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11.发明授权公开(公告)号：US08726443B2
公开(公告)日：2014-05-20
申请号：US12791145
申请日：2010-06-01
Applicant: Barry Freel , Geoffrey Hopkins
Inventor： Barry Freel , Geoffrey Hopkins
CPC classification number: B08B9/0436 , B08B9/00 , B08B9/045 , F23J3/02
Abstract: Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.
Abstract translation: 本文描述了用于减少热解和其它热转化过程中的累积沉积和不期望的二次热反应的系统和方法。 在一个实施例中，系统包括称为扩孔器的装置，用于去除热解过程的热转化和冷凝操作之间的产物沉积物。 铰刀可以包括但不限于机械往复杆或冲头，机械螺旋钻，钻头，高温刮水器，刷子或冲头以去除沉积物并防止二次反应。 或者或另外，铰刀可以使用蒸气，产物气体，再循环气体，其它气体射流或非冷凝液体的高速幕或射流（即液压或气动流）以去除沉积物。 优选地，铰刀在热解过程中除去沉积物，允许热解过程的连续操作。
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公开(公告)号：US20120125815A1
公开(公告)日：2012-05-24
申请号：US13338144
申请日：2011-12-27
Applicant: Barry Freel , Robert G. Graham
Inventor： Barry Freel , Robert G. Graham
CPC classification number: C10B55/04 , C10G9/32 , C10G31/06 , C10G2300/302 , C10G2300/4006 , C10G2300/4025 , C10G2300/4081
Abstract: The present invention is directed to the upgrading of heavy hydrocarbon feedstock that utilizes a short residence pyrolytic reactor operating under conditions that cracks and chemically upgrades the feedstock. The method for upgrading a heavy hydrocarbon feedstock comprises introducing a particulate heat carrier into an upflow reactor, introducing the heavy hydrocarbon feedstock into the upflow reactor at a location above that of the particulate heat carrier so that a loading ratio of the particulate heat carrier to feedstock is from about 15:1 to about 200:1, allowing the heavy hydrocarbon feedstock to interact with the heat carrier with a residence time of less than about 1 second, to produce a product stream, separating the product stream from the particulate heat carrier, regenerating the particulate heat carrier, and collecting a gaseous and liquid product from the product stream.
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公开(公告)号：US07905990B2
公开(公告)日：2011-03-15
申请号：US11943329
申请日：2007-11-20
Applicant: Barry Freel
Inventor： Barry Freel
CPC classification number: C10B57/00 , C10B27/00 , C10B49/22 , C10B53/02 , C10G1/02 , C10G9/28 , C10K1/04 , F28C3/08 , Y02E50/14 , Y02P20/145
Abstract: A rapid thermal conversion process for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. Biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. The liquid product may itself be used as the quench media.
Abstract translation: 用于在大规模生产中有效地将木材，其他生物质材料和其它碳质原料（包括碳氢化合物）有效转化成高产量的有价值的液体产品（例如生物油）的快速热转化方法。 将生物质材料，例如木材进料到转化系统，其中生物质材料与向上的热热载体（例如沙）流混合，其将生物质热转化成热蒸气流。 热蒸汽流在位于转化系统下游的一个或多个冷凝室中用骤冷介质快速淬火。 快速淬火将蒸气流冷凝成液体产物，其作为有价值的液体产物从冷凝室收集。 液体产品本身可以用作淬火介质。
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14.发明申请MITIGATION OF DEPOSITS AND SECONDARY REACTIONS IN THERMAL CONVERSION PROCESSES 有权沉淀过程中的沉降和二次反应在热转化过程中公开(公告)号：US20100236915A1
公开(公告)日：2010-09-23
申请号：US12791145
申请日：2010-06-01
Applicant: Barry Freel , Geoffrey Hopkins
Inventor： Barry Freel , Geoffrey Hopkins
CPC classification number: B08B9/0436 , B08B9/00 , B08B9/045 , F23J3/02
Abstract: Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.
