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11.发明授权Method of fluorinating by using N-fluoropyridinium pyridine heptafluorodiborate 失效使用N-氟吡啶鎓吡啶七氟二硼酸酯进行氟化的方法
公开(公告)号：US5086190A
公开(公告)日：1992-02-04
申请号：US647101
申请日：1991-01-29
IPC分类号： C07B39/00 , C07C45/51 , C07C45/54 , C07C45/56 , C07D213/89 , C07F5/02 , C07J1/00 , C07J41/00 , C07J51/00
CPC分类号： C07D213/89 , C07B39/00 , C07C45/511 , C07C45/54 , C07C45/56 , C07F5/022 , C07J1/0011 , C07J1/0025 , C07J41/0005 , C07J51/00
摘要： The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.
摘要翻译： 本发明提供了一种新化合物，其表示为本发明的新化合物，其通过氟与吡啶 - 三氟化硼反应制备，并且可用作有机化合物的氟化中的氟化剂。
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公开(公告)号：US20110288350A1
公开(公告)日：2011-11-24
申请号：US13110998
申请日：2011-05-19
申请人： Andrew Joseph Poss , Michael Van Der Puy , Rajiv Ratna Singh , David Nalewajek , Haridasan K. Nair
发明人： Andrew Joseph Poss , Michael Van Der Puy , Rajiv Ratna Singh , David Nalewajek , Haridasan K. Nair
IPC分类号： C07C17/281
CPC分类号： C07C17/23 , C07B2200/09 , C07C17/10 , C07C17/206 , C07C17/278 , C07C21/18 , C07C19/10
摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).
摘要翻译： 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。
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公开(公告)号：US20090099274A1
公开(公告)日：2009-04-16
申请号：US12241606
申请日：2008-09-30
CPC分类号： C08G18/1808 , C08G18/1816 , C08G18/40 , C08G2101/00 , C08G2101/0025 , C08G2105/02 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2203/162 , C08J2203/164 , C08J2203/18 , C08J2205/046 , C08J2205/10 , C08J2375/04
摘要： The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.
摘要翻译： 本发明提供了聚氨酯和聚异氰脲酸酯泡沫及其制备方法。更具体地说，本发明涉及开孔，聚氨酯和聚异氰脲酸酯泡沫及其制备方法。 泡沫的特征在于细小的均匀的细胞结构和很少或没有泡沫崩溃。 泡沫用多元醇预混物组合物制备，该组合物包含氢卤烯烃发泡剂，多元醇，硅氧烷表面活性剂和空间位阻胺催化剂的组合。
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公开(公告)号：US20070161827A1
公开(公告)日：2007-07-12
申请号：US11328048
申请日：2006-01-09
IPC分类号： C07C33/42
CPC分类号： C07C33/423 , C07C29/40
摘要： Disclosed are fluorinated diene alcohols perferably having a fluorine content of at least about 45 weight percent and having a plurality of moieties of the formula CFx and a plurality of moieties of the formula CHx, where each x is independently 1, 2 or 3 and where each CFx moiety is not directly bonded to another CFx moiety. Methods of synthesizing fluorinated diene alcohol compounds are also disclosed comprising reacting at least one C2-C3 alkene halide with at least one reactant of the formula (II): where Z is OH, OR6, OC(O)R7, or a halogen, R6 is a C1-C6 branched or straight chain alkyl, and R7 is a C1-C6 branched or straight chain alkyl or fluoroalkyl,
摘要翻译： 公开的氟化二烯醇优选具有至少约45重量％的氟含量并且具有多个式CF x X的部分和多个式CH x x的部分， 其中每个x独立地为1,2或3，并且其中每个CF x X部分不直接键合到另一个CF x X部分。 还公开了合成氟化二烯醇化合物的方法，包括使至少一种C 2 -C 3 -C 3烯烃卤化物与至少一种式（II）的反应物反应：其中Z 是OH，OR 6，OC（O）R 7或卤素，R 6是C 1 H 12 C 6 -C 6支链或直链烷基，R 7是C 1 -C 6 -C 6支链或直链烷基， 直链烷基或氟烷基，
