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11.发明授权Process for producing a lubricant base oil having improved oxidative stability 失效具有改善的氧化稳定性的润滑油基础油的制造方法
公开(公告)号：US6025305A
公开(公告)日：2000-02-15
申请号：US128727
申请日：1998-08-04
IPC分类号： C10G45/58 , C10G45/72 , C10G71/00 , C10M105/04 , C10N20/00 , C10N30/02 , C10N30/10 , C10N70/00 , G01N33/28 , C10M109/00 , C10M101/02
CPC分类号： G01N33/2888 , G01N33/2805 , C10G2400/10
摘要： The instant invention is directed to a process for producing an improved lubricating base stock having a preselected desired oxidation stability comprising the steps of: (a) hydroisomerizing a hydrocarbon wax to obtain a lubricating base stock, (b) irradiating, within the frequency of about 4600 to about 3500 cm.sup.-1 or about 1300 to about 600 cm.sup.-1, said lubricating base stock produced from hydroisomerization of said hydrocarbon wax, (c) measuring the absorption spectrum, within said frequency range of step (b), of said lubricating base stock using FT-IR, (d) converting said absorption spectrum into a number representative of the viscosity index of said lubricating base stock of step (a), (e) comparing the viscosity index produced in step (c) to a preselected viscosity index correlating to a preselected desired oxidative stability for said lubricating base stock of step (a), and then, (f) modifying said hydroisomerization of said hydrocarbon wax to increase the production of lubricating base stock having said preselected desired oxidative stability of step (e).
摘要翻译： 本发明涉及一种生产具有预选所需氧化稳定性的改进的润滑基料的方法，其包括以下步骤：（a）将烃蜡加氢异构化以获得润滑基础油料，（b）在约 4600至约3500cm -1或约1300至约600cm -1，所述润滑基础油料通过所述烃蜡的加氢异构化产生，（c）在步骤（b）的所述频率范围内测量所述润滑油 （d）将所述吸收光谱转化成代表步骤（a）的所述润滑基料的粘度指数的数字，（e）将步骤（c）中产生的粘度指数与预选粘度 指数与步骤（a）的所述润滑基础油料的预选所需的氧化稳定性相关，然后（f）改变所述烃蜡的所述加氢异构化以增加润滑剂b的产生 具有所述步骤（e）的所需预期氧化稳定性的原料。
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12.发明授权Hydroisomerization of a predominantly N-paraffin feed to produce high purity solvent compositions 失效主要是N-链烷烃进料的加氢异构化以产生高纯度溶剂组合物
公开(公告)号：US5866748A
公开(公告)日：1999-02-02
申请号：US636424
申请日：1996-04-23
CPC分类号： C10G45/58 , Y10S208/95
摘要： A process for the hydroisomerization of a predominantly C.sub.8 -C.sub.20 n-paraffinic feed to produce a high purity C.sub.8 -C.sub.20 paraffinic solvent composition having superior low temperature properties, and low viscosities. The feed is contacted, with hydrogen, over a dual functional catalyst to hydroisomerize and convert the feed to a product comprising a mixture of n-paraffins and isoparaffins, the isoparaffins component of which contains greater than 50 percent of mono-methyl species, with the molar ratio of isoparaffins:n-paraffins ranging from about 0.5:1 to 9:1.
摘要翻译： 主要C8-C20正链烷烃进料加氢异构化的方法，以产生具有优异的低温性能和低粘度的高纯度C8-C20链烷烃溶剂组合物。 进料与氢气在双官能催化剂上接触，将进料加氢异构化并转化成包含正链烷烃和异链烷烃的混合物的产物，其异链烷烃组分含有大于50％的单甲基物质，其中 异链烷烃的摩尔比：正链烷烃的范围为约0.5:1至9:1。
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公开(公告)号：US06590002B2
公开(公告)日：2003-07-08
申请号：US09905231
申请日：2001-07-13
申请人： Robert Jay Wittenbrink , Louis Francis Burns , Gregg Johnston Howsmon , Geoffrey Rhys Say , Charles Harrison Mauldin
发明人： Robert Jay Wittenbrink , Louis Francis Burns , Gregg Johnston Howsmon , Geoffrey Rhys Say , Charles Harrison Mauldin
IPC分类号： C07C2700
CPC分类号： C10G2/342 , B01J8/005 , B01J8/006 , B01J8/224 , B01J8/228 , B01J2208/00212 , B01J2208/00265 , B01J2208/00407
摘要： A hydrocarbon wax product from a HCS slurry comprising liquid synthesis product and catalyst particles is purified by circulating the slurry from a synthesis zone with a first temperature through a treatment zone with a second temperature in which a hydrogen-containing treatment gas contacts the slurry. The gas treatment removes impurities from the hydrocarbon wax product and also removes catalyst de-activating species which may be present in the slurry. Purified wax product is separated and removed from the treated slurry via wax withdrawal means. This avoids or minimizes the need for further treating the wax product. Remaining treated slurry may be returned to the synthesis zone.