Abstract translation: 本文描述了用于减少热解和其它热转化过程中的累积沉积和不期望的二次热反应的系统和方法。 在一个实施例中，系统包括称为扩孔器的装置，用于去除热解过程的热转化和冷凝操作之间的产物沉积物。 铰刀可以包括但不限于机械往复杆或冲头，机械螺旋钻，钻头，高温刮水器，刷子或冲头以去除沉积物并防止二次反应。 或者或另外，铰刀可以使用蒸气，产物气体，再循环气体，其它气体射流或非冷凝液体的高速幕或射流（即液压或气动流）以去除沉积物。 优选地，铰刀在热解过程中除去沉积物，允许热解过程的连续操作。
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公开(公告)号：US09670413B2
公开(公告)日：2017-06-06
申请号：US13536538
申请日：2012-06-28
Applicant: Lance Awender Baird , Barry Freel , Doug Clarke , Gregory Joseph Morin
Inventor： Lance Awender Baird , Barry Freel , Doug Clarke , Gregory Joseph Morin
CPC classification number: C10B49/10 , C10B49/00 , C10B49/16 , C10B49/20 , C10B49/22 , C10B53/02 , Y02E50/14 , Y02P20/145
Abstract: Methods and apparatuses for thermally converting or pyrolyzing biomass are provided. In one embodiment, a method of thermally converting biomass includes introducing the biomass to a reactor feed chamber. The method provides for flowing a low oxygen gas into the reactor feed chamber to purge the reactor feed chamber and biomass of oxygen. The method also includes delivering the purged biomass to a thermal conversion reactor and thermally converting the biomass in the thermal conversion reactor.
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Patent Agency Ranking
公开(公告)号：US20140001026A1
公开(公告)日：2014-01-02
申请号：US13536538
申请日：2012-06-28
Applicant: Lance Awender Baird , Barry Freel , Doug Clarke , Gregory Joseph Morin
Inventor： Lance Awender Baird , Barry Freel , Doug Clarke , Gregory Joseph Morin
IPC: C10B43/00
CPC classification number: C10B49/10 , C10B49/00 , C10B49/16 , C10B49/20 , C10B49/22 , C10B53/02 , Y02E50/14 , Y02P20/145
Abstract: Methods and apparatuses for thermally converting or pyrolyzing biomass are provided. In one embodiment, a method of thermally converting biomass includes introducing the biomass to a reactor feed chamber. The method provides for flowing a low oxygen gas into the reactor feed chamber to purge the reactor feed chamber and biomass of oxygen. The method also includes delivering the purged biomass to a thermal conversion reactor and thermally converting the biomass in the thermal conversion reactor.
Abstract translation: 提供了用于热转化或热解生物质的方法和装置。 在一个实施方案中，热转化生物质的方法包括将生物质引入反应器进料室。 该方法提供了将低氧气流入反应器进料室以吹扫反应器进料室和氧气的生物质。 该方法还包括将净化的生物量输送到热转化反应器并热转化热转化反应器中的生物质。
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公开(公告)号：US20130327629A1
公开(公告)日：2013-12-12
申请号：US13810405
申请日：2011-07-08
Applicant: Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers
Inventor： Paolo Palmas , Paul A. Sechrist , Sid Kulprathipanja , Stanley J. Frey , Barry Freel , Daniel N. Myers
IPC: C10B23/00
CPC classification number: C10B23/00 , C10B49/22 , C10B53/02 , C10C5/00 , C10K1/026 , F23G5/0273 , F23G5/30 , F23G5/46 , F23G5/50 , F23G7/10 , F23G2201/303 , F23G2201/304 , F23G2201/601 , F23G2206/10 , F23G2900/50205 , Y02E50/14 , Y02P20/133 , Y02P20/145 , Y02P30/20
Abstract: Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.
Abstract translation: 提供了用于控制再热器中总体热平衡，灰分积累和再燃烧的焦炭处理过程。 碳质生物质原料使用形成热解产物和废热转移介质的传热介质进行热解。 废弃的传热介质被分离成分离的炭和贫乏的传热介质。 将贫乏的废热转移介质引入通过含氧再生气体流流化的传热介质的致密层中。 所有或部分分离的炭在密实床中使用含氧再生气体气流燃烧。 分离的焦炭的一部分可以从热解系统输出以控制总体热平衡和灰分积累。
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公开(公告)号：US20110123407A1
公开(公告)日：2011-05-26
申请号：US13021508
申请日：2011-02-04
Applicant: Barry Freel
Inventor： Barry Freel
IPC: B01J19/24
CPC classification number: C10B57/00 , C10B27/00 , C10B49/22 , C10B53/02 , C10G1/02 , C10G9/28 , C10K1/04 , F28C3/08 , Y02E50/14 , Y02P20/145
Abstract: The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.
