公开(公告)号：US20190100480A1

公开(公告)日：2019-04-04

申请号：US16146019

申请日：2018-09-28

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Julia A. KORNFIELD ,  Mark E. DAVIS ,  Ming-Hsin WEI ,  Simon C. JONES

IPC: C07C7/13 ,  C08G61/08

CPC classification number: C07C7/13 ,  C08G61/08 ,  C08G2261/11 ,  C08G2261/122 ,  C08G2261/3322 ,  C08G2261/3323 ,  C08G2261/418

Abstract: Described herein are compositions having an eight-membered monocyclic unsaturated hydrocarbon, methods and system to separate the eight-membered monocyclic unsaturated hydrocarbon at from a hydrocarbon mixture including additional nonlinear unsaturated C8H2m hydrocarbons with 4≤m≤8, by contacting the hydrocarbon mixture with a 10-ring pore molecular sieve having a sieving channel with a 10-ring sieving aperture with a minimum crystallographic free diameter greater than 3 Å and a ratio of the maximum crystallographic free diameter to the minimum crystallographic free diameter between 1 and 2, the molecular sieve having a T1/T2 ratio≥20:1 wherein T1 is an element independently selected from Si and Ge, and T2 is an element independently selected from Al, B and Ga, the 10-ring pore molecular sieve further having a counterion selected from NH4+, Na+, K+ and Ca++.

公开(公告)号：US20160272503A1

公开(公告)日：2016-09-22

申请号：US15044041

申请日：2016-02-15

Applicant: CALIFORNIA INSTITUTE OF TECHNOLOGY

Inventor： Raymond ARCHER ,  Mark E. DAVIS

IPC: C01B39/48 ,  B01J37/00 ,  B01J29/86 ,  B01J29/70 ,  B01J20/18 ,  B01J20/30

CPC classification number: C01B39/48 ,  B01J20/18 ,  B01J20/3057 ,  B01J29/047 ,  B01J29/70 ,  B01J29/7007 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J37/0018 ,  C01B37/005 ,  C01B37/007 ,  C01B37/02 ,  C01B39/04 ,  C01B39/08 ,  C01B39/12

Abstract: Method for preparing molecular sieves and molecular sieves obtained thereby are described. The method includes preparing a reaction mixture, comprising a structure directing agent, at least one source of at least one oxide of a tetravalent element, optionally, one or more sources of one or more oxides selected from the group consisting of oxides of trivalent elements, pentavalent elements, and mixtures thereof, optionally, at least one source of an element selected from Groups 1 and 2 of the Periodic Table; and optionally, hydroxide ions or fluoride ions, and maintaining the reaction mixture under conditions sufficient to form crystals of the molecular sieve. In the method, various imidazolium cations are used as the structure directing element.

Abstract translation: 对由此得到的分子筛和分子筛的制备方法进行了说明。 该方法包括制备反应混合物，其包含结构导向剂，至少一种四价元素氧化物的源，任选的一种或多种一种或多种氧化物源，所述氧化物选自三价元素的氧化物， 五价元素及其混合物，任选地，至少一种选自元素周期表第1和2组元素的源; 和任选的氢氧根离子或氟离子，并将反应混合物保持在足以形成分子筛结晶的条件下。 在该方法中，使用各种咪唑阳离子作为结构导向元件。

公开(公告)号：US20150004094A1

公开(公告)日：2015-01-01

申请号：US14318470

申请日：2014-06-27

Applicant: California Institute of Technology

Inventor： Joel SCHMIDT ,  Mark E. DAVIS

IPC: B01J29/85 ,  B01J29/84 ,  B01J29/04 ,  B01J29/83

CPC classification number: B01J29/85 ,  B01J29/035 ,  B01J29/041 ,  B01J29/047 ,  B01J29/7003 ,  B01J29/83 ,  B01J29/84 ,  B01J29/86 ,  B01J29/87 ,  B01J29/88 ,  B01J29/89 ,  B01J2229/183 ,  C01B39/026 ,  C01B39/06 ,  C01B39/145 ,  C01B39/54

Abstract: A method for preparing molecular sieves with a Linde Type A (LTA) topology structure, and molecular sieves obtained thereby are described wherein a structure directing agent comprising a triquaternary cation is contacted with a source of a first oxide of a first tetravalent element or a source of a first oxide of a trivalent element; and a source of an oxide of a pentavalent elements.

Abstract translation: 描述了一种用于制备具有林德A型（LTA）拓扑结构的分子筛的方法和由此获得的分子筛，其中包含三元阳离子的结构导向剂与第一四价元素或源的第一氧化物源接触 的三价元素的第一氧化物; 和五价元素的氧化物源。