摘要:
Preparation of rubber-modified molding compositions comprises a1) anionic polymerization of a mixture (A) comprising acrylate derivatives or methacrylate derivatives or acrylate derivatives and methacrylate derivatives and a solvent, if desired comprising olefinically unsaturated compounds which are not an acrylate derivative or a methacrylate derivative, or a2) sequential anionic polymerization of acrylate derivatives or methacrylate derivatives or acrylate derivatives and methacrylate derivatives in the presence of a solvent which, if desired, comprises olefinically unsaturated compounds to give block copolymers, and b) subjecting the reaction mixture obtained in a1) or a2) or a1) and a2) to a free-radical-initiated polymerization, if desired after the addition of unsaturated compounds.
摘要:
A process for preparing a solution of high molecular weight polymers of conjugated dienes in a vinylaromatic hydrocarbon by anionic polymerization of the diene in the presence of an alkyllithium as catalyst and a process for preparing impact-modified polymers of vinylaromatic compounds is described. The first process comprises firstly polymerizing the diene in solution in an aromatic hydrocarbon which is free of ethylenic double bonds to a molecular weight below about 105, then adding a trialkylaluminum in a molar excess relative to the alkyllithium, diluting the solution obtained with the vinylaromatic compound and then coupling the polydiene with a polyepoxide or an alkyl (meth)acrylate to give a high molecular weight polymer. The solution obtained in this way is further processed to give an impact-modified polymer of a vinylaromatic hydrocarbon by polymerizing the solution prepared as described, if desired after addition of further amounts of a vinylaromatic compound, in a manner known per se.
摘要:
Anionic polymerization is used for the preparation of reaction mixtures comprising homopolymers, copolymers or block copolymers, and of homopolymers, copolymers and block copolymers which comprise acrylates or methacrylates or acrylates and methacrylates, wherein olefinically unsaturated compounds which are not acrylate or methacrylate derivatives are employed as solvent or as solvent component.
摘要:
The present invention concerns a novel method for preparing polymers (preferably (meth)acrylate polymers and copolymers) having a narrow molecular weight distribution by metal-free anionic polymerization in the presence of a phosphonium cation containing at least one annellated aromatic ring as substituent on the phosphorous atom.
摘要:
A process for producing an activated monomer composition comprising at least one lactam and/or lactone, one catalyst, and one activator permits storage of the resultant monomer composition, since this is stable with respect to polymerization. Said monomer composition is used inter alia in producing a polyamide molding via ring-opening, anionic polymerization.
摘要:
A process for producing an activated monomer composition comprising at least one lactam and/or lactone, one catalyst, and one activator permits storage of the resultant monomer composition, since this is stable with respect to polymerization. Said monomer composition is used inter alia in producing a polyamide molding via ring-opening, anionic polymerization.
摘要:
The invention relates to a nanocomposite containing (I) a star-shaped, branched block copolymer made of vinylaromatic monomers and dienes and (II) a layer silicate. The invention also relates to a method for the production thereof.
摘要:
The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.
摘要:
The invention relates to a flameproofed resilient block polymer comprising polymerized units of at least one vinylaromatic monomer and at least one diene monomer with at least one flameproofing agent B) which comprises a compound comprising phosphorus, in particular a phosphorus-containing melamine compound, a process for the preparation and the use for the production of moldings.
摘要:
An expandable pelletized material comprising A) a polymer matrix composed of A1) at least 55% by weight of polyamide (based on the entirety of components A1) and A2)) with a crystallinity of up to 30% and if appropriate a melting point in the range from 100 to 340° C. and a glass transition temperature in the range from 0 to 150° C., and A2) from 0 to 45% by weight of one or more thermoplastic polymers that differ from component A1); B) a physical blowing agent composition, and C) optionally further additives, is suitable for producing a moldable foam for use in the automobile industry, airline industry, construction industry, packaging industry, or sports and leisure industry, or in the transport sector, and/or in engineering.