摘要:
Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt.% to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.
摘要:
A process for the hydroisomerization of a predominantly C.sub.8 -C.sub.20 n-paraffinic feed to produce a high purity C.sub.8 -C.sub.20 paraffinic solvent composition having superior low temperature properties, and low viscosities. The feed is contacted, with hydrogen, over a dual functional catalyst to hydroisomerize and convert the feed to a product comprising a mixture of n-paraffins and isoparaffins, the isoparaffins component of which contains greater than 50 percent of mono-methyl species, with the molar ratio of isoparaffins:n-paraffins ranging from about 0.5:1 to 9:1.
摘要:
Discloses high purity solvent compositions constituted of n-paraffins and isoparaffins, with the isoparaffins containing predominantly methyl branches, and having an isoparaffin:n-paraffin ratio sufficient to provide superior low temperature properties and low viscosities. The solvent compositions are made by a process wherein a waxy, or long chain paraffinic feed, especially a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions at 700.degree. F.+ conversion levels ranging from about 20 to 90 wt. % to provide a C.sub.5 -1050.degree. F. crude fraction. The C.sub.5 -1050.degree. F. crude fraction is then topped via atmospheric distillation to produce a low boiling fraction with an upper end point boiling between about 650.degree. F. and 750.degree. F. The low boiling fraction is fractionated and a narrow boiling range solvent obtained therefrom; one which can be further divided into solvent grades of various boiling ranges.
摘要:
A process for the production of a winter diesel fuel from wax containing hydrocarbons produced by the Fischer-Tropsch hydrocarbon synthesis process. A 300° F.+ Fischer-Tropsch fraction is upgraded first by hydroisomerization followed by catalytic dewaxing resulting in a diesel fuel suitable for use as a winter diesel fuel having excellent cold flow properties and reduced emissions.
摘要:
A wide cut Fischer-Tropsch derived diesel fuel is produced wherein the distillate boils in a wider range than a conventional diesel fuel while providing favorable low temperature properties and environmentally beneficial effects. In particular, the fuel comprises a hydrocarbon distillate derived from the Fischer-Tropsch process having T90 greater than 640° F. (338° C.) but less than 1000° F. (538° C.) and a cold filter plugging point less than or equal to +5° C.
摘要:
A blended fuel, useful as a diesel fuel, wherein the fuel blend contains an undercut conventional diesel fuel, blended with a Fischer-Tropsch derived diesel fuel, such that the blend demonstrates better than expected emissions and a reduced sulfur content. In particular, the blend is an asymmetric diesel fuel blend comprising a Fischer-Tropsch derived hydrocarbon distillate having a T95 of at least 600° F., blended with a petroleum derived hydrocarbon distillate having an initial boiling point and a T95 no greater than 640° F.
摘要:
Discloses novel biodegradable high performance hydrocarbon base oils useful as lubricants in engine oil and industrial compositions, and process for their manufacture. A waxy, or paraffinic feed, particularly a Fischer-Tropsch wax, is reacted over a dual function catalyst to produce hydroisomerization and hydrocracking reactions, at 700° F.+ conversion levels ranging from about 20 to 50 wt. %, preferably about 25-40 wt. %, sufficient to produce a crude fraction, e.g., a C5-1050° F.+ crude fraction, containing 700° F.+ isoparaffins having from about 6.0 to about 7.5 methyl branches per 100 carbon atoms in the molecule. The methyl paraffins containing crude fraction is topped via atmospheric distillation to produce a bottoms fraction having an initial boiling point between about 650° F. and 750° F. which is then solvent dewaxed, and the dewaxed oil is then fractionated under high vacuum to produce biodegradable high performance hydrocarbon base oils.
摘要:
Discloses environmentally friendly, low temperature base oils and drilling fluids, or drilling mud compositions useful in the production of oil and gas. The drilling fluid is constituted of one or more of weighting agents, emulsifiers, wetting agents, viscosifiers, fluid loss control agents, proppants, and other particulates such as used in a gravel pack, emulsified with a paraffinic solvent composition which forms a continuous oil phase, or water-in-oil invert phase. The solvent composition is constituted of a mixture of C.sub.10- C.sub.24 n-paraffins and isoparaffins having an isoparaffin:n-paraffin molar ratio ranging from about 0.5:1 to about 9:1, the isoparaffins of the mixture contain greater than 30 percent, preferably from about 30 percent to about 50 percent, of mono-methyl species, and greater than 30 percent, preferably from about 30 percent to about 50 percent of multi-methyl branched species and isoparaffins which contain one or more branches of carbon number higher than methyl, based on the total weight of the isoparaffins in the mixture. The presence of the mono-methyl species is sufficient to provide the admirable environmentally friendly qualities, and the multi-methyl branched and isoparaffin species more highly branched than methyl provide low temperature properties.
摘要:
A diesel engine fuel is produced from Fischer-Tropsch wax by separating a light density fraction, e.g., C.sub.5 -C.sub.15, preferably C.sub.7 -C.sub.14 cut having at least 80+ wt % n-paraffins, no more than 5000 ppm alcohols as oxygen, less than 10 wt % olefins, twice aromatics and very low sulfur and nitrogen.
摘要:
A hydrocarbon wax product from a hydrocarbon synthesis slurry comprising liquid synthesis product and catalyst particles is purified by introducing a portion of hydrocarbon synthesis slurry from a hydrocarbon synthesis zone to a treatment zone in which a treatment gas contacts the hydrocarbon synthesis slurry. Hydrogen or a hydrogen-containing gas is useful as the treatment gas. The gas treatment removes impurities from the hydrocarbon wax portion of the hydrocarbon synthesis slurry. Purified wax product is separated and removed in situ via wax withdrawal means. This avoids or minimizes the need for further treating the wax product.