公开(公告)号：US09968918B2

公开(公告)日：2018-05-15

申请号：US14404776

申请日：2012-07-27

申请人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

发明人： Xionghou Gao ,  Haitao Zhang ,  Di Li ,  Zhengguo Tan ,  Hongchang Duan ,  Xueli Li ,  Chaowei Liu ,  Yunfeng Zheng ,  Xiaoliang Huang ,  Jinjun Cai ,  Zhishuang Pan ,  Xueqin Sun

IPC分类号： B01J29/06 ,  B01J29/85 ,  C01B39/24 ,  C01B39/02 ,  B01J35/10 ,  C10G11/05 ,  B01J37/28 ,  B01J29/08 ,  B01J29/40 ,  B01J21/16 ,  B01J29/70 ,  B01J29/80 ,  B01J37/06 ,  B01J37/08 ,  B01J37/30 ,  B01J35/00 ,  B01J37/00 ,  B01J29/60 ,  B01J37/04

CPC分类号： B01J29/85 ,  B01J21/16 ,  B01J29/084 ,  B01J29/088 ,  B01J29/40 ,  B01J29/605 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7049 ,  B01J29/80 ,  B01J35/002 ,  B01J35/10 ,  B01J35/109 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  B01J37/28 ,  B01J37/30 ,  B01J2229/18 ,  B01J2229/186 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/40 ,  B01J2229/42 ,  C01B39/026 ,  C01B39/24 ,  C10G11/05 ,  C10G2400/30

摘要： The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material. The raw material is subjected to a rare-earth exchange and a dispersing pre-exchange; the molecular sieve slurry is then filtered, washed with water and subjected to a first calcination to obtain a rare earth sodium Y molecular sieve which has been subjected to such “first-exchange first-calcination”, wherein the steps of rare earth exchange and dispersing pre-exchange are not restricted in sequence; and then the rare earth sodium Y molecular sieve which has been subjected to “one-exchange one-calcination” is subjected to “second exchange and second calcination” including ammonium exchange and a phosphorus modification, wherein the steps of the ammonium exchange and the phosphorus modification are not restricted in sequence. The steps of the ammonium exchange and the phosphorus modification can be conducted continuously or non-continuously, the second calcination is conducted after the ammonium exchange for reducing sodium, the phosphorus modification can be conducted before or after the second calcination. The catalyst provided by the invention has the characteristics of high heavy oil conversion capacity, high total liquid yield, and high yield of light oil.

公开(公告)号：US09580329B2

公开(公告)日：2017-02-28

申请号：US13740839

申请日：2013-01-14

申请人： Rive Technology, Inc.

发明人： Kunhao Li ,  Javier Garcia-Martinez ,  Michael G. Beaver

IPC分类号： B01J29/06 ,  C01B39/02 ,  C01B39/22 ,  C01B39/14 ,  C01B39/04 ,  B01J29/04 ,  B01J29/70 ,  B01J29/08 ,  B01J37/00 ,  B01J35/10

CPC分类号： C01B39/026 ,  B01J29/041 ,  B01J29/082 ,  B01J29/7003 ,  B01J35/1033 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/109 ,  B01J37/0018 ,  C01B39/04 ,  C01B39/14 ,  C01B39/22

摘要： Mesoporous X and A zeolites and methods for production thereof are disclosed herein. Such mesoporous zeolites can be prepared by contacting an initial zeolite with an acid in conjunction with a mesopore forming agent. The initial zeolite can have a framework silicon-to-aluminum content in the range of from about 1 to about 2.5. Additionally, such mesoporous zeolites can have a total 20 to 135 Å diameter mesopore volume of at least 0.05 cc/g.

摘要翻译： 介孔X和A沸石及其生产方法在本文中公开。 这种介孔沸石可以通过使初始沸石与酸与中孔形成剂结合使其接触来制备。 初始沸石可以具有在约1至约2.5范围内的骨架硅 - 铝含量。 此外，这种介孔沸石可以具有至少0.05cc / g的总直径为20至135的中孔体积。

公开(公告)号：US09434708B2

公开(公告)日：2016-09-06

申请号：US14369485

申请日：2012-12-27

申请人： Furanix Technologies B.V.

