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公开(公告)号:US20210024671A1
公开(公告)日:2021-01-28
申请号:US17068486
申请日:2020-10-12
Applicant: Chevron Phillips Chemical Company LP
Inventor: Ashish M. SUKHADIA , Guylaine ST. JEAN , Qing YANG , Max P. MCDANIEL
IPC: C08F210/16 , C08F10/02 , C08F10/08 , C08F10/14 , C08J5/18 , C08L23/08 , C08F210/18 , C08F210/02
Abstract: An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.
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公开(公告)号:US20200377630A1
公开(公告)日:2020-12-03
申请号:US16990820
申请日:2020-08-11
Applicant: Chevron Phillips Chemical Company LP
Inventor: Max P. MCDANIEL , Eric D. SCHWERDTFEGER , Jeremy M. PRAETORIUS
IPC: C08F110/02 , C08F4/18 , C08F4/24
Abstract: A hydrogel comprising water, and a plurality of titanium-silica-chromium nanoparticle agglomerates, wherein each titanium-silica-chromium nanoparticle agglomerate is an agglomeration of titanium-silica-chromium nanoparticles, the agglomerates having an average titanium penetration depth designated x with a coefficient of variation for the average titanium penetration depth of less than about 1.0 wherein a silica content of the hydrogel is of from about 10 wt. % to about 35 wt. % based on a total weight of the hydrogel.
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公开(公告)号:US20200369803A1
公开(公告)日:2020-11-26
申请号:US16990816
申请日:2020-08-11
Applicant: Chevron Phillips Chemical Company LP
Inventor: Max P. MCDANIEL , Eric D. SCHWERDTFEGER , Jeremy M. PRAETORIUS
IPC: C08F110/02 , C08F4/18 , C08F4/24
Abstract: A hydrogel comprising water, and a plurality of titanium-silica nanoparticle agglomerates, wherein each titanium-silica nanoparticle agglomerate is an agglomeration of titanium-silica nanoparticles, the agglomerates having an average titanium loading designated x with a coefficient of variation for the average titanium loading of less than about 1.0, wherein a silica content of the hydrogel is of from about 10 wt. % to about 35 wt. % based on a total weight of the hydrogel.
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公开(公告)号:US20180305473A1
公开(公告)日:2018-10-25
申请号:US15495116
申请日:2017-04-24
Applicant: Chevron Phillips Chemical Company LP
Inventor: Eric D. SCHWERDTFEGER , Max P. MCDANIEL , Ted H. CYMBALUK , Jeremy M. PRAETORIUS , Kathy S. CLEAR , Alan L. SOLENBERGER
IPC: C08F10/02
CPC classification number: C08F10/02 , B01J23/26 , B01J35/023 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J37/0203 , B01J37/0205 , B01J37/08 , B01J37/086 , B01J37/14 , B01J2523/00 , C08F2/34 , C08F4/025 , C08F4/24 , C08F4/76 , C08F4/78 , C08F110/02 , B01J2523/41 , B01J2523/47 , B01J2523/67
Abstract: A method comprising calcining a catalyst precursor comprising chromium and a silica support material at a temperature in the range of from about 95° C. to about 400° C. in a bed fluidized by a gas flowing at a volumetric flow rate of from about 2.5 to about 30 times the settled volume of the bed per minute to form a calcined catalyst precursor. A method comprising calcining a catalyst precursor comprising chromium and silica at a temperature in the range of from about 95° C. to about 400° C. with a gas flowing through the bed at a gas hourly space velocity of from about 15 to about 200 per hour. A method comprising calcining a catalyst precursor comprising chromium and silica at a temperature in the range of from about 95° C. to about 400° C. with a gas flowing through the bed at a weight hourly space velocity of from about 1.9 to about 240 per hour.
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公开(公告)号:US20170080406A1
公开(公告)日:2017-03-23
申请号:US14858512
申请日:2015-09-18
Applicant: Chevron Phillips Chemical Company LP
Inventor: Jeremy M. PRAETORIUS , Eric D. SCHWERDTFEGER , Max P. MCDANIEL , Ted H. CYMBALUK , Connor D. BOXELL , Alan L. SOLENBERGER , Kathy S. CLEAR
CPC classification number: B01J23/26 , B01J21/08 , B01J35/1019 , B01J35/1023 , B01J35/1047 , B01J37/0203 , B01J37/0236 , B01J37/08 , C08F10/02 , C08F110/02 , C08F4/22 , C08F4/24 , C08F4/025 , C08F4/16 , C08F2500/12
Abstract: A method comprising a) drying a support material comprising silica at temperature in the range of from about 150° C. to about 220° C. to form a dried support; b) contacting the dried support with methanol to form a slurried support; c) subsequent to b), cooling the slurried support to a temperature of less than about 60° C. to form a cooled slurried support; d) subsequent to c), contacting the cooled slurried support with a titanium alkoxide to form a titanated support; and e) thermally treating the titanated support by heating to a temperature of equal to or greater than about 150° C. for a time period of from about 5 hours to about 30 hours to remove the methanol and yield a dried titanated support.
