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公开(公告)号：US20200299471A1
公开(公告)日：2020-09-24
申请号：US16607634
申请日：2018-04-26
Applicant: CORNING INCORPORATED
Inventor： Jun Hou , Kevin Robert McCarthy
Abstract: Described herein are articles and methods of making articles, including a transparent composite film having a fiber filler embedded in a polymer network. The polymer network of the transparent composite film is a cured, cross-linked matrix including a first and second structure segment. The structure segments may contribute or impart improved properties in the transparent composite film. The select structure segments can provide increased modulus and reduced glass transition temperature thereby allowing for a desirable balance of flexibility and rigidity in the transparent composite film. The improved transparent composite film is suitable for many applications including use in display devices.
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12.发明申请公开(公告)号：US20160177092A1
公开(公告)日：2016-06-23
申请号：US14957095
申请日：2015-12-02
Applicant: Corning Incorporated
Inventor： Kevin Robert McCarthy , David Neal Schissel
CPC classification number: C08L75/08 , C08G18/12 , C08G18/2825 , C08G18/3206 , C08G18/4825 , C08G18/758 , C08G18/8175 , C08G18/48
Abstract: A non-radiation curable reinforcing agent for optical fiber coatings and coating compositions. The reinforcing agent includes structurally flexible soft block segments and structurally rigid hard block segments. The soft block segments and hard block segments include urethane or urea linkages and act as strengthening additives in optical fiber coatings. Strength reinforcement occurs through interactions of the reinforcing agent with the polymeric network formed from curable components of the coating composition. Interactions include physical entanglements and hydrogen bonding. Soft block segments include block units that may include high molecular weight polyol linkages and soft block segments include block units that may include low molecular weight alkylene linkages. Coatings that include the reinforcing agents exhibit low Young's modulus, high tensile strength, and low glass transition temperatures and are suitable for use as primary coatings in optical fibers.
Abstract translation: 用于光纤涂层和涂料组合物的非辐射固化增强剂。 增强剂包括结构上柔性的软块段和结构刚性硬块段。 软块段和硬块段包括氨基甲酸酯或脲键，并且在光纤涂层中用作强化添加剂。 通过增强剂与由涂料组合物的可固化组分形成的聚合物网络的相互作用发生强度增强。 相互作用包括物理缠结和氢键。 软嵌段段包括可以包括高分子量多元醇键的嵌段单元，软嵌段部分包括可以包括低分子量亚烷基键的嵌段单元。 包括增强剂的涂层表现出低的杨氏模量，高拉伸强度和低玻璃化转变温度，并且适合用作光纤中的主要涂层。
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公开(公告)号：US09322991B2
公开(公告)日：2016-04-26
申请号：US14603874
申请日：2015-01-23
Applicant: Corning Incorporated
Inventor： Dana Craig Bookbinder , Kevin Robert McCarthy , Weijun Niu , David Neal Schissel
CPC classification number: G02B6/03694 , C03C25/106 , C03C25/285 , G02B1/045 , G02B1/12 , G02B1/14 , G02B6/02395
Abstract: Coating compositions that include acrylic polymers as reinforcing agents. The coating compositions are radiation-curable and include a multifunctional acrylate component, an acrylic monomer diluent, an acrylic polymer, and a photoinitiator. The acrylic polymer is not radiation-curable and lacks hydrogen-donor groups, urea groups, and urethane groups. The acrylic polymer is non-reactive and does not chemically bond to the crosslinked network formed by curing the acrylate components. Instead, the acrylic polymer reinforces the cured network through physical interactions. Representative acrylic polymers include (meth)acrylates that lack substituents with hydrogen-donor, urea, and urethane groups.