摘要翻译： 包含液体合成产物和催化剂颗粒的HCS浆料的烃蜡产物通过使第一温度的合成区的浆料循环通过处理区，其中含氢处理气体与浆料接触的第二温度循环来纯化。 气体处理从烃蜡产物中除去杂质，并除去可能存在于浆料中的催化剂去活化物质。 通过蜡提取装置从经处理的浆料中分离并除去纯化的蜡产物。 这避免或最小化对进一步处理蜡产品的需要。 剩余处理的浆料可以返回到合成区。
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公开(公告)号：US06296757B1
公开(公告)日：2001-10-02
申请号：US08544343
申请日：1995-10-17
IPC分类号： C10G1400
摘要： Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.− portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
摘要翻译： 通过将费 - 托产物分离成更轻和更重的馏分（例如在约700°F），将非挥发性费 - 托方法从具有优异的润滑性，氧化稳定性和高十六烷值的柴油燃料或混合原料生产， 加热处理的700°F +级分，并将加氢处理产物的700°F部分与尚未加氢处理的较轻级分组合。
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公开(公告)号：US06274029B1
公开(公告)日：2001-08-14
申请号：US09464179
申请日：1999-12-16
IPC分类号： C10L104
摘要： Diesel fuels or blending stocks having excellent lubricity, oxidative stability and high cetane number are produced from non-shifting Fischer-Tropsch processes by separating the Fischer-Tropsch product into a lighter and heavier fractions, e.g., at about 700° F., subjecting the 700° F.+fraction to hydro-treating, and combining the 700° F.+portion of the hydrotreated product with the lighter fraction that has not been hydrotreated.
摘要翻译： 通过将费 - 托产物分离成更轻和更重的馏分（例如在约700°F），将非挥发性费 - 托方法从具有优异的润滑性，氧化稳定性和高十六烷值的柴油燃料或混合原料生产， 加热处理的700°F +级分，并将加氢处理的产物的700°F +部分与未加氢处理的较轻级分组合。
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公开(公告)号：US6096690A
公开(公告)日：2000-08-01
申请号：US83489
申请日：1998-05-22
CPC分类号： C09K8/36 , C09K8/34 , Y10S507/905
摘要： Discloses environmentally friendly, low temperature base oils and drilling fluids, or drilling mud compositions useful in the production of oil and gas. The drilling fluid is constituted of one or more of weighting agents, emulsifiers, wetting agents, viscosifiers, fluid loss control agents, proppants, and other particulates such as used in a gravel pack, emulsified with a paraffinic solvent composition which forms a continuous oil phase, or water-in-oil invert phase. The solvent composition is constituted of a mixture of C.sub.10- C.sub.24 n-paraffins and isoparaffins having an isoparaffin:n-paraffin molar ratio ranging from about 0.5:1 to about 9:1, the isoparaffins of the mixture contain greater than 30 percent, preferably from about 30 percent to about 50 percent, of mono-methyl species, and greater than 30 percent, preferably from about 30 percent to about 50 percent of multi-methyl branched species and isoparaffins which contain one or more branches of carbon number higher than methyl, based on the total weight of the isoparaffins in the mixture. The presence of the mono-methyl species is sufficient to provide the admirable environmentally friendly qualities, and the multi-methyl branched and isoparaffin species more highly branched than methyl provide low temperature properties.