Abstract translation: 本发明提供了改进的快速热转化方法，用于在大规模生产中有效地将木材，其他生物质材料和其它含碳原料（包括碳氢化合物）转化为高产量的有价值的液体产品，例如生物油。 在一个实施方案中，生物质材料（例如木材）进料到转化系统，其中生物质材料与向上的热热载体（例如沙子）混合，其将生物质热转化成热蒸气流。 热蒸汽流在位于转化系统下游的一个或多个冷凝室中用骤冷介质快速淬火。 快速淬火将蒸气流冷凝成液体产物，其作为有价值的液体产物从冷凝室收集。 在一个实施方案中，液体产物本身用作骤冷介质。
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公开(公告)号：US20090298927A1
公开(公告)日：2009-12-03
申请号：US12295916
申请日：2007-04-02
Applicant: David Boulard , Robert G. Graham , Barry Freel
Inventor： David Boulard , Robert G. Graham , Barry Freel
IPC: A61K31/337 , C07D305/14 , C07D311/04 , C07D473/04 , C07C45/78
CPC classification number: C07D305/14 , A61K36/00 , A61K36/13 , C10B49/22 , C10B53/02 , C10C5/00 , Y02E50/14
Abstract: The present invention is related to a thermal extract of a plant material and methods of extraction thereof. The method of producing a thermal extract from a plant starting material by means of a thermal extraction of the starting material wherein the improvement consists in requiring smaller amounts of costly and/or toxic organic solvents for the extraction and partitioning steps.
Abstract translation: 本发明涉及植物材料的热提取物及其提取方法。 通过原料的热提取从植物原料生产热提取物的方法，其中改进在于需要较少量的昂贵和/或有毒的有机溶剂用于萃取和分配步骤。
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20.发明申请MITIGATION OF DEPOSITS AND SECONDARY REACTIONS IN THERMAL CONVERSION PROCESSES 有权沉淀过程中的沉降和二次反应在热转化过程中公开(公告)号：US20090266380A1
公开(公告)日：2009-10-29
申请号：US12110197
申请日：2008-04-25
Applicant: Barry Freel , Geoffrey Hopkins
Inventor： Barry Freel , Geoffrey Hopkins
CPC classification number: B08B9/0436 , B08B9/00 , B08B9/045 , F23J3/02
Abstract: Described herein are systems and methods for reducing cumulative deposition and unwanted secondary thermal reactions in pyrolysis and other thermal conversion processes. In an embodiment, a system comprises a device, referred to as a reamer, for removing product deposits between thermal conversion and condensation operations of a pyrolysis process. The reamer may comprise, but is not limited to, a mechanical reciprocating rod or ram, a mechanical auger, a drill bit, a high-temperature wiper, brush, or punch to remove deposits and prevent secondary reactions. Alternatively or in addition, the reamer may use a high-velocity curtain or jet (i.e., a hydraulic or pneumatic stream) of vapor, product gas, recycle gas, other gas jet or non-condensing liquid to remove deposits. Preferably, the reamer removes deposits during the pyrolysis process allowing for continuous operation of the pyrolysis process.
Abstract translation: 本文描述了用于减少热解和其它热转化过程中的累积沉积和不期望的二次热反应的系统和方法。 在一个实施例中，系统包括称为扩孔器的装置，用于去除热解过程的热转化和冷凝操作之间的产物沉积物。 铰刀可以包括但不限于机械往复杆或冲头，机械螺旋钻，钻头，高温刮水器，刷子或冲头以去除沉积物并防止二次反应。 或者或另外，铰刀可以使用蒸气，产物气体，再循环气体，其它气体射流或非冷凝液体的高速幕或射流（即液压或气动流）以去除沉积物。 优选地，铰刀在热解过程中除去沉积物，允许热解过程的连续操作。
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