Abstract translation: 包括丙烯酸聚合物作为增强剂的涂料组合物。 涂料组合物是可辐射固化的，并且包括多官能丙烯酸酯组分，丙烯酸类单体稀释剂，丙烯酸聚合物和光引发剂。 丙烯酸聚合物不是可辐射固化的，并且缺乏氢供体基团，脲基团和氨基甲酸酯基团。 丙烯酸类聚合物是非反应性的，并且不化学键合到通过固化丙烯酸酯组分形成的交联网络。 相反，丙烯酸聚合物通过物理相互作用增强了固化网络。 代表性的丙烯酸类聚合物包括不具有氢供体，尿素和氨基甲酸酯基团的取代基的（甲基）丙烯酸酯。
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公开(公告)号：US20150219845A1
公开(公告)日：2015-08-06
申请号：US14603874
申请日：2015-01-23
Applicant: Corning Incorporated
Inventor： Dana Craig Bookbinder , Kevin Robert McCarthy , Weijun Niu , David Neal Schissel
CPC classification number: G02B6/03694 , C03C25/106 , C03C25/285 , G02B1/045 , G02B1/12 , G02B1/14 , G02B6/02395
Abstract: Coating compositions that include acrylic polymers as reinforcing agents. The coating compositions are radiation-curable and include a multifunctional acrylate component, an acrylic monomer diluent, an acrylic polymer, and a photoinitiator. The acrylic polymer is not radiation-curable and lacks hydrogen-donor groups, urea groups, and urethane groups. The acrylic polymer is non-reactive and does not chemically bond to the crosslinked network formed by curing the acrylate components. Instead, the acrylic polymer reinforces the cured network through physical interactions. Representative acrylic polymers include (meth)acrylates that lack substituents with hydrogen-donor, urea, and urethane groups.
Abstract translation: 包括丙烯酸聚合物作为增强剂的涂料组合物。 涂料组合物是可辐射固化的，并且包括多官能丙烯酸酯组分，丙烯酸类单体稀释剂，丙烯酸聚合物和光引发剂。 丙烯酸聚合物不是可辐射固化的，并且缺乏氢供体基团，脲基团和氨基甲酸酯基团。 丙烯酸类聚合物是非反应性的，并且不化学键合到通过固化丙烯酸酯组分形成的交联网络。 相反，丙烯酸聚合物通过物理相互作用增强了固化网络。 代表性的丙烯酸类聚合物包括不具有氢供体，尿素和氨基甲酸酯基团的取代基的（甲基）丙烯酸酯。
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公开(公告)号：US20140341521A1
公开(公告)日：2014-11-20
申请号：US14248737
申请日：2014-04-09
Applicant: Corning Incorporated
Inventor： Michelle Dawn Fabian , Kevin Robert McCarthy , Weijun Niu , David Neal Schissel , Michael James Winningham
CPC classification number: G02B6/245 , C03C25/1065 , C09D4/06 , G02B1/12 , G02B6/02395
Abstract: A low cost composition that cures rapidly and which is suitable for coating an optical fiber comprises at least one ethylenically unsaturated monomer; at least one photoinitiator; and at least one non-radiation-curable polar polymer having pendent groups that facilitate low energy chemical bonding, hydrogen bonding, dipolar interactions or other interactions with radical compounds formed during polymerization of the monomer. The non-radiation-curable polar polymer(s) are inexpensive and reduce and/or eliminate the need for expensive urethane acrylate oligomers, without sacrificing properties, and while achieving rapid cure speeds.
Abstract translation: 固化快速且适用于光纤涂层的低成本组合物包含至少一种烯属不饱和单体; 至少一种光引发剂; 以及具有侧基的至少一种不可辐射固化的极性聚合物，其有助于低聚能量化学键合，氢键合，偶极相互作用或与单体聚合期间形成的自由基化合物的其它相互作用。 不可辐射固化的极性聚合物是便宜的，并且在不牺牲性能的同时降低和/或消除对昂贵的聚氨酯丙烯酸酯低聚物的需要，并且同时实现快速固化速度。
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Patent Agency Ranking
公开(公告)号：US20240367420A1
公开(公告)日：2024-11-07
申请号：US18290835
申请日：2022-07-11
Applicant: Corning Incorporated
Inventor： Kiyomi DeLige Fahy , Jenny Kim , Lingke Li , Yang Li , Kevin Robert McCarthy , Hongxiang Wang , Arlin Lee Weikel
Abstract: Laminates can comprise a substrate and a film. The film can comprise a film thickness from about 5 micrometers to about 400 micrometers and a tri-block copolymer comprising a first block positioned between two second blocks. The first block can be grafted with a first functional group. The first block can comprise a first glass transition temperature of about 0° C. or less. The two second blocks can each comprise a glass transition temperature of about 50° C. or more. A combined weight of the two second blocks can be from about 10 wt % to about 50 wt % of the tri-block copolymer. The film can comprise a refractive index from about 1.48 to about 1.55. Methods of forming a laminate can comprise disposing a film over a substrate. Methods can further comprise heating the film and the substrate to a first temperature and then a second temperature.