摘要翻译： 公开了环保的低温基础油和钻井液，或用于生产油和气的钻井泥浆组合物。 钻井液由一种或多种增重剂，乳化剂，润湿剂，增粘剂，流体损失控制剂，支撑剂和其它颗粒组成，例如在用石蜡溶剂组合物乳化的砾石包装中使用的颗粒，其形成连续油相 ，或油包水反相。 溶剂组合物由具有约0.5:1至约9:1的异链烷烃：正链烷烃摩尔比的C10-C24正链烷烃和异链烷烃的混合物构成，混合物的异链烷烃含量大于30％ 约30％至约50％的单甲基物质，以及大于30％，优选约30％至约50％的多甲基支链物质和含有一个或多个碳数高于甲基的支链的异链烷烃 ，基于混合物中异链烷烃的总重量。 单甲基物质的存在足以提供令人敬佩的环境友好的品质，并且比甲基更高支化的多甲基支链和异链烷烃提供低温性能。
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公开(公告)号：US5906727A
公开(公告)日：1999-05-25
申请号：US81364
申请日：1998-05-19
CPC分类号： C10G45/58
摘要： Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt.% to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.
摘要翻译： 公开了由正链烷烃和异链烷烃构成的高纯度溶剂组合物，其中主要含有甲基支链的异链烷烃，并且具有足以提供优异的低温性能和低粘度的异链烷烃：正链烷烃比率。 溶剂组合物通过以下方法制备，其中蜡状或长链石蜡原料，特别是费 - 托蜡在双功能催化剂上反应，以在700°F下进行加氢异构化和加氢裂化反应。+转化率范围为约20 至90重量％以提供C5-1050°F粗馏分。 然后通过常压蒸馏将C5-1050°F粗馏分顶起来产生沸点高于约650°F至750°F的高沸点馏分。将低沸点馏分分馏，并将窄沸点溶剂 由此获得; 可以进一步分为各种沸程的溶剂等级。
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公开(公告)号：US5807413A
公开(公告)日：1998-09-15
申请号：US691769
申请日：1996-08-02
CPC分类号： C10L1/08
摘要： A diesel engine fuel is produced from Fischer-Tropsch wax by separating a light density fraction, e.g., C.sub.5 -C.sub.15, preferably C.sub.7 -C.sub.14 cut having at least 80+ wt % n-paraffins, no more than 5000 ppm alcohols as oxygen, less than 10 wt % olefins, twice aromatics and very low sulfur and nitrogen.
摘要翻译： 通过分离光密度分数，例如C5-C15，优选具有至少80重量％正链烷烃的C7-C14切割，不超过5000ppm的醇作为氧，柴油发动机燃料减少 超过10重量％的烯烃，两次芳烃和非常低的硫和氮。
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公开(公告)号：US06860909B2
公开(公告)日：2005-03-01
申请号：US10461824
申请日：2003-06-13
CPC分类号： C10L1/08 , Y10S208/95
摘要： A blend useful as a diesel fuel, as well as a method for its production, comprising a high quality Fischer-Tropsch derived distillate boiling in the range of a diesel fuel blended with a cracked stock boiling in the range of a diesel fuel wherein the final blend contains 10-35 wt. % aromatics and 1-20 wt. % polyaromatics and produces low regulated emissions levels.
摘要翻译： 用作柴油燃料的共混物以及其生产方法包括在柴油燃料范围内沸腾的高质量费 - 托衍生的馏出物，其与在柴油燃料范围内沸腾的裂化原料混合，其中最终 共混物含有10-35wt。 ％芳族化合物和1-20重量％ ％多芳族化合物，并产生低调节排放水平。
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公开(公告)号：US06833064B2
公开(公告)日：2004-12-21
申请号：US09922321
申请日：2001-08-03
申请人： Paul Joseph Berlowitz , Robert Jay Wittenbrink , Daniel Francis Ryan , William Berlin Genetti , Jack Wayne Johnson
发明人： Paul Joseph Berlowitz , Robert Jay Wittenbrink , Daniel Francis Ryan , William Berlin Genetti , Jack Wayne Johnson
IPC分类号： C10L104
CPC分类号： C10L1/08 , Y10S208/95
摘要： A wide cut Fischer-Tropsch derived diesel fuel is produced wherein the distillate boils in a wider range than a conventional diesel fuel while providing favorable low temperature properties and environmentally beneficial effects. In particular, the fuel comprises a hydrocarbon distillate derived from the Fischer-Tropsch process having T90 greater than 640° F. (338° C.) but less than 1000° F. (538° C.) and a cold filter plugging point less than or equal to +5° C.
摘要翻译： 产生广泛的费 - 托衍生的柴油燃料，其中馏出物在比常规柴油燃料更宽的范围内沸腾，同时提供有利的低温性质和环境有益的效果。 特别地，燃料包括衍生自费 - 托法的烃馏出物，其具有T90大于640°F（338℃）但小于1000°F（538℃），冷过滤器堵塞点较少 超过+ 5℃
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