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公开(公告)号：US06355113B1
公开(公告)日：2002-03-12
申请号：US09186932
申请日：1998-11-06
申请人： David Nalewajek , Rajat Subhra Basu , David Paul Wilson , Michael Van Der Puy , Ellen Louise Swan , Peter Brian Logsdon , Gary J. Zyhowski , Hepburn Ingham , Daniel Franklin Harnish , Joel Edward Rodgers
发明人： David Nalewajek , Rajat Subhra Basu , David Paul Wilson , Michael Van Der Puy , Ellen Louise Swan , Peter Brian Logsdon , Gary J. Zyhowski , Hepburn Ingham , Daniel Franklin Harnish , Joel Edward Rodgers
IPC分类号： B08B308
CPC分类号： C11D7/5018 , C11D7/24 , C11D7/28 , C23G5/02 , C23G5/024 , H05K3/26 , H05K2203/0766 , H05K2203/0783 , H05K2203/1518
摘要： A non-aqueous cleaning process uses an organic solvent for removing soil or surface contamination from contaminated articles such as printed circuit boards which are cleaned by immersion into a sump compartment of a cleaning tank containing the organic cleaning solvent. The organic solvent is preferably a hydrocarbon solvent. The cleaned articles, now coated with the organic cleaning solvent, are then disposed in a rinsing sump containing a fluorocarbon based rinsing solvent having an affinity for the organic cleaning solvent. The organic solvent is thus removed from the articles which are then dried without waste water as in a conventional solvent vapor degreasing solvent process.
摘要翻译： 非水清洗方法使用有机溶剂去除被污染物品（例如印刷电路板）污染的土壤或表面污染物，其通过浸入含有有机清洗溶剂的清洗槽的贮槽室中清洗。 有机溶剂优选为烃溶剂。 然后将现在涂覆有机清洁溶剂的清洁物品置于含有对有机清洁溶剂具有亲和性的基于碳氟化合物的漂洗溶剂的漂洗池中。 因此，有机溶剂从制品中除去，然后如常规溶剂蒸汽脱脂溶剂法那样无需废水干燥。
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公开(公告)号：US5696307A
公开(公告)日：1997-12-09
申请号：US184810
申请日：1994-01-21
CPC分类号： C07C19/08 , C11D7/5018 , C23G5/02803
摘要： Hydrofluoroalkanes useful as solvents, especially for vapor degreasing and solvent cleaning, are one or many of the following formulae: CHF.sub.2 --X--(CHF).sub.n --X--Y wherein X is selected from the group consisting of CHF, CF.sub.2 and CH.sub.2, Y is CH.sub.3, and n is 0, 1 or 2.
摘要翻译： 可用作溶剂，特别是用于蒸气脱脂和溶剂清洗的溶剂的氢氟烷烃是下列一种或多种：CHF 2 -X-（CHF）n X-Y，其中X选自CHF，CF 2和CH 2，Y是CH 3， n为0,1或2。
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17.发明授权Preparation of 1,1,1,2,3-pentafluoropropane by reduction of 1,2,3-trichloropentafluropropane 失效通过还原1,2,3-三氯丙基丙烷制备1,1,1,2,3-五氟丙烷
公开(公告)号：US5315048A
公开(公告)日：1994-05-24
申请号：US130083
申请日：1993-09-30
摘要： The present invention relates to a process for the reductive dechlorination of ClCF.sub.2 CFClCF.sub.2 Cl to CF.sub.3 CHFCH.sub.2 F comprising the step of contacting 1,2,3-trichloropentafluoropropane and H.sub.2 in the presence of a catalyst selected from the group consisting of palladium, platinum, ruthenium, rhodium, iridium and mixtures thereof supported on alumina under reaction conditions sufficient to produce a product stream containing 1,1,1,2,3-pentafluoropropane.
