G77/26 , C09D183/08 , Y10T428/31663
摘要: A silicone base release or lubricating agent is disclosed which is comprised of the reaction product of a silanol-containing polydiorganosiloxane fluid with a first reaction product of epoxy or glycidoxy functional silanes and aminofunctional silanes.
摘要翻译: 公开了一种硅氧烷基脱模剂或润滑剂,其由含硅烷醇的聚二有机硅氧烷流体与环氧或缩水甘油氧基官能硅烷和氨基官能硅烷的第一反应产物的反应产物组成。
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