发明人： Ana Sofia Vagueiro De Sousa Dias ,  Jan Cornelis Van Der Waal ,  Etienne Mazoyer

IPC分类号： C07D307/48 ,  B01J21/08 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/70

CPC分类号： C07D307/48 ,  B01J21/08 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  B01J29/60 ,  B01J29/7003 ,  B01J29/7007

摘要： In a process for carrying out a reaction, a liquid reaction mixture is contacted with a catalyst that includes silica and/or a silicate, in which process a silicon compound that is soluble in the liquid reaction mixture is added to the reaction mixture before being contacted with the catalyst. The aqueous reaction mixture suitably contains water, an alcohol or a mixture thereof.

摘要翻译： 在进行反应的过程中，将液体反应混合物与包括二氧化硅和/或硅酸盐的催化剂接触，其中在接触之前将可溶于液体反应混合物的硅化合物加入到反应混合物中 与催化剂。 含水反应混合物适当地含有水，醇或其混合物。

公开(公告)号：US09278340B2

公开(公告)日：2016-03-08

申请号：US13059932

申请日：2009-08-20

申请人： Inder Pal Singh ,  Shradha Singh ,  Ritesh Patel ,  Bharat Mistry ,  Manish Mehta ,  Peter Omolo Otieno

发明人： Inder Pal Singh ,  Shradha Singh ,  Ritesh Patel ,  Bharat Mistry ,  Manish Mehta ,  Peter Omolo Otieno

IPC分类号： B01J29/06 ,  B01J23/10 ,  B01J23/00 ,  B01J27/26 ,  B01J29/70 ,  B01J35/00 ,  B01J37/00 ,  B01J37/03 ,  C07B41/12 ,  C07C67/03 ,  C07C67/08 ,  C10L1/02 ,  C11C3/00

CPC分类号： C07C67/08 ,  B01J23/002 ,  B01J23/10 ,  B01J27/26 ,  B01J29/06 ,  B01J29/072 ,  B01J29/076 ,  B01J29/7003 ,  B01J29/7053 ,  B01J35/0006 ,  B01J37/0009 ,  B01J37/03 ,  B01J2229/42 ,  B01J2523/00 ,  C07B41/12 ,  C07C67/03 ,  C10G2300/1011 ,  C10L1/026 ,  C10L2200/0476 ,  C10L2270/026 ,  C11C3/003 ,  C11C3/10 ,  Y02E50/13 ,  Y02P30/20 ,  C07C69/52 ,  C07C69/24 ,  B01J2523/27 ,  B01J2523/3706 ,  B01J2523/23 ,  B01J2523/31

摘要： Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.

摘要翻译： 描述了用于将甘油三酯和游离脂肪酸转化为生物柴油的固体混合催化剂和方法。 可以使用间歇或连续方法与用于甘油三酯与烷基醇的酯交换的催化剂以高产率和纯度产生相应的单羧酸酯和甘油。 类似地，烷基和芳基羧酸和游离脂肪酸也被转化为相应的烷基酯。 所描述的催化剂是耐热的，持久的和高活性的。

公开(公告)号：US20120296138A1

公开(公告)日：2012-11-22

申请号：US13457502

申请日：2012-04-27

申请人： Joseph E. Pelati

发明人： Joseph E. Pelati

IPC分类号： C07C2/88 ,  B01J8/02

CPC分类号： B01J8/12 ,  B01J8/08 ,  B01J8/085 ,  B01J8/10 ,  B01J8/125 ,  B01J8/24 ,  B01J29/068 ,  B01J29/072 ,  B01J29/076 ,  B01J29/08 ,  B01J29/082 ,  B01J29/084 ,  B01J29/085 ,  B01J29/087 ,  B01J29/10 ,  B01J29/103 ,  B01J29/16 ,  B01J29/163 ,  B01J29/40 ,  B01J29/60 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7038 ,  B01J29/90 ,  B01J2208/00557 ,  B01J2219/0004 ,  B01J2229/186 ,  C07C2/862 ,  C07C2529/08 ,  C07C2529/10 ,  C07C2529/16 ,  Y02P20/584 ,  C07C15/46

摘要： A method is disclosed for making styrene and/or ethylbenzene by reacting toluene with a C1 source in the presence of a catalyst in a reactor sized and configured to provide for a moving catalyst bed therethrough to form a product stream including styrene and/or ethylbenzene.