摘要翻译： 本发明涉及将ClCF 2 CFClCF 2 Cl还原脱氯至CF 3 CHFCH 2 F的方法，包括在选自钯，铂，钌，铑，铱的催化剂存在下使1,2,3-三氯五氟丙烷与H 2接触的步骤 和其混合物在足以产生含有1,1,1,2,3-五氟丙烷的产物流的反应条件下负载在氧化铝上。
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公开(公告)号：US08901360B2
公开(公告)日：2014-12-02
申请号：US13110979
申请日：2011-05-19
IPC分类号： C07C21/18 , C07C17/278 , C07C17/04 , C07C17/20 , C07C17/23 , C07C17/25 , C07C17/354
CPC分类号： C07C17/278 , C07C17/04 , C07C17/206 , C07C17/23 , C07C17/25 , C07C17/354 , C07C19/10 , C07C21/22 , C07C21/18
摘要： Disclosed is a process for preparing cis-1,1,1,4,4,4-hexafluorobutene comprising the steps of (a) reacting CCl4 with a compound having the formula CF3CX═CXH, where each X is independently halogen or hydrogen, to form a compound having the formula CF3CXClCXHCCl3; (b) fluorinating the compound formed in step (a) to form a compound having the formula CF3CXHCXHCF3; (c) converting the compound formed in step (b) by a reaction selected from the group consisting of dehydrohalogenation, dehalogenation and both reactions, to form a compound having the formula CF3C≡CCF3; and (d) catalytically reducing the compound formed in step (c) with hydrogen to form the compound having the formula:
摘要翻译： 公开了一种制备顺式-1,1,1,4,4,4-六氟丁烯的方法，包括以下步骤：（a）使CCl4与具有式CF 3 C X = C X H的化合物反应，其中每个X独立地为卤素或氢， 形成式CF3CXClCXHCCl3的化合物; （b）氟化步骤（a）中形成的化合物以形成具有式CF 3 C XHCXHCF 3的化合物; （c）通过选自脱卤化氢，脱卤和两种反应的反应转化步骤（b）中形成的化合物，以形成具有式CF 3C≡CCF3的化合物; 和（d）用氢气将步骤（c）中形成的化合物催化还原以形成具有下式的化合物：
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公开(公告)号：US4935519A
公开(公告)日：1990-06-19
申请号：US406659
申请日：1989-09-13
IPC分类号： C07D213/89 , C07F5/02
CPC分类号： C07D213/89 , C07F5/022
摘要： The present invention provides a novel compound represented as ##STR1## The present novel compound is prepared by reacting fluorine with pyridine-boron trifluoride and is useful as a fluorinating agent in the fluorination of organic compounds.
摘要翻译： 本发明提供了一种新化合物，其表示为本发明的新化合物，其通过氟与吡啶 - 三氟化硼反应制备，并且可用作有机化合物的氟化中的氟化剂。
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公开(公告)号：US08604257B2
公开(公告)日：2013-12-10
申请号：US13110998
申请日：2011-05-19
申请人： Andrew Joseph Poss , Michael Van Der Puy , Rajiv Ratna Singh , David Nalewajek , Haridasan K. Nair
发明人： Andrew Joseph Poss , Michael Van Der Puy , Rajiv Ratna Singh , David Nalewajek , Haridasan K. Nair
IPC分类号： C07C17/266
CPC分类号： C07C17/23 , C07B2200/09 , C07C17/10 , C07C17/206 , C07C17/278 , C07C21/18 , C07C19/10
摘要： Disclosed is a process for the preparation of fluorine-containing olefins comprising contacting a chlorofluoroalkane with hydrogen in the presence of a catalyst at a temperature sufficient to cause replacement of the chlorine substituents of the chlorofluoroalkane with hydrogen to produce a fluorine-containing olefin. Also disclosed are catalyst compositions for the hydrodechlorination of chlorofluoroalkanes comprising copper metal deposited on a support, and comprising palladium deposited on calcium fluoride, poisoned with lead and reducing the in the presence or absence of a dehydrochlorination catalyst under conditions effective to form a product stream comprising cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336).
摘要翻译： 公开了一种制备含氟烯烃的方法，包括在催化剂存在下，使氯氟烷烃与氢气在足以使氯氟烷烃的氯取代基被氢取代以产生含氟烯烃的温度下接触。 还公开了用于加氢脱氯氯氟烷烃的催化剂组合物，其包含沉积在载体上的铜金属，并且包含沉积在氟化钙上的钯，由铅中毒并在有效形成产物流的条件下在脱氯化氢催化剂存在或不存在下还原，包含 顺式-1,1,1,4,4,4-六氟-2-丁烯（HFO-1336）。
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