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公开(公告)号:US20140256901A1
公开(公告)日:2014-09-11
申请号:US13794052
申请日:2013-03-11
Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
Inventor: Ashish M. SUKHADIA , Guylaine ST. JEAN , Qing YANG , Max P. MCDANIEL
CPC classification number: C08F10/02 , C08F10/04 , C08F10/06 , C08F10/08 , C08F10/10 , C08F10/14 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2203/16 , C08L2205/025
Abstract: An ethylene alpha-olefin copolymer having (a) a density of from about 0.910 g/cc to about 0.940 g/cc; (b) a weight average molecular weight of from about 150,000 g/mol to about 300,000 g/mol; and (c) a melt index at a load of 2.16 kg of from about 0.01 dg/10 min. to about 0.5 dg/min.; wherein a 1 mil blown film formed from the polymer composition is characterized by (i) a Dart Impact strength greater than about 175 g/mil; (ii) an Elmendorf machine direction tear strength greater than about 20 g/mil; and (iii) an Elmendorf transverse direction tear strength greater than about 475 g/mil.
Abstract translation: 一种乙烯α-烯烃共聚物,其具有(a)约0.910g / cc至约0.940g / cc的密度; (b)重均分子量为约150,000g / mol至约300,000g / mol; 和(c)2.16kg负荷下的熔体指数为约0.01dg / 10min。 至约0.5dg / min。 其中由所述聚合物组合物形成的1密耳吹塑膜的特征在于(i)大于约175g / mil的落镖冲击强度; (ii)Elmendorf机器方向撕裂强度大于约20g / mil; 和(iii)Elmendorf横向撕裂强度大于约475g / mil。
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公开(公告)号:US20220144982A1
公开(公告)日:2022-05-12
申请号:US17579777
申请日:2022-01-20
Applicant: Chevron Phillips Chemical Company LP
Inventor: Max P. MCDANIEL , Eric D. SCHWERDTFEGER , Jeremy M. PRAETORIUS
IPC: C08F110/02 , C08F4/24 , C08F4/18
Abstract: A hydrogel comprising water, and a plurality of titanium-silica-chromium nanoparticle agglomerates, wherein each titanium-silica-chromium nanoparticle agglomerate is an agglomeration of titanium-silica-chromium nanoparticles, the agglomerates having an average titanium penetration depth designated x with a coefficient of variation for the average titanium penetration depth of less than about 1.0 wherein a silica content of the hydrogel is of from about 10 wt. % to about 35 wt. % based on a total weight of the hydrogel.
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18.
公开(公告)号:US20210292446A1
公开(公告)日:2021-09-23
申请号:US17340438
申请日:2021-06-07
Applicant: Chevron Phillips Chemical Company LP
Inventor: Max P. MCDANIEL , Kathy S. CLEAR , William C. ELLIS , Deloris R. GAGAN
Abstract: A method comprising contacting a silica support with a titanium-containing solution to form a titanated silica support, wherein the titanium-containing solution comprises a titanium compound, a solvent, and an amino acid.
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公开(公告)号:US20190134610A1
公开(公告)日:2019-05-09
申请号:US16237011
申请日:2018-12-31
Applicant: Chevron Phillips Chemical Company LP
Inventor: Jeremy M. PRAETORIUS , Eric D. SCHWERDTFEGER , Max P. MCDANIEL , Ted H. CYMBALUK , Connor D. BOXELL , Alan L. SOLENBERGER , Kathy S. CLEAR
Abstract: A method comprising a) drying a support material comprising silica at temperature in the range of from about 150° C. to about 220° C. to form a dried support; b) contacting the dried support with methanol to form a slurried support; c) subsequent to b), cooling the slurried support to a temperature of less than about 60° C. to form a cooled slurried support; d) subsequent to c), contacting the cooled slurried support with a titanium alkoxide to form a titanated support; and e) thermally treating the titanated support by heating to a temperature of equal to or greater than about 150° C. for a time period of from about 5 hours to about 30 hours to remove the methanol and yield a dried titanated support.
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公开(公告)号:US20140275457A1
公开(公告)日:2014-09-18
申请号:US13799516
申请日:2013-03-13
Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LP
Inventor: Max P. MCDANIEL , Kathy S. COLLINS , Eric D. SCHWERDTFEGER , Alan L. SOLENBERGER
IPC: C08F4/22
CPC classification number: C08F4/22 , C08F10/00 , C08F4/24 , C08F4/025 , C08F110/02 , C08F2500/12
Abstract: A method comprising contacting a support material with a transition metal compound to produce a mixture; thermally treating the mixture in the presence of oxygen at a temperature in a range of from about 100° C. to about 500° C. for a period of from about 1 hour to about 10 hours, wherein at least a portion of the transition metal sublimes onto the support material to produce a support material comprising a dispersed transition metal; and thermally treating the support material comprising the dispersed transition metal in an oxidizing atmosphere at a temperature in a range of from about 550° C. to about 900° C. for a period of from about 1 hour to about 10 hours to produce a polymerization catalyst.
Abstract translation: 一种方法,包括使支撑材料与过渡金属化合物接触以产生混合物; 在氧气存在下,在约100℃至约500℃的温度范围内热处理混合物约1小时至约10小时,其中至少一部分过渡金属 升华到支撑材料上以产生包含分散的过渡金属的支撑材料; 并在包含分散的过渡金属的载体材料的氧化气氛中,在约550℃至约900℃的温度范围内热处理约1小时至约10小时,以产生聚合 催化剂。
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