摘要翻译： 公开了一种制备苯乙烯和/或乙苯的方法，该方法是在催化剂存在下，通过甲苯与C1源反应来制备苯乙烯和/或乙苯，其尺寸和构造为提供通过其移动的催化剂床，以形成包含苯乙烯和/或乙苯的产物流。

公开(公告)号：US20120258852A1

公开(公告)日：2012-10-11

申请号：US13440781

申请日：2012-04-05

申请人： Javier Garcia Martinez ,  Ernest Senderov ,  Richard Hinchey

发明人： Javier Garcia Martinez ,  Ernest Senderov ,  Richard Hinchey

IPC分类号： C01B39/02 ,  C01B39/20 ,  C01B39/26 ,  B01J29/06 ,  C01B39/42 ,  C01B39/44 ,  C01B39/24 ,  C01B39/14 ,  C01B39/38

CPC分类号： C01B39/026 ,  B01J29/041 ,  B01J29/08 ,  B01J29/084 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7015 ,  B01J29/7034 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/109 ,  B01J37/0018 ,  B01J2229/16 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38

摘要： Compositions and methods for preparing mesoporous and/or mesostructured materials from low Si/Al zeolites. Various embodiments described herein relate to preparation of mesoporous and/or mesostructured zeolites via a framework modification step followed by a mesopore introduction step.

摘要翻译： 用于从低Si / Al沸石制备介孔和/或介孔结构材料的组合物和方法。 本文所述的各种实施方案涉及通过框架改性步骤制备介孔和/或介孔结构的沸石，然后进行介孔引入步骤。

公开(公告)号：US20120167453A1

公开(公告)日：2012-07-05

申请号：US13380298

申请日：2010-06-22

申请人： Thomas Willner

发明人： Thomas Willner

IPC分类号： C10L1/00

CPC分类号： C10G3/40 ,  B01J29/7003 ,  C10G1/02 ,  C10G3/60 ,  C10G2300/1014 ,  C10G2300/1018 ,  Y02E50/14 ,  Y02P30/20

摘要： The invention relates to a method for producing crude oil from biomass by direct liquefaction under atmospheric pressure, involving the following steps: introducing dried biomass into a reactor containing heavy oil to form a sump oil phase consisting of biomass and heavy oil; maintaining the temperature of the sump oil phase at a predetermined reaction temperature; condensing and collecting the volatile reaction products; and isolating and collecting the crude oil. Said method is characterized in that the heavy oil phase has at least 5 wt. % organically bound oxygen.

摘要翻译： 本发明涉及通过在大气压下直接液化从生物质生产原油的方法，包括以下步骤：将干燥的生物质引入含有重油的反应器中以形成由生物质和重油组成的油底壳; 将油底壳油相的温度保持在预定的反应温度; 冷凝收集挥发性反应产物; 并分离和收集原油。 所述方法的特征在于重油相具有至少5wt。 ％有机结合氧。

公开(公告)号：US08197669B2

公开(公告)日：2012-06-12

申请号：US12277434

申请日：2008-11-25

申请人： Albert A. Vierheilig

发明人： Albert A. Vierheilig

IPC分类号： C10G11/05 ,  C10G11/00 ,  C10G11/02 ,  C10G11/04

CPC分类号： C10G11/05 ,  B01J21/005 ,  B01J23/007 ,  B01J23/02 ,  B01J29/06 ,  B01J29/084 ,  B01J29/088 ,  B01J29/60 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/78 ,  B01J29/7807 ,  B01J29/7815 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1042 ,  B01J37/0045 ,  B01J2229/42 ,  C10G11/02 ,  C10G11/18 ,  C10G2300/205 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/28

摘要： The present invention is directed to catalytic cracking additives comprising a metals trapping material; and a high activity catalyst. The present invention is directed to processes for the catalytic cracking of feedstock comprising contacting said feedstock under catalytic cracking conditions with a composition comprising a bulk catalyst and a catalytic cracking additive, wherein the catalytic cracking additive comprises a metals trapping material; and a high activity catalyst. The invention is also directed to processes for increasing the performance of a bulk catalyst in the presence of at least one metal comprising contacting a feedstock with a catalytic cracking additive comprising a metals trapping material; and a high activity catalyst.