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17.发明授权公开(公告)号：US11709291B2
公开(公告)日：2023-07-25
申请号：US16965218
申请日：2019-01-25
Applicant: CORNING INCORPORATED
Inventor： Jun Hou , Kuan-Ting Kuo , Kevin Robert McCarthy , Robert Lee Smith, III
IPC: B32B7/14 , G02B1/111 , G02B1/14 , B32B5/02 , B32B17/04 , B32B27/28 , H10K50/84 , G02B1/115 , H04M1/02
CPC classification number: G02B1/111 , B32B5/024 , B32B7/14 , B32B17/04 , B32B27/281 , G02B1/14 , H10K50/84 , B32B2262/101 , B32B2307/536 , B32B2307/584 , B32B2457/206 , G02B1/115 , H04M1/0268
Abstract: Optically transparent fiber glass cover substrates for electronic displays. The cover substrates include an optically transparent fiberglass composite layer including a fiberglass layer embedded in a matrix material and an optically transparent hard-coat layer bonded to a top surface of the optically transparent fiberglass composite layer. A bottom surface of the optically transparent fiberglass composite layer may define a bottommost exterior surface of a cover substrate. The bottommost exterior surface of a cover substrate may be disposed over a display surface of an electronic display to protect the display surface from damage.
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公开(公告)号：US11447610B2
公开(公告)日：2022-09-20
申请号：US16607634
申请日：2018-04-26
Applicant: CORNING INCORPORATED
Inventor： Jun Hou , Kevin Robert McCarthy
IPC: C08J5/04 , C08J5/18 , C08F22/20 , C08L35/02 , D03D15/267
Abstract: Described herein are articles and methods of making articles, including a transparent composite film having a fiber filler embedded in a polymer network. The polymer network of the transparent composite film is a cured, cross-linked matrix including a first and second structure segment. The structure segments may contribute or impart improved properties in the transparent composite film. The select structure segments can provide increased modulus and reduced glass transition temperature thereby allowing for a desirable balance of flexibility and rigidity in the transparent composite film. The improved transparent composite film is suitable for many applications including use in display devices.
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公开(公告)号：US11414527B2
公开(公告)日：2022-08-16
申请号：US16607874
申请日：2018-04-23
Applicant: CORNING INCORPORATED
Inventor： Jun Hou , Kevin Robert McCarthy
IPC: B32B27/12 , B32B27/30 , B32B27/40 , C08J5/08 , C08J5/04 , C08J7/046 , C08J5/18 , C09D175/16 , G02F1/1333 , C08G18/81
Abstract: Described herein are articles and methods of making articles, including a transparent composite film having a fiber filler embedded in a polymer network and further including a hard coating. The polymer network of the film is a cured, cross-linked matrix. The hard coating is a cross-linked aromatic urethane acrylate oligomer and a photoinitiator and provides a flexible protective layer that maintains good hardness, puncture-resistance and scratch-resistance.
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公开(公告)号：US09505880B2
公开(公告)日：2016-11-29
申请号：US14259390
申请日：2014-04-23
Applicant: Corning Incorporated
Inventor： Kevin Robert McCarthy , Weijun Niu , David Neal Schissel , Arthur Lawrence Wallace
IPC: G02B6/02 , C08G65/332
CPC classification number: C08G65/3322
Abstract: A method of synthesizing urethane-free polyfunctional acrylate compounds. The method includes reaction of a polyol with acrylic acid in the presence of an inhibitor. A catalyst may also be present. The catalyst may be an acid and the inhibitor may be a substituted phenol compound. Excess acid may be removed by adding a salt and excess water may be removed by adding a drying agent. The reaction converts alcohol groups of the polyol to acrylate groups to provide a radiation-curable polyfunctional acrylate compound. The reaction is applicable to polyols generally and provides a scalable high yield process for forming urethane-free polyfunctional acrylates over a wide range of molecular weights. Coatings made from the acrylate products exhibit modulus and tensile strength characteristics favorable for primary fiber coatings.
Abstract translation: 一种合成无氨基甲酸酯的多官能丙烯酸酯化合物的方法。 该方法包括在抑制剂存在下，多元醇与丙烯酸的反应。 催化剂也可以存在。 催化剂可以是酸，抑制剂可以是取代的酚化合物。 可以通过加入盐除去过量的酸，并且可以通过加入干燥剂除去过量的水。 该反应将多元醇的醇基转化为丙烯酸酯基团，以提供可辐射固化的多官能丙烯酸酯化合物。 该反应通常适用于多元醇，并提供可扩展的高收率方法，用于在宽范围的分子量下形成无氨基甲酸酯的多官能丙烯酸酯。 由丙烯酸酯产品制成的涂料显示出对初级纤维涂层有利的模量和拉伸强度特性。
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