摘要翻译： 本发明涉及包含金属捕获材料的催化裂化添加剂; 和高活性催化剂。 本发明涉及原料的催化裂化方法，包括在催化裂化条件下将所述原料与包含本体催化剂和催化裂化添加剂的组合物接触，其中催化裂化添加剂包括金属捕获材料; 和高活性催化剂。 本发明还涉及在至少一种金属的存在下增加本体催化剂的性能的方法，包括使原料与包含金属捕集材料的催化裂化添加剂接触; 和高活性催化剂。

公开(公告)号：US20090291828A1

公开(公告)日：2009-11-26

申请号：US12497460

申请日：2009-07-02

申请人： Kazushige OHNO ,  Masafumi KUNIEDA ,  Takahiko IDO

发明人： Kazushige OHNO ,  Masafumi KUNIEDA ,  Takahiko IDO

IPC分类号： B01J29/06 ,  B01J29/072 ,  B01J29/40 ,  B01J29/18 ,  B01J29/08

CPC分类号： B01D53/9418 ,  B01D46/2429 ,  B01D46/2444 ,  B01D46/2448 ,  B01D46/2459 ,  B01D2046/2496 ,  B01D2251/2067 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/20738 ,  B01D2255/50 ,  B01D2279/30 ,  B01J29/06 ,  B01J29/072 ,  B01J29/076 ,  B01J29/084 ,  B01J29/146 ,  B01J29/40 ,  B01J29/46 ,  B01J29/60 ,  B01J29/63 ,  B01J29/65 ,  B01J29/68 ,  B01J29/7003 ,  B01J29/7007 ,  B01J29/7607 ,  B01J29/7615 ,  B01J35/04 ,  B01J35/06 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/346 ,  C04B28/001 ,  C04B28/24 ,  C04B28/26 ,  C04B35/18 ,  C04B35/803 ,  C04B38/0019 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/3427 ,  C04B2235/3463 ,  Y02A50/2325 ,  C04B12/04 ,  C04B14/047 ,  C04B14/10 ,  C04B14/30 ,  C04B14/303 ,  C04B14/4625 ,  C04B24/383 ,  C04B14/4612 ,  C04B14/4693 ,  C04B14/4631 ,  C04B14/4681

摘要： A honeycomb structure includes a plurality of honeycomb units and an adhesive layer. Each of the plurality of honeycomb units has a longitudinal direction and includes zeolite, an inorganic binder, a first end face, a second end face, and a cell wall. The second end face is located opposite to the first end face in the longitudinal direction. The cell wall extends from the first end face to the second end face along the longitudinal direction to define cells. The adhesive layer includes zeolite and is provided between the plurality of honeycomb units to connect the plurality of honeycomb units. A ratio of a coefficient of thermal expansion of the adhesive layer to a coefficient of thermal expansion of each of the plurality of honeycomb units is in a range from approximately 0.8 to approximately 1.2.

摘要翻译： 蜂窝结构体包括多个蜂窝单元和粘合剂层。 多个蜂窝单元中的每一个具有纵向方向，并且包括沸石，无机粘合剂，第一端面，第二端面和泡孔壁。 第二端面在纵向方向上与第一端面相对。 细胞壁沿着纵向方向从第一端面延伸到第二端面以限定细胞。 粘合剂层包括沸石，并且设置在多个蜂窝单元之间以连接多个蜂窝单元。 粘合剂层的热膨胀系数与多个蜂窝单元中的每一个的热膨胀系数的比率在大约0.8至大约1.2的范围内。

公开(公告)号：US20060030477A1

公开(公告)日：2006-02-09

申请号：US11165570

申请日：2005-06-24

申请人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

发明人： Alexandra Chaumonnot ,  Aurelie Coupe ,  Clement Sanchez ,  Patrick Euzen ,  Cedric Boissiere ,  David Grosso

IPC分类号： B01J29/04 ,  B01J29/06 ,  B01J29/87

CPC分类号： C01B37/02 ,  B01J29/005 ,  B01J29/0308 ,  B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/7003 ,  B01J37/0045 ,  B01J2229/62 ,  C01B39/04 ,  C01B39/40

摘要： A material with a hierarchical porosity is described, constituted by at least two spherical elementary particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 20 nm, said spherical elementary particles having a maximum diameter of 10 μm. the matrix based on silicon oxide may contain aluminium. The preparation of said material is also described.

摘要翻译： 描述具有分层孔隙率的材料，由至少两个球形基本粒子构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm的范围内，并且具有厚度在1至20nm范围内的非晶壁，所述球形基本粒子的最大直径为10μm。 基于氧化硅的基体可以含有铝。 还描述了所述材料的制备。